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2021 年度 実績報告書

Exploiting cascade reactions of high performance tearylenes for solar applications.

研究課題

研究課題/領域番号 19K15312
研究機関奈良先端科学技術大学院大学

研究代表者

Martin Colin  奈良先端科学技術大学院大学, 研究推進機構, 特任助教 (70836361)

研究期間 (年度) 2019-04-01 – 2022-03-31
キーワードTerarylenes / X-Rays / Cascade reaction / Photophysics
研究実績の概要

This grant focused on three key research areas (A, B and C).
A - Optimization of the cascade reaction: Analysis of the first generation (G1) of five molecules complete with photophysical, thermal and electrochemical analysis was completed in Year 2. In year 3 a further 8 molecules were prepared and tested. B - Studies of the cascade reaction in plastic/solid media: This part of the project was expanded from polymers and gels to also include other media such as micelles and pickering emulsions in conjunction with Assistant Professor M. Louis in the Kawai laboratory at NAIST. A Masters student has begun work on this topic. With the conclusion of my research position this part of the research topic will be continued in conjunction with Dr. Louis in NAIST. C - Expansion of frameworks towards detection of X-rays: A further second generation (G2) of eight targets designed to increase X-Ray absorption have now been prepared and fully characterized. These are added to the first generation prepared in Year 1 of this project. With the conclusion of my research position this part of the research topic will be continued in conjunction with Dr. Louis in NAIST.
A number of papers in these areas have been published

  • 研究成果

    (5件)

すべて 2021

すべて 雑誌論文 (4件) (うち国際共著 3件、 査読あり 3件、 オープンアクセス 1件) 学会発表 (1件) (うち国際学会 1件)

  • [雑誌論文] Molecular Rotor Functionalized with a Photoresponsive Brake2021

    • 著者名/発表者名
      Asato Ryosuke、Martin Colin J.、Abid Seifallah、Gisbert Yohan、Asanoma Fumio、Nakashima Takuya、Kammerer Claire、Kawai Tsuyoshi、Rapenne Gwenael
    • 雑誌名

      Inorganic Chemistry

      巻: 60 ページ: 3492~3501

    • DOI

      10.1021/acs.inorgchem.0c03330

    • 査読あり / 国際共著
  • [雑誌論文] Ruthenium complexes of sterically-hindered pentaarylcyclopentadienyl ligands2021

    • 著者名/発表者名
      Asato Ryosuke、Martin Colin J.、Gisbert Yohan、Abid Seifallah、Kawai Tsuyoshi、Kammerer Claire、Rapenne Gwenael
    • 雑誌名

      RSC Advances

      巻: 11 ページ: 20207~20215

    • DOI

      10.1039/D1RA03875C

    • 査読あり / オープンアクセス / 国際共著
  • [雑誌論文] Nanocars based on Polyaromatic or Porphyrinic Chassis2021

    • 著者名/発表者名
      Nishino Toshio、Martin Colin J.、Yasuhara Kazuma、Rapenne Gwenael
    • 雑誌名

      Journal of Synthetic Organic Chemistry, Japan

      巻: 79 ページ: 1050~1055

    • DOI

      10.5059/yukigoseikyokaishi.79.1050

    • 査読あり / 国際共著
  • [雑誌論文] Energy Storage upon Photochromic 6-π Photocyclization and Efficient On-Demand Heat Release with Oxidation Stimuli2021

    • 著者名/発表者名
      Asato Ryosuke、Martin Colin J.、Nakashima Takuya、Calupitan Jan Patrick、Rapenne Gwenael、Kawai Tsuyoshi
    • 雑誌名

      The Journal of Physical Chemistry Letters

      巻: 12 ページ: 11391~11398

    • DOI

      10.1021/acs.jpclett.1c03052

  • [学会発表] Systematic studies of structural variations in terarylene photohydride generators2021

    • 著者名/発表者名
      C. J. Martin, J. P. Calupitan, G. Rapenne, T. Nakashima and T. Kawai
    • 学会等名
      RSC Photophysics and Photochemistry Group Early Career Members Meeting, Web meeting
    • 国際学会

URL: 

公開日: 2022-12-28  

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