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2023 年度 実績報告書

New Malonamide Polyethoxylated Surfactant for Eco-friendly Ion Foam Flotation Process

研究課題

研究課題/領域番号 22K20487
研究機関国立研究開発法人日本原子力研究開発機構

研究代表者

Micheau Cyril  国立研究開発法人日本原子力研究開発機構, 原子力科学研究部門 原子力科学研究所 物質科学研究センター, 博士研究員 (70961291)

研究期間 (年度) 2022-08-31 – 2024-03-31
キーワードFlotation / Malonamide / Foam / Interface / Synthesis
研究実績の概要

This work aims to develop a new surfactant system for the extraction and separation of rare earth elements and/or platinum group metals using the ion foam flotation process. For this purpose, synthesis and characterisation of a new malonamide polyethoxylated surfactant is consider.
For the synthesis, two main routes are planned: (i) esterification between the polyethoxylated carboxylic acid surfactant AKYPO LS-O90 and the N(1), N(3)-Bis(2-hydroxyethyl)malonamide, and (ii) alkylation between malonamide molecule and the polyethoxylated alcohol surfactant BrijO10 (or Brij S10). Reactants have been ordered and received, and the characterisation of surfactants were performed in term of purity, pKa and micelle surface charge. Additional synthesis routes are being consider in order to reduce reactant cost and synthesis steps.
For the characterisation of the process in term of flotation efficiency and microstructure through SANS and NR analyses, dedicated columns (and flowmeter) were designed, ordered and received. Technical feasibility of SANS experiments on foam with the new column has been demonstrated with a model surfactant system. NR measurement on malonamide standard systems has been performed at J-PARC, MLF, as a preliminary experiment and had demonstrated the feasibility of analysing liquid-air interfaces.
Finally, the results obtained led to the publication of two articles in peer reviewed journal (Langmuir and J. Mol. Liq.) as well as press release in Japanese journals. This study opened new routes in separation chemistry and is a milestone for future projects.

  • 研究成果

    (3件)

すべて 2024 2023 その他

すべて 国際共同研究 (1件) 雑誌論文 (2件)

  • [国際共同研究] CEA/CNRS(フランス)

    • 国名
      フランス
    • 外国機関名
      CEA/CNRS
  • [雑誌論文] Organization of malonamides from the interface to the organic bulk phase2024

    • 著者名/発表者名
      Micheau Cyril、Ueda Yuki、Motokawa Ryuhei、Akutsu-Suyama Kazuhiro、Yamada Norifumi L.、Yamada Masako、Moussaoui Sayed Ali、Makombe Elizabeth、Meyer Daniel、Berthon Laurence、Bourgeois Damien
    • 雑誌名

      Journal of Molecular Liquids

      巻: 401 ページ: 124372~124372

    • DOI

      10.1016/j.molliq.2024.124372

  • [雑誌論文] Foam Flotation of Clay Particles Using a Bifunctional Amine Surfactant2023

    • 著者名/発表者名
      Micheau Cyril、Ueda Yuki、Motokawa Ryuhei、Bauduin Pierre、Girard Luc、Diat Olivier
    • 雑誌名

      Langmuir

      巻: 39 ページ: 10965~10977

    • DOI

      10.1021/acs.langmuir.3c01213

URL: 

公開日: 2024-12-25  

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