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2023 年度 実施状況報告書

バイオマス由来炭素材料を用いたバイオマス改質水素製造用非貴金属触媒の開発

研究課題

研究課題/領域番号 22KF0034
配分区分基金
研究機関東北大学

研究代表者

冨重 圭一  東北大学, 工学研究科, 教授 (50262051)

研究分担者 GAI CHAO  東北大学, 工学研究科, 外国人特別研究員
研究期間 (年度) 2023-03-08 – 2025-03-31
キーワードBiomass / Steam reforming / Biochar / Catalysis / Tar
研究実績の概要

In fiscal year 2022, we deployed a series of biochar-based nanocatalysts towards a model reaction of steam reforming of methanol (SRM). As a proof of concept, we set out to explore, for the first time, a simple yet effective bifunctional system for SRM under harsh conditions. The combinations to achieve best SRM performance were successfully screened. Last year, we successfully used surface science experiments and first-principles calculations (e.g., HAADF-STEM, XAFS, TPSR, DFT) to reveal the catalyst structure and potential reaction mechanism for the enhanced catalysis. The paper is now under preparation. Besides, we have prepared a review about the engineering of biochar-supported metal catalysts for biomass tar elimination that is inseparably associated with the original research proposal.

現在までの達成度 (区分)
現在までの達成度 (区分)

2: おおむね順調に進展している

理由

Dr. Gai continued the research smoothly. The catalyst developed in fiscal year 2022 was characterized in this year, with various characterization methods in our lab and SPring-8 (he obtained his machine time by himself). The results will be published in a scientific journal soon.

今後の研究の推進方策

We will firstly submit the two papers after revision in the near future, and then focused on the experimental study of long-term stabilities of the established hydrochar-based bifunctional system for SRM under harsh conditions in this fiscal year.

  • 研究成果

    (5件)

すべて 2023

すべて 学会発表 (5件) (うち国際学会 3件、 招待講演 1件)

  • [学会発表] Engineering of hydrochar-based functional materials for catalytic biomass conversion2023

    • 著者名/発表者名
      Chao Gai
    • 学会等名
      National Conference on Energy Chemistry Conference
  • [学会発表] Steering biomass waste into value-added biofuels under facile condition by hydrochar-based nanocatalysts2023

    • 著者名/発表者名
      Chao Gai
    • 学会等名
      International Symposium for the 80th Anniversary of the Tohoku Branch of the Chemical Society of Japan
    • 国際学会 / 招待講演
  • [学会発表] Structure-property relationships of hydrochar-based nanocatalyst in promoting tar forming under mild conditions2023

    • 著者名/発表者名
      Chao Gai
    • 学会等名
      6th National Conference on Biochar Research and Application
  • [学会発表] Hydrochar-based nanomaterials as platforms for energy and environmental applications2023

    • 著者名/発表者名
      Chao Gai
    • 学会等名
      International Conference on Carbon Resources to Chemicals
    • 国際学会
  • [学会発表] Hydrochar-based nanomaterials as platforms for energy and environmental applications2023

    • 著者名/発表者名
      Chao Gai
    • 学会等名
      9th Asia-Pacific Congress on Catalysis (APCAT-9)
    • 国際学会

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公開日: 2024-12-25  

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