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2022 年度 実施状況報告書

New Malonamide Polyethoxylated Surfactant for Eco-friendly Ion Foam Flotation Process

研究課題

研究課題/領域番号 22K20487
研究機関国立研究開発法人日本原子力研究開発機構

研究代表者

Micheau Cyril  国立研究開発法人日本原子力研究開発機構, 原子力科学研究部門 原子力科学研究所 物質科学研究センター, 博士研究員 (70961291)

研究期間 (年度) 2022-08-31 – 2024-03-31
キーワードFlotation / Malonamide / Foam / Interface / Synthesis
研究実績の概要

This work aims to develop a new surfactant system for the extraction and separation of rare earth elements and/or platinum group metals using the ion foam flotation process. For this purpose, synthesis and characterisation of a new malonamide polyethoxylated surfactant is consider. For the synthesis, two main routes are planned: (i) esterification between the polyethoxylated carboxylic acid surfactant AKYPO LS-O90 and the N(1), N(3)-Bis(2-hydroxyethyl)malonamide, and (ii) alkylation between malonamide molecule and the polyethoxylated alcohol surfactant BrijO10 (or Brij S10). Reactants have been ordered and received, and the characterisation of surfactants were performed in term of purity, pKa and micelle surface charge. Additional synthesis routes are being consider in order to reduce reactant cost and synthesis steps. For the characterisation of the process in term of flotation efficiency and microstructure through SANS and NR analyses, dedicated columns (and flowmter) were designed, ordered and received. Technical feasibility of SANS experiments on foam with the new column has been demonstrated with a model surfactant system. NR measurement on malonamide standard systems has been performed at J-PARC, MLF, as a preliminary experiment and had demonstrated the feasibility of analysing liquid-air interfaces. Finally, these preliminary analyses allowed redacting and submitting two articles in peer reviewed journal.

現在までの達成度 (区分)
現在までの達成度 (区分)

3: やや遅れている

理由

Synthesis of the new surfactant system has not been completed yet due to delay and unavailability of the reactants.

今後の研究の推進方策

Future work will focus on the synthesis of the surfactant system and its characterisation (purity, pKa, cmc, foaming properties). NR experiments on surfactant systems (Akypo LS-O90 and Brij O10) are planned from at J-PARC and will give basic data for the analysis of the new surfactant system after its synthesis. Business trip at ICSM (France) is planned during June, for surface tension measurement and foam analysis of the new surfactant system.

次年度使用額が生じた理由

New surfactant molecules will be synthesized by using the cost, i.e., B-A, in second year.

  • 研究成果

    (3件)

すべて 2023 その他

すべて 国際共同研究 (1件) 雑誌論文 (1件) (うち国際共著 1件、 査読あり 1件) 学会発表 (1件) (うち国際学会 1件、 招待講演 1件)

  • [国際共同研究] マルクール分離化学研究所(フランス)

    • 国名
      フランス
    • 外国機関名
      マルクール分離化学研究所
  • [雑誌論文] Deuterated Malonamide Synthesis for Fundamental Research on Solvent Extraction Systems2023

    • 著者名/発表者名
      Micheau Cyril、Ueda Yuki、Akutsu-Suyama Kazuhiro、Bourgeois Damien、Motokawa Ryuhei
    • 雑誌名

      Solvent Extraction and Ion Exchange

      巻: 41 ページ: 221~240

    • DOI

      10.1080/07366299.2023.2166351

    • 査読あり / 国際共著
  • [学会発表] Deuterated malonamide synthesis to probe interfacial mechanisms involved in solvent extraction process2023

    • 著者名/発表者名
      Cyril Micheau
    • 学会等名
      Deuterium Science Entering a New Phase (J-PARC Workshop)
    • 国際学会 / 招待講演

URL: 

公開日: 2023-12-25  

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