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2022 年度 実績報告書

錯体ナノ空間が可能にする窒素含有ラダー高分子の精密合成と機能開拓

研究課題

研究課題/領域番号 22J14553
配分区分補助金
研究機関東京大学

研究代表者

ZHANG Xiyuan  東京大学, 新領域創成科学研究科, 特別研究員(DC2)

研究期間 (年度) 2022-04-22 – 2024-03-31
キーワードPolyacrylonitrile / Metal-Organic Frameworks / Ladder polymer
研究実績の概要

This research proposal aims to explore the synthesis and potential applications of nitrogen-doped conjugated ladder polymers (LPs) within coordination nanochannels. Nitrogen-doped conjugated LPs are anticipated to exhibit promising optical and electronic properties due to their extended conjugated and doped structures. However, LPs synthesized using traditional methods inevitably suffer from defects, such as crosslinking and single-stranded bonds, limiting their applicability. In this study, I propose to synthesize defect-free LPs within coordination nanochannels using Metal-Organic Frameworks (MOFs). The confined nanochannels could prevent interchain interaction and facilitate the extension of polymer chains promoting the formation of long conjugated defect-free LPs. After the synthesis of LPs, I will also explore methods for solubilizing and processing them using deep eutectic solvent (DES). Based on the dissolution, I will investigate the physical properties of the defect-free LPs and explore their potential in device fabrication.

現在までの達成度 (区分)
現在までの達成度 (区分)

1: 当初の計画以上に進展している

理由

This research focuses on the synthesis and potential applications of nitrogen-doped conjugated ladder polymers (LPs) within the coordination nanochannels of Metal-Organic Frameworks (MOFs). In 2022, I successfully completed a project on the "Thermal transformation of polyacrylonitrile accelerated by the formation of ultrathin nanosheets in MOFs." This project resulted in the synthesis of a unimolecularly thick 2D-PAN nanosheet, which exhibited good solubility in organic solvents. Using this 2D-PAN nanosheet, 2D-LP was synthesized, displaying high aromaticity and long conjugation due to the unique conformation of 2D-PAN. Consequently, carbon materials derived from 2D-LP also exhibited high structural regularity. These results suggest that the obtained 2D-LP holds great promise for device applications. Moving forward, I plan to investigate methodologies for processing defect-free LPs, further expanding their potential applications.

今後の研究の推進方策

The application of the obtained LPs has been challenging due to their large molecular size and rigid backbone, which prevent them from dissolving in traditional organic solvents. To overcome this difficulty, I plan to explore methods for solubilizing and processing LPs. This year, I will investigate the use of deep eutectic solvents (DES) as a potential solvent for LPs, as their hydrogen bond interactions and Coulomb interactions may facilitate dissolution. To study the solution properties of LPs, I will conduct measurements using IR, UV-Vis, and DLS techniques. Once the LPs are dissolved, I aim to perform electrochemical deposition to fabricate thin films. Following this step, I will employ Raman, SEM, AFM, and GIXRD to evaluate the quality and characteristics of the resulting thin films. By addressing these challenges, I hope to expand the potential applications of LPs and unlock their full potential.

  • 研究成果

    (3件)

すべて 2023 2022

すべて 雑誌論文 (2件) (うち査読あり 2件) 学会発表 (1件)

  • [雑誌論文] Thermal Transformation of Polyacrylonitrile Accelerated by the Formation of Ultrathin Nanosheets in a Metal?Organic Framework2023

    • 著者名/発表者名
      Xiyuan Zhang, Takashi Kitao, Ami Nishijima, Takashi Uemura
    • 雑誌名

      ACS Macro Letters

      巻: 12 ページ: 415~420

    • DOI

      10.1021/acsmacrolett.3c00072

    • 査読あり
  • [雑誌論文] Nanoconfined synthesis of conjugated ladder polymers2022

    • 著者名/発表者名
      Takashi Kitao, Xiyuan Zhang, Takashi Uemura
    • 雑誌名

      Polymer Chemistry

      巻: 13 ページ: 5003~5018

    • DOI

      10.1039/D2PY00809B

    • 査読あり
  • [学会発表] Fabrication of ultrathin polyacrylonitrile nanosheet using metal-organic framework2022

    • 著者名/発表者名
      Xiyuan Zhang, Ami Saito, Takashi Kitao, Takashi Uemura
    • 学会等名
      第71回高分子学会年次大会

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公開日: 2023-12-25  

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