高度な固体電気化学式ガスセンサ構築のための反応界面の設計・制御

2012 年度 研究成果報告書

• 研究課題/領域番号: 22350095
• 研究種目: 基盤研究(B)
• 配分区分: 補助金
• 応募区分: 一般
• 研究分野: 無機工業材料
• 研究機関: 九州大学
• 研究代表者: 三浦 則雄 九州大学, 産学連携センター, 教授 (70128099)
• 研究期間 (年度): 2010 – 2012
• キーワード: 固体電気化学 / ガスセンサ / 固体電解質 / 安定化ジルコニア / 自動車排ガス / 環境モニタリング / 揮発性有機化合物

研究概要

安定化ジルコニアをベース材料とした自動車排ガス監視用及び環境モニタリング用の高性能な固体電気化学式ガスセンサの構築を、酸化物系やナノ貴金属とのコンポジット系材料を用いた最適な検知極材料の探索、反応界面の微細構造や組成の設計および作動条件の最適化などにより行ない、特異的なガスセンシング機能を付与することができた

研究成果

• [雑誌論文] Sensing Characteristics of Aged Zirconia-based Hydrogen Sensor Utilizing Zn-Ta-based Oxide Sensing-electrode (2013)
  • 著者名/発表者名: S. A. Anggraini, M. Breedon, N. Miura
  • 雑誌名: Electrochemistry Communications 巻: 31 ページ: 133-136
  • DOI: DOI:10.1016/j.elecom.2013.03.028
  • 査読あり
• [雑誌論文] Augmenting H2Sensing Performance of YSZ-based Electrochemical Gas Sensors via the Application of Au Mesh and YSZ Coating (2013)
  • 著者名/発表者名: M. Breedon, N. Miura
  • 雑誌名: Sensors and Actuators B 巻: 182 ページ: 40-44
  • DOI: DOI:10.1016/j.snb.2013.02.108
  • 査読あり
• [雑誌論文] Stabilized Zirconia-based Sensor Utilizing SnO2-based Sensing Electrode with an Integrated Cr2O3 Catalyst Layer for Sensitive and Selective Detection of Hydrogen (2013)
  • 著者名/発表者名: M. Yamaguchi, S. A. Anggraini, Y. Fujio, T. Sato, M. Breedon, N. Miura
  • 雑誌名: International Journal of Hydrogen Energy 巻: 38 ページ: 305-312
  • DOI: DOI:10.1016/j.electacta.2011.08.108
  • 査読あり
• [雑誌論文] Fe-based Solid Reference Electrode Utilized in YSZ-based Oxygen Sensor (2013)
  • 著者名/発表者名: H. Jin, M. Breedon, Y. Tanaka, N. Miura
  • 雑誌名: ECS Electrochemistry Letters 巻: 2(1) ページ: B1-B3
  • DOI: DOI:10.1149/2.003301eel
  • 査読あり
• [雑誌論文] Zn-Ta-based oxide as a hydrogen sensitive electrode material for zirconia-based electrochemical gas sensors (2013)
  • 著者名/発表者名: S. A. Anggraini, M. Breedon, N. Miura
  • 雑誌名: Sensors and Actuators B (in press)
  • DOI: DOI:10.1016/j.snb.2012.09.038
  • 査読あり
• [雑誌論文] Potentiometric YSZ-based Sensors Using Zn-Ta-O-based Sensing Electrode for Selective H2Detection (2012)
  • 著者名/発表者名: S. A. Anggraini, M. Breedon, N. Miura
  • 雑誌名: ECS Transactions 巻: 50(12) ページ: 179-187
  • DOI: DOI:10.1149/05012.0179ecst
  • 査読あり
• [雑誌論文] Selectivity Enhancement of YSZ-based VOC Sensor Utilizing SnO2/NiO-SE via the Application of a Physical Gas-diffusion Barrier (2012)
  • 著者名/発表者名: T. Sato, M. Breedon, N. Miura
  • 雑誌名: ECS Transactions 巻: 50(12) ページ: 129-137
  • DOI: DOI:10.1149/05012.0129ecst
  • 査読あり
• [雑誌論文] C3H6Sensing Characteristics of Rod-type Yttria-stabilized Zirconia -based Sensor for ppb Level Environmental Monitoring Applications (2012)
  • 著者名/発表者名: Y. Suetsugu, T. Sato, M. Breedon, N. Miura
  • 雑誌名: Electrochimica Acta 巻: 73 ページ: 118-122
  • DOI: DOI:10.1016/j.electacta.2011.08.108
  • 査読あり
• [雑誌論文] Enhanced Response of High Temperature H2 Sensors via the Application of Micro-dimensional Gold Mesh (2012)
  • 著者名/発表者名: M. Breedon, N. Miura
  • 雑誌名: Proceedings of IMCS14 ページ: 1159-1162
  • DOI: DOI:10.5162/IMCS2012/P1.9.3
• [雑誌論文] Gas Selectivity Improvement of YSZ-based VOC Sensor via Application of Selective Catalytic Layer over Sensing-electrode (2012)
  • 著者名/発表者名: T. Sato, M. Breedon, N. Miura
  • 雑誌名: Proceedings of IMCS14 ページ: 566-568
  • DOI: DOI:10.5162/IMCS2012/6.5.2
• [雑誌論文] Sensitive and Selective Detection of Hydrogen Using YSZ-based Sensor with Zn-Ta-based Oxide Sensing-electrode (2012)
  • 著者名/発表者名: S. A. Anggraini, M. Breedon, N. Miura
  • 雑誌名: Proceedings of the 14th International Meeting on Chemical Sensors (IMCS14) ページ: 563-565
  • DOI: DOI:10.5162/IMCS2012/6.5.1
• [雑誌論文] Working Mechanism of Novel Mn-based Reference Electrode for Solid-state Electrochemical Gas Sensors (2012)
  • 著者名/発表者名: H. Jin, M. Breedon, V. V. Plashnitsa, N. Miura
  • 雑誌名: Journal of The Electrochemical Society 巻: 159(10) ページ: B801-B810
  • DOI: DOI:10.1149/2.035210jes
  • 査読あり
• [雑誌論文] Selective Hydrogen Detection at High Temperature by Using Yttria-stabilized Zirconia-based Sensor with Coupled Metal-oxide-based Sensing Electrodes (2012)
  • 著者名/発表者名: M. Yamaguchi, S. A. Anggraini, Y. Fujio, M. Breedon, V. V. Plashnitsa, N. Miura
  • 雑誌名: Electrochimica Acta 巻: 76 ページ: 152-158
  • DOI: DOI:10.1016/j.electacta.2012.04.126
  • 査読あり
• [雑誌論文] The Synthesis and Gas Sensitivity of CuO Micro-dimensional Structures Featuring a Stepped Morphology (2012)
  • 著者名/発表者名: M. Breedon, S. Zhuiykov, N. Miura
  • 雑誌名: Materials Letters 巻: 82 ページ: 51-53
  • DOI: DOI:10.1016/j.matlet.2012.05.024
  • 査読あり
• [雑誌論文] Improvement of Toluene Selectivity Via the Application of an Ethanol Oxidizing Catalytic Cell Upstream of a YSZ-based Sensor for Air Monitoring Applications (2012)
  • 著者名/発表者名: T. Sato, M. Breedon, N. Miura
  • 雑誌名: Sensors 巻: 12(4) ページ: 4706-4714
  • DOI: DOI:10.3390/s120404706
  • 査読あり
• [雑誌論文] Construction of Sensitive and Selective Zirconia-based CO Sensors Using ZnCr2O4-based Sensing Electrodes (2012)
  • 著者名/発表者名: Y. Fujio, V. V. Plashnitsa, M. Breedon, N. Miura
  • 雑誌名: Langmuir 巻: 28 ページ: 1638-1645
  • DOI: DOI:10.1021/la203935w
  • 査読あり
• [雑誌論文] Sensing Behavior of YSZ-based Amperometric NO2Sensors Consisting of Mn-based Reference-electrode and In2O3Sensing-electrode (2012)
  • 著者名/発表者名: H. Jin, M. Breedon, N. Miura
  • 雑誌名: Talanta 巻: 88 ページ: 318-323
  • DOI: DOI:10.1016/j.talanta.2011.10.047
  • 査読あり
• [雑誌論文] Fabrication and Evaluation of Room-temperature Type Solid-state Electrochemical Gas Sensor Utilizing Proton-conducting Membrane (2011)
  • 著者名/発表者名: D. Teraoka, M. Breedon, N. Miura
  • 雑誌名: Proceedings of CSS13 ページ: 143-144
• [雑誌論文] Sensing Performance of YSZ-based Mixed-potential-type Gas Sensors Utilizing Zn-Ta-based Oxide Sensing Electrodes, Proceedings of the 13th Cross Straits Symposium on Materials (2011)
  • 著者名/発表者名: S. A. Anggraini, M. Breedon, N. Miura
  • 雑誌名: Energy, and Environmental Sciences (CSS13) ページ: 39-40
• [雑誌論文] Stabilized Zirconia-based Planar Sensor Using Coupled Oxide (+Au) Electrodes for Highly Selective CO Detection (2011)
  • 著者名/発表者名: S. A. Anggraini, V. V. Plashnitsa, P. Elumalai, M. Breedon, N. Miura
  • 雑誌名: Sensors and Actuators B 巻: 160 ページ: 1273-1281
  • DOI: DOI:10.1016/j.snb.2011.09.062
  • 査読あり
• [雑誌論文] Stabilization of Sensing Performance for Mixed-potential-type Zirconia-based Hydrocarbon Sensor (2011)
  • 著者名/発表者名: Y. Fujio, V. V. Plashnitsa, P. Elumalai, N. Miura
  • 雑誌名: Talanta 巻: 85(1) ページ: 575-581
  • DOI: DOI:10.1016/j.talanta.2011.04.024
  • 査読あり
• [雑誌論文] Spontaneous Gradual Accumulation of Hexagonally-aligned Nano-silica on Gold Nanoparticles Embedded in Stabilized Zirconia: A Pathway from Catalytic to NH3-sensing Performance (2011)
  • 著者名/発表者名: V. V. Plashnitsa, P. Elumalai, Y. Fujio, T. Kawaguchi, N. Miura
  • 雑誌名: Nanoscale 巻: 3 ページ: 2286-2293
  • DOI: DOI:10.1039/c1nr10091b
  • 査読あり
• [雑誌論文] CO Sensing Characteristics of YSZ-based Planar Sensor Using Rh-sensing Electrode Composed of Tetrahedral Sub-micron Particles (2011)
  • 著者名/発表者名: V. V. Plashnitsa, S. A. Anggraini, N.Miura
  • 雑誌名: Electrochemistry Communications 巻: 13 ページ: 444-446
  • DOI: DOI:10.1016/j.elecom.2011.02.016
  • 査読あり
• [雑誌論文] Compact YSZ-rod-based Hydrocarbon Sensor Utilizing Metal-oxide Sensing-electrode and Mn-based Reference-electrode Combination (2011)
  • 著者名/発表者名: H. Jin, V. V. Plashnitsa, M. Breedon, N. Miura
  • 雑誌名: Electrochemical and Solid-State Letters 巻: 14(6) ページ: J23-J25
  • DOI: DOI:10.1149/1.3568883
  • 査読あり
• [雑誌論文] YSZ-based Sensor Using NiO Sensing Electrode for Detection of Volatile Organic Compounds in ppb Level (2011)
  • 著者名/発表者名: T. Sato, V. V. Plashnitsa, M. Utiyama, N. Miura
  • 雑誌名: Journal of The Electrochemical Society 巻: 158(6) ページ: J175-J178
  • DOI: DOI:10.1149/1.3573780
  • 査読あり
• [雑誌論文] Novel Solid-State Manganese Oxide-Based Reference Electrode for YSZ-Based Oxygen Sensors (2011)
  • 著者名/発表者名: N. Miura, H. Jin, R. Wama, S. Nakakubo, P. Elumalai, V. V. Plashnitsa
  • 雑誌名: Sensors and Actuators B 巻: 152(2) ページ: 261-266
  • DOI: DOI:10.1016/j.snb.2010.12.018
  • 査読あり
• [雑誌論文] Mn-Based Solid-State Reference-Electrode Utilized for Miniaturized YSZ-Based Gas Sensor, Proceedings of the 12th Cross Straits Symposium on Materials (2010)
  • 著者名/発表者名: H. Jin, R. Wama, V. V. Plashnitsa, N. Miura
  • 雑誌名: Energy, and Environmental Sciences ページ: 90-91
• [学会発表] Effect of Aging Process on Sensing Characteristics of YSZ-based Sensor Using Zn-Ta-based Oxide as Sensing Electrode for Selective H2Detection (2013)
  • 著者名/発表者名: Sri Ayu Anggraini
  • 学会等名: 第54回化学センサ研究発表会
  • 発表場所: 東北大学(宮城)
  • 年月日: 2013-03-29
• [学会発表] Zn-Ta-based oxides as sensing electrode material for YSZ-based potentiometric gas sensor aiming at sensitive and selective detection of H2 (2012)
  • 著者名/発表者名: Sri Ayu Anggraini
  • 学会等名: 第38回固体イオニクス討論会
  • 発表場所: 京都テルサ(京都)
  • 年月日: 2012-12-04
• [学会発表] Room-temperature Type Compact Solid-state Electrochemical Hydrogen Sensor (2012)
  • 著者名/発表者名: Daichi Teraoka
  • 学会等名: 9th-NCRS
  • 発表場所: Fukuoka Japan
  • 年月日: 2012-11-02
• [学会発表] Simulation of Toluene Sensitivity for YSZ-based Sensor Utilizing NiO Sensing-electrode (2012)
  • 著者名/発表者名: Tomoaki Sato
  • 学会等名: 9th-NCRS
  • 発表場所: Fukuoka Japan
  • 年月日: 2012-11-02
• [学会発表] The Adsorption of NO2Onto YSZ Surfaces (2012)
  • 著者名/発表者名: Michael Breedon
  • 学会等名: The 9th International Symposium on "Novel Carbon Resource Sciences"(9th-NCRS)
  • 発表場所: Fukuoka Japan
  • 年月日: 2012-11-02
• [学会発表] Potentiometric YSZ-based Sensors Using Zn-Ta-O-based Sensing Electrode for Selective H2Detection (2012)
  • 著者名/発表者名: Sri Ayu Anggraini
  • 学会等名: PRiME2012
  • 発表場所: Hawaii USA
  • 年月日: 2012-10-09
• [学会発表] Selectivity Enhancement of YSZ-based VOC Sensor Utilizing SnO2/NiO-SE via the Application of a Physical Gas-diffusion Barrier (2012)
  • 著者名/発表者名: Tomoaki Sato
  • 学会等名: Pacific Rim Meeting on Electrochemical and Solid-state Science(PRiME2012)
  • 発表場所: Hawaii USA
  • 年月日: 2012-10-09
• [学会発表] Gas Selectivity Improvement of YSZ-based VOC Sensor via Application of Selective Catalytic Layer over Sensing-electrode (2012)
  • 著者名/発表者名: Tomoaki Sato
  • 学会等名: IMCS14
  • 発表場所: Nuremberg Germany
  • 年月日: 2012-05-21
• [学会発表] Sensitive and Selective Detection of Hydrogen Using YSZ-based Sensor with Zn-Ta-based Oxide Sensing-electrode (2012)
  • 著者名/発表者名: Sri Ayu Anggraini
  • 学会等名: IMCS14
  • 発表場所: Nuremberg Germany
  • 年月日: 2012-05-21
• [学会発表] Enhanced Response of High Temperature H2 Sensors via the Application of Micro-dimensional Gold Mesh (2012)
  • 著者名/発表者名: Michael Breedon
  • 学会等名: The 14th International Meeting on Chemical Sensors (IMCS14)
  • 発表場所: Nuremberg Germany
  • 年月日: 2012-05-21
• [学会発表] YSZ-based Potentiometric /Amperometric Gas Sensor Utilizing a Mn-based Solid-state Reference-electrode (2011)
  • 著者名/発表者名: Han Jin
  • 学会等名: ACCS2011
  • 発表場所: Taipei Taiwan
  • 年月日: 2011-11-16
• [学会発表] Room-temperature Type Solid-state Electrochemical Gas Sensor Using Proton-conductor (2011)
  • 著者名/発表者名: Daichi Teraoka
  • 学会等名: ACCS2011
  • 発表場所: Taipei Taiwan
  • 年月日: 2011-11-16
• [学会発表] Effect of Gold Particle on Sensing Performance of Zirconia-based CO Sensor (2011)
  • 著者名/発表者名: Yuki Fujio
  • 学会等名: 9th Asian Conference on Chemical Sensors(ACCS2011)
  • 発表場所: Taipei Taiwan
  • 年月日: 2011-11-16
• [学会発表] Solid-state Electrochemical Gas Sensor for Selective Detection of Aromatic Hydrocarbons at ppb Levels (2011)
  • 著者名/発表者名: Tomoaki Sato
  • 学会等名: 62nd-ISE
  • 発表場所: Niigata Japan
  • 年月日: 2011-09-12
• [学会発表] Mixed-potential-type YSZ-based Gas Sensor Aiming at Selective Detection of Hydrogen (2011)
  • 著者名/発表者名: Mami Yamaguchi
  • 学会等名: 62nd Annual Meeting of the International Society of Electrochemistry(62nd-ISE)
  • 発表場所: Niigata Japan
  • 年月日: 2011-09-12
• [学会発表] Development of Mixed-potential-type YSZ-based Gas Sensors (2011)
  • 著者名/発表者名: Norio Miura
  • 学会等名: 18th International Conference on Solid State Ionics
  • 発表場所: Warsaw Poland
  • 年月日: 2011-07-03
• [学会発表] Room-temperature Type Solid-state Electrochemical Gas Sensor Using Proton-conductor (2011)
  • 著者名/発表者名: Daichi Teraoka
  • 学会等名: 7th-NCRS
  • 発表場所: Seoul Korea
  • 年月日: 2011-06-23
• [学会発表] Sensing Characteristics of Rod-type Compact YSZ-based Sensor for Detection of Propylene in ppb Level (2011)
  • 著者名/発表者名: Tomoaki Sato
  • 学会等名: The 7th International Symposium on "Novel Carbon Resource Sciences"(7th-NCRS)
  • 発表場所: Seoul Korea
  • 年月日: 2011-06-23
• [学会発表] YSZ-based Sensors Using Oxide Sensing Electrodes for Detection of Hydrocarbons in ppb Level (2011)
  • 著者名/発表者名: Tomoaki Sato
  • 学会等名: 9th-ISE
  • 発表場所: Turku Finland
  • 年月日: 2011-05-08
• [学会発表] Potentiometric/Amperometric Rod-type YSZ-based Gas Sensor Attached with Mn-based Reference-electrode (2011)
  • 著者名/発表者名: Han Jin
  • 学会等名: The 9th Spring Meeting of the International Society of Electrochemistry (9th-ISE)
  • 発表場所: Turku Finland
  • 年月日: 2011-05-08
• [学会発表] Development of High-performance Solid-state Electrochemical Gas Sensors with Multiple Applications in the Proposed Hydrogen Economy (2011)
  • 著者名/発表者名: Yuki Fujio
  • 学会等名: International HYDROGENIUS and I2CNER Joint Symposium
  • 発表場所: Fukuoka Japan
  • 年月日: 2011-02-03
• [学会発表] Mn-Based Solid-State Reference-Electrode Utilized for Miniaturized YSZ-Based Gas Sensor (2010)
  • 著者名/発表者名: Han Jin
  • 学会等名: The 12th Cross Straits Symposium on Materials, Energy, and Environmental Sciences
  • 発表場所: Pohang Korea
  • 年月日: 2010-11-17
• [学会発表] Zirconia-based Mixed-potential Type Sensor Aiming at Detection of Very Low Concentrations of VOCs in Air Environment (2010)
  • 著者名/発表者名: Tomoaki Sato
  • 学会等名: IMCS13
  • 発表場所: Perth Australia
  • 年月日: 2010-07-12
• [学会発表] The Attractiveness of Solid-State Electrochemical Gas Sensors (2010)
  • 著者名/発表者名: Norio Miura
  • 学会等名: IMCS13
  • 発表場所: Perth Australia
  • 年月日: 2010-07-12
• [学会発表] Stabilization of Gas Response of Zirconia-based Sensor Using Composite Sensing Electrodes (2010)
  • 著者名/発表者名: Vladimir V. Plashnitsa
  • 学会等名: IMCS13
  • 発表場所: Perth Australia
  • 年月日: 2010-07-12
• [学会発表] CO Sensing Characteristics of Zirconia-based Sensor attached with ZnCr2O4(+ noble metal) Sensing-electrode (2010)
  • 著者名/発表者名: Yuki Fujio
  • 学会等名: The 13th International Meeting on Chemical Sensors (IMCS13)
  • 発表場所: Perth Australia
  • 年月日: 2010-07-12
• [学会発表] Mixed-potential -type Planar YSZ-based Carbon Monoxide Sensor Using a Couple of Oxide(+Au) Electrodes (2010)
  • 著者名/発表者名: Sri Ayu Anggraini
  • 学会等名: ACEC2010
  • 発表場所: Kumamoto Japan
  • 年月日: 2010-05-20
• [学会発表] Mechano -chemical Approach for Fabrication of Nano-structured NiO Sensing Electrode Used in Zirconia Based NO2 Sensor (2010)
  • 著者名/発表者名: Vladimir V. Plashnitsa
  • 学会等名: 7th Asian Conference on Electrochemistry (ACEC2010)
  • 発表場所: Kumamoto Japan
  • 年月日: 2010-05-20