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2020 年度 実施状況報告書

Developing novel p-type BiOX oxyhalides thin layer for stable and efficient CsPbI3 perovskite solar cells

研究課題

研究課題/領域番号 20K15385
研究機関桐蔭横浜大学

研究代表者

郭 章林  桐蔭横浜大学, 工学研究科, 特任研究員 (40869559)

研究期間 (年度) 2020-04-01 – 2022-03-31
キーワードperovskite solar cells / all-inorganic perovskite / high voltage / high efficiency
研究実績の概要

The target of this project is to developing high-performance and stable CsPbX3 perovskite solar cells. We have achieved the following results under the support of this project.
Firstly, a simple method of making an amorphous SnOx electron transporting layer was developed for improving the Voc of CsPbX3 solar cells. A record-high Voc of 1.41 V for CsPbI2Br (1.91 eV) solar cells with the efficiency of 15.53% was achieved.
Secondly, a new polymer PDTDT was synthesized and used as a dopant-free hole-transporting material, which boosted the efficiency of CsPbI2Br cells to 17.36%. The device performance (1 cm2 cell) was certified by AIST.
One paper was published in the Journal of American Chemistry Society and one more was submitted. One Japanese patent application was submitted.

現在までの達成度 (区分)
現在までの達成度 (区分)

2: おおむね順調に進展している

理由

There are two specific aims of this project: developing high-performance CsPbX3 cells and improving the stability of CsPbX3 cells.
In the first year, we were focusing on increasing the efficiency of CsPbX3 cells by developing an efficient electron transporting layer of SnOx and hole-transporting materials of PDTDT. The successful development of these two parts of the solar cell structure enabled us to achieve superb device performances including Voc and efficiency. In addition, the synthesized PDTDT is working as a dopant-free hole-transporting material, which is also benefiting the stability of CsPbX3 cells because it is free of hydrophilic dopants.
The results of the first year not only realized the aim of developing high-performance CsPbX3 cells but also, to some extent, promoted the progress in improving the stability of CsPbX3 cells.
The results of the first year will be utilized in the next step of developing Bi-based inorganic oxyhalides BiOX (X= I, F, Cl, Br) compounds to protect moisture-sensitive CsPbX3 perovskites.

今後の研究の推進方策

The next step of this project is to improve the stability of CsPbX3 solar cells.
Firstly, the developed amorphous SnOx and dopant-free polymer PDTDT will be continuously used in fabricating CsPbI3, CsPbI2.25Br0.75 and CsPbI2Br solar cells.
Secondly, as planned, we will study the method of constructing oxyhalides BiOX layer on top of perovskite film and study the effect of BiOX layer on the solar cell performance and stability.
The mechanism related to solar cell performance and stability will be elucidated.

次年度使用額が生じた理由

In the year 2020, our research activities were hindered by the COVID-19 because of the emergency declaration in Japan. We worked at home for more than two months on paperwork rather than experiments and all the conferences were canceled, postponed, or changed to online. Therefore, the actual expenditure in the year 2020 was less than planned. We want to use the left amount in the next fiscal year (2021) by ordering necessary chemicals in our experiments, participating in conferences to share our results.

  • 研究成果

    (4件)

すべて 2021 2020

すべて 雑誌論文 (1件) (うち査読あり 1件) 学会発表 (2件) (うち国際学会 2件、 招待講演 1件) 産業財産権 (1件)

  • [雑誌論文] VOC Over 1.4 V for Amorphous Tin-Oxide-Based Dopant-Free CsPbI2Br Perovskite Solar Cells2020

    • 著者名/発表者名
      Guo Zhanglin、Jena Ajay Kumar、Takei Izuru、Kim Gyu Min、Kamarudin Muhammad Akmal、Sanehira Yoshitaka、Ishii Ayumi、Numata Youhei、Hayase Shuzi、Miyasaka Tsutomu
    • 雑誌名

      Journal of the American Chemical Society

      巻: 142 ページ: 9725-9734

    • DOI

      10.1021/jacs.0c02227

    • 査読あり
  • [学会発表] VOC over 1.4 V for amorphous tin oxide-based dopant-free CsPbI2Br perovskite solar cells2021

    • 著者名/発表者名
      Guo Zhanglin
    • 学会等名
      Pacifichem 2021 Congress
    • 国際学会
  • [学会発表] Interfacial Engineering for High Voltage (>1.4V) Performance of Inorganic Perovskite Solar Cells2021

    • 著者名/発表者名
      Tsutomu Miyasaka
    • 学会等名
      2021 MRS Spring Meeting & Exhibit
    • 国際学会 / 招待講演
  • [産業財産権] 光電変換素子及び発電デバイス2021

    • 発明者名
      宮坂 力、郭 章林、アジェイ クマー ジェナ、武井 出
    • 権利者名
      宮坂 力、郭 章林、アジェイ クマー ジェナ、武井 出
    • 産業財産権種類
      特許
    • 産業財産権番号
      特願2021-053883

URL: 

公開日: 2021-12-27  

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