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2023 年度 実施状況報告書

Upcycling of Ca-rich residues after Fe recovery from steel slag into photocatalyst composites for H2 evolution and carbon negative

研究課題

研究課題/領域番号 23K17064
研究機関九州大学

研究代表者

CHUAICHAM CHITIPHON  九州大学, 工学研究院, 特任助教 (60875772)

研究期間 (年度) 2023-04-01 – 2025-03-31
キーワードCalcium oxalate / Fe-doped hydroxyapatite
研究実績の概要

Currently, iron oxalate dihydrate (abbreviated as FOD-ore) was synthesized from iron ore using a process involving oxalic acid for iron extraction, followed by photo-reduction. Various analytical techniques were employed to characterize the physicochemical properties of the FOD-ore sample. The FOD-ore was tested for its ability to catalyze the degradation of rhodamine B (RhB), a representative organic pollutant found in wastewater. The results revealed that the FOD-ore could degrade over 85% of RhB faster than that achieved with FOD alone. Additionally, the remaining calcium oxalate was used as a calcium source to produce Fe-doped hydroxyapatite as a photocatalyst. The obtained Fe-doped hydroxyapatite was characterized by several methods and will be used for photocatalytic H2 evolution.

現在までの達成度 (区分)
現在までの達成度 (区分)

2: おおむね順調に進展している

理由

This research project is advancing according to our strategy, which involves extracting calcium oxalate from slag and utilizing it as a calcium source to fabricate photocatalysts. Furthermore, we have employed these newly obtained photocatalysts to initiate the degradation of organic pollutants, marking the initial phase of assessing their photocatalytic effectiveness.

今後の研究の推進方策

Our next step involves creating a composite material by combining Fe-doped hydroxyapatite derived from slag with C3N4, which will then be utilized for testing its photocatalytic efficiency in hydrogen (H2) evolution. This experimentation aims to assess the performance of the synthesized samples in catalyzing the generation of hydrogen through photocatalysis. Additionally, we will explore various conditions and parameters during the composite fabrication process and H2 evolution testing to identify optimal conditions for maximizing the performance of the resulting sample.

次年度使用額が生じた理由

I will use it to prepare the system for H2 evolution via photocatalysis.

  • 研究成果

    (4件)

すべて 2023

すべて 雑誌論文 (3件) (うち国際共著 3件、 オープンアクセス 2件) 学会・シンポジウム開催 (1件)

  • [雑誌論文] Preparation of Iron Oxalate from Iron Ore and Its Application in Photocatalytic Rhodamine B Degradation2023

    • 著者名/発表者名
      Chuaicham Chitiphon、Shenoy Sulakshana、Trakulmututa Jirawat、Balakumar Vellaichamy、Santawaja Phatchada、Kudo Shinji、Sekar Karthikeyan、Sasaki Keiko
    • 雑誌名

      Separations

      巻: 10 ページ: 378~378

    • DOI

      10.3390/separations10070378

    • オープンアクセス / 国際共著
  • [雑誌論文] Enhancement of Photocatalytic Rhodamine B Degradation over Magnesium?Manganese Baring Extracted Iron Oxalate from Converter Slag2023

    • 著者名/発表者名
      Chuaicham Chitiphon、Trakulmututa Jirawat、Shenoy Sulakshana、Balakumar Vellaichamy、Santawaja Phatchada、Kudo Shinji、Sekar Karthikeyan、Sasaki Keiko
    • 雑誌名

      Separations

      巻: 10 ページ: 440~440

    • DOI

      10.3390/separations10080440

    • オープンアクセス / 国際共著
  • [雑誌論文] 3D/2D photocatalyst fabricated from Pt loading TiO2 nanoparticles and converter slag-derived Fe-doped hydroxyapatite for efficient H2 evolution2023

    • 著者名/発表者名
      Shu Kaiqian、Chuaicham Chitiphon、Sasaki Keiko
    • 雑誌名

      Chemical Engineering Journal

      巻: 477 ページ: 146994~146994

    • DOI

      10.1016/j.cej.2023.146994

    • 国際共著
  • [学会・シンポジウム開催] ACS Fall 20232023

URL: 

公開日: 2024-12-25  

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