| 研究実績の概要 |
Contracted porphyrinoides were tentatively studied to investigate new function and application-provability. Research on organic batteries continuing undergoes and provides promising results for future publications. Some are reported through an international conference (Pacifichem, Dec. 15~20, Honolulu).
Specific properties of micro-level molecules are tightly connected to the advanced functions of macro-level molecular materials. In recent, single molecular electoproperty on antiaromatic porphyrinoide has been examined to develop those practical application.
On the procedure, antiaromatic porphyrinoide exhibiting distinct chemical reactivity has been examined to interpret the molecular chemical properties and certain results obtained on the corresponding research have been submitted to journals for publication. One of them has been published in the last fiscal year (Angew. Chem. Int. Ed. 2015, 54, 8454-8457; Angew. Chem. 2015, 127, 8574-8577.)
Chemosensing capability was induced to bodipy molecule created with hemi-porphyrin and functionalized to have an ethynyl pyridine which can selectively capture various metal ions. The research has been done in a collaborative research and reported in a journal (J. Photochem. Photobiol. A: Chem. doi:10.1016/j.jphotochem.2015.08.015, In Press, The corrected proof is accessible).
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| 現在までの達成度 (区分) |
現在までの達成度 (区分)
2: おおむね順調に進展している
理由
Initial plans for 2015 followed by 2016 have been progressed and some results either were submitted to chemistry journals: Some were published and some are either in press or on preparation.
Most studies in the last fiscal year have aimed on the investigation of practical functional porphyrinoides toward appropriate applications. Several molecular candidates were prepared and their properties were examined. The molecular systems were studied on both micro (individual molecular level) and macro-level properties (intermolecular interaction to show macromolecular properties).
Compared to the earlier fiscal year, schedule adjustment on collaboration and experimental management little bit slower the progress, but smoothly undergoes to obtain promising results.
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