非対称トリブロック共重合体ミセルを鋳型とする中空無機ナノ粒子の合成と構造制御

2011 年度 研究成果報告書

• 研究課題/領域番号: 20310054
• 研究種目: 基盤研究(B)
• 配分区分: 補助金
• 応募区分: 一般
• 研究分野: ナノ構造科学
• 研究機関: 佐賀大学
• 研究代表者: 中島 謙一 佐賀大学, 工学系・研究科, 教授 (10104720)
• 研究分担者: 矢田 光徳 佐賀大学, 工学系・研究科, 准教授 (20274772)
• 研究期間 (年度): 2008 – 2011
• キーワード: ナノ構造化学

研究概要

本研究では、シリカ、チタニア、炭酸カルシウムなどさまざまな無機材料の中空ナノ粒子を数種の鋳型高分子を用いて合成し、われわれの方法(J. Am. Chem. Soc., 129, 1534(2007))が汎用的であることを立証した。さらに、得られた中空無機ナノ粒子を薬物送達や応用やリチウムイオン電池などへ応用した。

研究成果

• [雑誌論文] Synthesis of magneticα-Fe_2O_3 and Fe_3O_4 hollow nanospheres for sustained release of ibuprofen (2012)
  • 著者名/発表者名: Manickam Sasidharan, Hom Nath Luitel, Nanda Gunawardhana, Masamichi Inoue, Shin-ichi Yusa, Takanori Watari, Kenichi Nakashima
  • 雑誌名: Mater. Lett. 巻: Vol.73 ページ: 4-7
  • 査読あり
• [雑誌論文] CeO_2 hollow nanospheres as anode material for lithium ion batteries (2012)
  • 著者名/発表者名: Sasidharan Manickam, Nanda Gunawardhana, Masaki Yoshio, and Kenichi Nakashima
  • 雑誌名: Chem. Lett. 巻: Vol.41 ページ: 386-388
  • 査読あり
• [雑誌論文] WO_3 hollow nanospheres for high-lithium storage capacity and good cyclability (2012)
  • 著者名/発表者名: Manickam Sasidharan, Nanda Gunawardhana, Masaki Yoshio and Kenichi Nakashima
  • 雑誌名: Nano Energy 巻: Vol.1 ページ: 503-508
  • 査読あり
• [雑誌論文] Novel MoO_3 and WO_3 Hollow Nanospheres Assembled with Polymeric Micelles (2012)
  • 著者名/発表者名: Jing Jing Liu, Manickam Sasidharan, Dian Liu, Yuuichi Yokoyama, Shin-ichi Yusa, and Kenichi Nakashima
  • 雑誌名: Mater. Lett. 巻: Vol.66 ページ: 25-28
  • 査読あり
• [雑誌論文] Incorporation and release behavior of amitriptylene in core-shell-corona type triblock copolymer micelles (2011)
  • 著者名/発表者名: Bishnu Prasad Bastakoti, Sudhina Guragain, Yuuichi Yokoyama, Shin-ichi Yusa, Kenichi Nakashima
  • 雑誌名: Colloids Surf. B : Biointerfaces 巻: Vol.88 ページ: 734-740
  • 査読あり
• [雑誌論文] Periodic Organosilica Hollow Nanospheres as Anode Materials for Lithium Ion Rechargeable Batteries (2011)
  • 著者名/発表者名: Manickam Sasidharan, Kenichi Nakashima, Nanda Gunawardhana, Toshiyuki Yokoi, Masanori Ito, Masamichi Inoue, Shin-ichi Yusa, Masaki Yoshio, and Takashi Tatsumi
  • 雑誌名: Nanoscale 巻: Vol.3 ページ: 4768-4773
  • 査読あり
• [雑誌論文] Novel synthesis of bifunctional catalysts with different microenvironments (2011)
  • 著者名/発表者名: Manickam Sasidharan, Satoru Fujita, Masataka Ohashi, Yasutomo Goto, Kenichi Nakashima, and Shinji Inagaki
  • 雑誌名: Chem. Commun. 巻: Vol.47 ページ: 10422-10424
  • 査読あり
• [雑誌論文] Synthesis, characterization and application for lithium-ion rechargeable batteries of hollow silica nanospheres (2011)
  • 著者名/発表者名: Manickam Sasidharan, Dian Liu, Nanda Gunawardhana, Masaki Yoshio, and Kenichi Nakashima
  • 雑誌名: J. Mater. Chem. 巻: Vol.21 ページ: 13881-13888
  • 査読あり
• [雑誌論文] Micelles of poly(styrene-b-2-vinylpyridine-b-ethylene oxide) with blended Polystyrene core and their application to the synthesis of hollow silica nanospheres (2011)
  • 著者名/発表者名: Dian Liu, Manickam Sasidharan and Kenichi Nakashima
  • 雑誌名: J. Colloid Interface Sci. 巻: Vol.358 ページ: 354-359
  • 査読あり
• [雑誌論文] Novel titania hollow nanospheres of size 28±1 nm using soft-template and their application for lithium-ion rechargeable batteries (2011)
  • 著者名/発表者名: Manickam Sasidharan, Kenichi Nakashima, Nanda Gunawardhana, Toshiyuki Yokoi, Masamichi Inoue, Shin-ichi Yusa, Masaki Yoshio, and Takashi Tatsumi
  • 雑誌名: Chem. Commun. 巻: Vol.47 ページ: 6921-6923
  • 査読あり
• [雑誌論文] Synthesis of Hollow CaCO3 Nanospheres Templated by Micelles of Poly(styrene-b-acrylic acid-b-ethylene glycol) in Aqueous Solutions (2011)
  • 著者名/発表者名: Bishnu Prasad Bastakoti, Sudhina Guragain, Yuuichi Yokoyama, Shin-ichi Yusa, and Kenichi Nakashima
  • 雑誌名: Langmuir 巻: Vol.27 ページ: 379-384
  • 査読あり
• [雑誌論文] Hybrid micelle Formation from Poly(ethylene oxide-b-sodium 2-acrylamido-1-propane sulfonate-b-styrene) and Fe^<3+> Ion in Aqueous Solution (2010)
  • 著者名/発表者名: B. P. Bastakoti, S. Guragain, Y. Yokoyama, S. Yusa, and K. Nakashima
  • 雑誌名: Colloid Polym. Sci. 巻: Vol.288 ページ: 991-996
  • 査読あり
• [雑誌論文] Stimuli-Induced Core-Corona Inversion of Micelles of Water Soluble Poly(sodium 2-(acryl amido)-2-methylpropanesulfonate-b-N-isopropyl acrylamide) (2010)
  • 著者名/発表者名: S. Guragain, B. P. Bastakoti, S. Yusa, and K. Nakashima
  • 雑誌名: Polymer 巻: Vol.51 ページ: 3181-3186
  • 査読あり
• [雑誌論文] Schizophrenic Micellization of Poly(ethylene oxide-b-methacrylic acid) Induced by Phosphate and Calcium ions (2010)
  • 著者名/発表者名: S. Guragain, B. P. Bastakoti, and K. Nakashima
  • 雑誌名: J. Colloid Interface. Sci. 巻: Vol.350 ページ: 63-68
  • 査読あり
• [雑誌論文] Synthesis of Hollow Silica Nanospheres Templated by Micelle of Poly(styrene-b-[ 3-(methacryloylamino) propyl] trimethylammonium chloride-b-ethylene oxide) (2010)
  • 著者名/発表者名: J. Liu, D. Liu, S. Manickam, Y. Yokoyama, S. Yusa, and K. Nakashima
  • 雑誌名: Chem. Lett. 巻: Vol.39 ページ: 584-585
  • 査読あり
• [雑誌論文] Complex Micelle Formation between Poly(ethylene oxide-b-N-methyl-2-vinyl pyridinium iodide) and Poly(methacrylic acid) (2010)
  • 著者名/発表者名: S. Guragain, B. Bastakoti, M. Hasegawa, K. Nakashima
  • 雑誌名: Colloid Surf. A 巻: Vol.363 ページ: 86-91
  • 査読あり
• [雑誌論文] Mixed Micelles of Poly(styrene-b-3-(methacryloylamino) propyltrimethylammonium chloride-b-ethylene oxide) and Anionic Amphiphiles in Aqueous Solutions (2010)
  • 著者名/発表者名: J. Liu, A. Yoneda, D. Liu, Y. Yokoyama, S. Yusa, and K. Nakashima
  • 雑誌名: Can. J. Chem. 巻: Vol.88 ページ: 208-216
  • 査読あり
• [雑誌論文] Micelle Formation of Poly(ethylene oxide-b-sodium 2-(acrylamido)-2-methyl-1-propane sulfonate-b-styrene) and Its Interaction with Dodecyl Trimethyl Ammonium Chloride and Dibucaine (2010)
  • 著者名/発表者名: B. P. Bastakoti, S. Guragain, A. Yoneda, Y. Yokoyama, S. Yusa, K. Nakashima
  • 雑誌名: Polym. Chem. 巻: Vol.1 ページ: 347-353
  • 査読あり
• [雑誌論文] Physicochemical Properties of Micelles of Poly(styrene-b-[ 3-(methacryloyl amino) propyl] trimethylammonium chloride-b-ethylene oxide) in Aqueous Solutions (2009)
  • 著者名/発表者名: J. Liu, D. Liu, Y. Yokoyama, S. Yusa, and K. Nakashima
  • 雑誌名: Langmuir 巻: Vol.25 ページ: 739-743
  • 査読あり
• [雑誌論文] Fine-Tuning of Cavity Size and Wall Thickness of Silica Hollow Nanoparticles by Templating Polymeric Micelles with Core-Shell-Corona Structure (2009)
  • 著者名/発表者名: D. Liu, A. Khanal, K. Nakashima, Y. Inoue, and M. Yada
  • 雑誌名: Chem. Lett. 巻: Vol.38 ページ: 130-131
  • 査読あり
• [雑誌論文] Hybrid Polymeric Micelles Based on Poly(styrene-b-2-vinyl-1-methylpyridinium iodide-b-ethylene oxide) and Tungstate (2009)
  • 著者名/発表者名: D. Liu, K. Nakashima, Z. Tuzar, and P. Stepanek
  • 雑誌名: Polym. J. 巻: Vol.41 ページ: 492-497
  • 査読あり
• [雑誌論文] Synthesis of Hollow Metal Oxide Nanospheres by Templating Polymeric Micelles with Core-Shell-Corona Architecture (2009)
  • 著者名/発表者名: D. Liu and K. Nakashima
  • 雑誌名: Inorg. Chem. 巻: Vol.48 ページ: 3898-3900
  • 査読あり
• [雑誌論文] V_2O_5 hollow nanospheres : A lithium intercalation host with good rate capability and capacity retention
  • 著者名/発表者名: Sasidharan Manickam, Nanda Gunawardhana, Masaki Yoshio, and Kenichi Nakashima
  • 雑誌名: J. Electrochem. Soc. 巻: (in press)
  • 査読あり
• [雑誌論文] La_2O_3 hollow nanospheres for high performance lithium-ion rechargeable batteries
  • 著者名/発表者名: Manickam Sasidharan, Nanda Gunawardhana, Masamichi Inoue, Shin-ichi Yusa, Masaki Yoshio, and Kenichi Nakashima
  • 雑誌名: Chem. Commun. 巻: (in press)
  • 査読あり
• [雑誌論文] α-Fe_2O_3 and Fe_3O_4 hollow nanospheres as high-capacity anode materials for rechargeable Li-ion batteries
  • 著者名/発表者名: Manickam Sasidharan, Nanda Gunawardhana, Masaki Yoshio, and Kenichi Nakashima
  • 雑誌名: Ionics 巻: (in press)
  • 査読あり
• [雑誌論文] Novel LaBO_3 Hollow Nanospheres of Size 34±2 nm Templated by Polymeric Micelles
  • 著者名/発表者名: Sasidharan Manickam, Nanda Gunawardhana, Hom Luitel, Toshiyuki Yokoi, Masamichi Inoue, Shin-ichi Yusa, Takanori Watari, Masaki Yoshio, Takashi Tatsumi, and Kenichi Nakashima
  • 雑誌名: J. Colloid Interface Sci. 巻: (in press)
  • 査読あり
• [雑誌論文] α-MoO_3 hollow nanospheres as an anode material for Li-ion battery
  • 著者名/発表者名: Manickam Sasidharan, Nanda Gunawardhana, Hiroaki Noma, Masaki Yoshio, and Kenichi Nakashima
  • 雑誌名: Bull. Chem. Soc. Jpn. 巻: (in press)
  • 査読あり
• [雑誌論文] Synthesis of Hollow BaSO_4 Nanospheres Templated by Core-Shell-Corona Type
  • 著者名/発表者名: Bishnu Bastakoti, Sudhina Guragain, Yuuichi Yokoyama, Shin-ichi Yusa, Kenichi Nakashima
  • 雑誌名: Polymeric Micelles, New J. Chem. 巻: (in press)
  • 査読あり
• [学会発表] Synthesis of WO_3 and MoO_3 hollow nanospheres templated by polymeric micelle with core-shell-corona structure (2010)
  • 著者名/発表者名: Kenichi Nakashima, Jingjing Liu, Dian Liu, Sasidharan Manickam, Yuuichi Yokoyama, Yusa, Shin-ichi
  • 学会等名: 2010 International Chemical Congress of Pacific Basin Societies
  • 発表場所: Honolulu, Hawaii, USA
  • 年月日: 20100000
• [学会発表] Synthesis of Hollow Calcite Nanosphere by Templating Polymeric Micelle with Core-Shell-Corona Structure (2010)
  • 著者名/発表者名: Bishnu Prasad Bastakoti, Sudhina Guragain, Airi Yoneda, Yuuichi Yokoyama, Shin-ichi Yusa, Kenichi Nakashima
  • 学会等名: 第47回化学関連支部合同九州大会
  • 発表場所: 北九州
  • 年月日: 20100000
• [学会発表] SYNTHESIS OF CaCO_3 AND BaCO_3 HOLLOW NANOSPHERES TEMPLATED BY POLYMERIC MICELLES WITH CORE-SHELL-CORONA STRUCTURE (2010)
  • 著者名/発表者名: Bishnu Prasad Bastakoti, Sudhina Guragain, Yuuichi Yokoyama, Shin-ichi Yusa, Kenichi Nakashima
  • 学会等名: 240th ACS National Meeting & Exposition
  • 発表場所: Boston, USA
  • 年月日: 20100000
• [学会発表] Micelles Formation of Poly(ethyleneoxide-b-sodium-2-(acrylamido)-2-methyl-1-propane sulphonate-b-styrene) and Its Interaction with Dibucaine (2010)
  • 著者名/発表者名: Bishnu Prasad Bastakoti, Sudhina Guragain, Airi Yoneda, Yuuichi Yokoyama, Shin-ichi, Yusa, Kenichi Nakashima
  • 学会等名: The 3rd International Kyushu Colloid Colloquium
  • 発表場所: Fukuoka
  • 年月日: 20100000
• [学会発表] Stimuli-induced micelle formation of block copolymers, International Symposium on Stimuli-Responsive Materials (2008)
  • 著者名/発表者名: Kenichi Nakashima
  • 学会等名: The University of Southern Mississippi
  • 発表場所: USA
  • 年月日: 20080000
• [図書] Micelles of Ionic Block Copolymers as Carriers and Nano-reactors for Ionic Molecules" in" Bottom-up Nanofabrication : Supramolecules, Self-Assemblies, and Organized Films (2009)
  • 著者名/発表者名: K. Nakashima and A. Khanal
  • 総ページ数: 385-406
  • 出版者: American Scientific Publishers, Valencia, California
• [備考]
  • URL: http://extwww.cc.saga-u.ac.jp/~nakashik/index.html