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2023 年度 実施状況報告書

Novel group-IV nitride films by reactive sputtering as potential nonlinear optical materials in Si photonics

研究課題

研究課題/領域番号 23K03941
研究機関豊橋技術科学大学

研究代表者

PiedraLorenzana JoseAlberto  豊橋技術科学大学, 工学(系)研究科(研究院), 助教 (80909747)

研究分担者 石川 靖彦  豊橋技術科学大学, 工学(系)研究科(研究院), 教授 (60303541)
山根 啓輔  豊橋技術科学大学, 工学(系)研究科(研究院), 准教授 (80610815)
研究期間 (年度) 2023-04-01 – 2026-03-31
キーワードNitride materials / Silicon Photonics / Nonlinear Optics / Reactive Sputtering
研究実績の概要

In the first part of the project, we focused on the fabrication of the germanium nitride samples by RF sputtering. By x-ray diffraction and scanning electron microscopy and ellipsometry we have characterized the samples and observed the influence of the Sputtering power in the crystallographic quality of the samples. Particularly we observed a poor incorporation of the Nitrogen atoms at larger power values compared with Aluminum Nitride and Silicon Nitride, in order to solve this problem, we have changed the deposition conditions including the sputtering power and the germanium nitrogen rate deposition. With this we successfully achieved Germanium Nitride samples for 100 watts power.
Preliminary results of the optical characterization related to the band gap energy look promising.

現在までの達成度 (区分)
現在までの達成度 (区分)

2: おおむね順調に進展している

理由

In this project we have faced some unexpected difficulties in the preparation of the Germanium Nitride samples. From previous experience the Aluminum Nitride and Silicon Nitride deposition conditions are more flexible than the ones for successful Germanium Nitride within our equipment. From this we required a larger number of experiments focused on the growth deposition of Germanium Nitride. The first year of the project was expected to focus in the Germanium Nitride deposition which is going right on schedule.

今後の研究の推進方策

There are some depositions conditions that we are investigating in order to improve our results. We have studied low sputtering power conditions, but we are researching the lowest possible that the equipment is able to provide as the Argon Nitrogen rate.
The next part is the complete optical characterization which has already started.
For the last year of the research well continue with the etching procedure of the germanium nitride, considering similar material as aluminum nitride we had planned the etching conditions since there is not many information available for our material, and with this the fabrication of the optical ring resonator.

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公開日: 2024-12-25  

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