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2021 年度 実施状況報告書

Electrodeposition and Characterization of Atomic-Level Metal Clusters

研究課題

研究課題/領域番号 21K04827
研究機関東京工業大学

研究代表者

チャン ツォーフーマーク  東京工業大学, 科学技術創成研究院, 准教授 (10647069)

研究分担者 曽根 正人  東京工業大学, 科学技術創成研究院, 教授 (30323752)
研究期間 (年度) 2021-04-01 – 2024-03-31
キーワードElectrodeposition / Atomic Metal / Conductive Polymer / Catalyst / Biosensor
研究実績の概要

This project aims to develop an electrochemical method to manipulate metals atoms decorated on conjugated polymers. The works include continuous improvement in reliability of the electrochemical method, fundamental studies on properties of the atomic metal clusters decorated polymer, and application of the atomic metal clusters decorated polymer in electrochemical biosensors. In this fiscal year, three referred papers related to this project are published, and the project number is mentioned in the acknowledgement, and these three papers are involved the fundamental studies, and one is on the application as glucose sensors. Results obtained by the support of this project are also presented in 7 international and 2 domestic conferences.

現在までの達成度 (区分)
現在までの達成度 (区分)

2: おおむね順調に進展している

理由

Preparation of the atomic metal clusters decorated polymer materials is expected to be difficult, and improving the atomic electrodeposition process is a target in this project. We are in the process of developing a new generation of the equipment.

Despite the difficulty in preparation of the atomic metal clusters decorated polymer, we still manage to project valuable results to publish 3 referred papers and several presentations in international and domestic conferences.

Therefore, the progress is rather smooth and expected to be better in the new fiscal year.

今後の研究の推進方策

Completing second generation of the atomic electrodeposition equipment is critical in this project. This upgrade is almost complete in previous fiscal year, and it shall be completed in this fiscal year.

The research work has been on atomic gold clusters on polyaniline. The mechanism should be applicable to metals other than gold. In this new fiscal year, platinum or palladium will be studied.

By simulation, bandgap of the atomic gold decorated polyaniline is reported to be affected by the number of gold in a cluster. Direct evaluation of the bandgap will be evaluated in this year. Demonstrating the advantage as catalytic materials in biosensors is a target and will be continued.

  • 研究成果

    (14件)

すべて 2022 2021 その他

すべて 国際共同研究 (1件) 雑誌論文 (3件) (うち査読あり 3件、 オープンアクセス 2件) 学会発表 (10件) (うち国際学会 7件)

  • [国際共同研究] National Yang Ming Chiao Tung University(その他の国・地域)

    • 国名
      その他の国・地域
    • 外国機関名
      National Yang Ming Chiao Tung University
  • [雑誌論文] Supercritical carbon dioxide assisted co-electrodeposition of nickel-titanium dioxide composite film and the dispersity2022

    • 著者名/発表者名
      Chien Yu-An、Chen Chun-Yi、Sone Masato、Chang Tso-Fu Mark
    • 雑誌名

      The Journal of Supercritical Fluids

      巻: 181 ページ: 105495~105495

    • DOI

      10.1016/j.supflu.2021.105495

    • 査読あり
  • [雑誌論文] Development of polypyrrole/nano-gold composite for non-enzymatic glucose sensors2022

    • 著者名/発表者名
      Kawakami Hiroki、Ito Yuki、Chien Yu-An、Chen Chun-Yi、Chiu Wan-Ting、Chakraborty Parthojit、Nakamoto Takamichi、Sone Masato、Chang Tso-Fu Mark
    • 雑誌名

      Micro and Nano Engineering

      巻: 14 ページ: 100109~100109

    • DOI

      10.1016/j.mne.2022.100109

    • 査読あり / オープンアクセス
  • [雑誌論文] Sample size effect in Ni-TiO2 composites fabricated by supercritical CO2 emulsified CO-electroplating for miniaturized device2022

    • 著者名/発表者名
      Chien Yu-An、Chen Chun-Yi、Sone Masato、Chang Tso-Fu Mark
    • 雑誌名

      Micro and Nano Engineering

      巻: 15 ページ: 100135~100135

    • DOI

      10.1016/j.mne.2022.100135

    • 査読あり / オープンアクセス
  • [学会発表] アスコルビン酸センサのためのポリアニリン・原⼦⾦電極の開発2022

    • 著者名/発表者名
      岡本 奎祐, 川上 宙輝, CHIENYu-An, Pathojit Chakraborty, 中本⾼道, 曽根正⼈, Tso-Fu Mark Chang
    • 学会等名
      2022年応物理学会春季講演会
  • [学会発表] Fabrication and Characterization of Ultrahigh Strength Ni-TiO2 Composite Coatings Electroplated with Supercritical Carbon Dioxide Emulsified Electrolyte2022

    • 著者名/発表者名
      Yu-an Chien, Chun-Yi Chen, Masato Sone, Tso-Fu Mark Chang
    • 学会等名
      2022年応物理学会春季講演会
  • [学会発表] 非酵素型グルコースセンサーに向けたポリピロール・金ナノ粒子触媒電極の開発2021

    • 著者名/発表者名
      川上 宙輝, 伊藤 勇毅, Yu-An Chien, Wan-Ting Chiu, Parthojit Chakraborty, Chun-Yi Chen, Tso-Fu Mark Chang, 中本 高道, 曽根 正人
    • 学会等名
      第82回応用物理学会秋季学術講演会
  • [学会発表] Non-enzymatic Polypyrrole/Nano-Gold Composite Electrode for Glucose Oxidation2021

    • 著者名/発表者名
      Hiroki Kawakami, Yuki Ito, Yu-An Chien, Wan-Ting Chiu, Parthojit Chakraborty, Chun-Yi Chen, Tso-Fu Mark Chang, Takamichi Nakamoto, Masato Sone
    • 学会等名
      TACT2021 International Thin Films Conference
    • 国際学会
  • [学会発表] Polyaniline-Atomic Au Modified Platinum Electrode with Ionic Liquid As Configuration for Enhanced Electrochemical Sensing2021

    • 著者名/発表者名
      Parthojit Chakraborty, Hiroki Kawakami, Tso-Fu Mark Chang, Masato Sone, Takamichi Nakamoto
    • 学会等名
      IEEE Sensors 2021
    • 国際学会
  • [学会発表] Development of Polypyrrole/Gold Nanoparticle Composite Electrode for Electrochemical Sensor2021

    • 著者名/発表者名
      Hiroki Kawakami, Yuki Ito, Yu-An Chien, Wan-Ting Chiu, Parthojit Chakraborty, Chun-Yi Chen, Tso-Fu Mark Chang, Takamichi Nakamoto, Masato Sone
    • 学会等名
      Micro and Nano Engineering Conference 2021
    • 国際学会
  • [学会発表] Electro-co-deposition of Au-TiO2 Composites with Improved Mechanical Property toward Miniaturized Electronics2021

    • 著者名/発表者名
      Yu-An Chien, Tso-Fu Mark Chang, Chun-Yi Chen, Daisuke Yamane, Hiroyuki Ito, Katsuyuki Machida, Kazuya Masu, Masato Sone
    • 学会等名
      The 2021 International Chemical Congress of Pacific Basin Societies (Pacifichem 2021)
    • 国際学会
  • [学会発表] Supercritical Carbon Dioxide Assisted Co-Electrodeposition of TiO2 Nanoparticle Reinforced Ni Films2021

    • 著者名/発表者名
      Yu-An Chien, Chun-Yi Chen, Masato Sone, Tso-Fu Mark Chang
    • 学会等名
      30th Topical Meeting of the International Society of Electrochemistry
    • 国際学会
  • [学会発表] Nanoparticle Reinforced High Strength Ni-TiO2 Composite Film Electroplated by Supercritical Carbon Dioxide Assisted Method2021

    • 著者名/発表者名
      Yu-An Chien, Chun-Yi Chen, Masato Sone, Tso-Fu Mark Chang
    • 学会等名
      TACT2021 International Thin Films Conference
    • 国際学会
  • [学会発表] Co-Electrodeposition of TiO2 Nanoparticle Reinforced High Strength Ni Film Assisted by Supercritical Carbon Dioxide for Miniaturized Electronics2021

    • 著者名/発表者名
      Yu-An Chien, Chun-Yi Chen, Tso-Fu Mark Chang, Masato Sone
    • 学会等名
      Micro and Nano Engineering Conference 2021 (MNE2021)
    • 国際学会

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公開日: 2022-12-28  

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