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2022 年度 実施状況報告書

Electrocatalytic Reductive Functionalization of Carbon Dioxide

研究課題

研究課題/領域番号 19K15671
研究機関東京工業大学

研究代表者

Li Yamei  東京工業大学, 地球生命研究所, 特任助教 (10745128)

研究期間 (年度) 2019-04-01 – 2024-03-31
キーワードAmino acid decomposition / Electrochemistry / Carbonaceous chondrite / Mineral catalysis
研究実績の概要

Based on the results on electrochemical decomposition of amino acids in CO2-saturated solution, I have studied the amino acid decomposition chemistry on the parent bodies of carbonaceous chondrites and asteroid. The significance is that these extraterrestrial samples could have provided amino acids for seeding origin of life on Earth. These research results have resulted in one published
paper (Nature Communications, 2022) and one manuscript currently under review (Li et al., under review). Our major finding is that aqueous alteration can lead to complex behavior of organics on its parent body, including both synthetic and breakdown mechanisms. Our findings suggest that water/rock differentiated Solar System bodies could have generated the chemical heterogenity in various samples.

現在までの達成度
現在までの達成度

1: 当初の計画以上に進展している

理由

The research is progressed as planned and have generated a novel model which can account for the organic distributions in extraterrestrial samples. The model together with the experimental results could contribute to diverse research fields, including astrobiology, origins of life, meteorite and planetary sciences. Our model provides some new hypotheses in an underexplored area, with relevance to origins of life, life detection, and potential upcoming missions.

今後の研究の推進方策

In the future, I plan to extend the model to real extraterrestrial samples.In detail, I would like to test the electrochemical reactivities of meteorites samples and possibly the return sample from asteroid Ryugu (under application). By studying these samples, the pristine catalytic properties of naturally-occuring minerals can be testified. The reaction mechanism and kinetic information can provide important constraints for deepening our understanding on the chemical evolution of their parent bodies.

  • 研究成果

    (7件)

すべて 2022 その他

すべて 雑誌論文 (1件) (うち国際共著 1件、 査読あり 1件、 オープンアクセス 1件) 学会発表 (4件) (うち国際学会 3件、 招待講演 1件) 図書 (1件) 備考 (1件)

  • [雑誌論文] Geoelectrochemistry-driven alteration of amino acids to derivative organics in carbonaceous chondrite parent bodies2022

    • 著者名/発表者名
      Li Yamei、Kitadai Norio、Sekine Yasuhito、Kurokawa Hiroyuki、Nakano Yuko、Johnson-Finn Kristin
    • 雑誌名

      Nature Communications

      巻: 13 ページ: 1-14

    • DOI

      10.1038/s41467-022-32596-3

    • 査読あり / オープンアクセス / 国際共著
  • [学会発表] Geo-electrochemistry drove chemical evolution in water/rock interacted environments on Earth and icy planetesimals2022

    • 著者名/発表者名
      Yamei LI
    • 学会等名
      21st International Sedimentological Congress
    • 国際学会
  • [学会発表] Geoelectrochemistry-driven alteration of amino acids to derivative organics in carbonaceous chondrite parent bodies2022

    • 著者名/発表者名
      Yamei LI
    • 学会等名
      AbSciCon meeting
    • 国際学会
  • [学会発表] Geo-electrochemistry drove chemical evolution in water/rock interacted environments on Earth and icy planetesimals2022

    • 著者名/発表者名
      Yamei LI
    • 学会等名
      The 45th Annual Meeting of the Molecular Biology Society of Japan
    • 招待講演
  • [学会発表] molecular descriptors of aqueous alteration-induced organic decomposition in parent body of carbonaceous chondrites and Ryugu asteroid2022

    • 著者名/発表者名
      Yamei LI
    • 学会等名
      Hayabusa 2022 Symposium
    • 国際学会
  • [図書] Mineralogy2022

    • 著者名/発表者名
      Yamei LI
    • 総ページ数
      266
    • 出版者
      Intech Open
    • ISBN
      978-1-80355-466-2
  • [備考] Research highlight

    • URL

      https://www.elsi.jp/en/news_events/highlights/2022/chemical_evolution_early_solar_system/

URL: 

公開日: 2023-12-25  

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