| 研究課題/領域番号 |
20K05590
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| 研究機関 | 国立研究開発法人物質・材料研究機構 |
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研究代表者 |
Shrestha L.Kumar 国立研究開発法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, 主幹研究員 (90588922)
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| 研究期間 (年度) |
2020-04-01 – 2023-03-31
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| キーワード | Hierarchical structure / Fullerene assemblies / Vapor Sensing |
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| 研究実績の概要 |
Successful fabrication of a novel molecularly-thin nitrogen-doped 2D fullerphene by the carbonization of assembled fullerene C60-ethylenediamine (EDA) thin film, which exhibits a hierarchically micro/mesoporous structure at its surfaces. N-doping of fullerphene is dominated by pyrrolic and quaternary nitrogen
atoms, which allow selective and repetitive adsorption and desorption of lowmolecular-weight carboxylic acid vapors through noncovalent interactions.
Furthermore, novel micron-sized two-dimensional self-assembled fullerene rosettes and rice-husk shaped fullerene crystals with micropore architecture showed high sensitivity to aliphatic acid vapors compared to the aromatic vapors.
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| 現在までの達成度 (区分) |
現在までの達成度 (区分)
2: おおむね順調に進展している
理由
The Covid-19 situation has improved and we could work in the lab smoothly.
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| 今後の研究の推進方策 |
Fabrication of morphology-controlled hierarchical micro/mesoporous fullerene crystals with high surface area and well-developed porosity and composite with metallic nanoparticles and their oxide to enhance the selectivity and sensitivity to the targeted vapors such as formaldehyde, toluene, and acid vapors.
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