1986 年度実績報告書

有機化学における反応理論の体系化

研究課題

研究課題/領域番号	61303003
研究機関	九州大学
研究代表者	都野雄甫九大, 理学部, 教授 (10029845)
研究分担者	西本吉助大阪市立大学, 理学部, 教授 (20046949) 竹下斉九州大学, 生産研, 教授 (70004281) 速水醇一京都大学, 教養部, 教授 (30025283) 藤尾瑞枝九州大学, 理学部, 助手 (10029887) 三島正章九州大学, 理学部, 助手 (20037279)
キーワード	気相炭素陽イオン / イオンサイクロトロン共鳴(法) / 溶媒効果 / 置換基効果 / 基質-試薬会合錯体 / プロトン移動反応 / シグマトロピー / 芳香族求核置換反応
研究概要	1活性中間体とその反応挙動および構造-反応性相関関係:気相におけるベンジル陽イオン【C_6】【H_5】【CR2!〓】(R=【H_2】,MeH,【Me_2】,【CH_3】・【CF_3】)の本質的安定度を、イオンサイクロトロン共鳴法を用いてプロトン移動平衡およびクロライド移動平衡により決定し、各系の置換基効果の解析を行った。α-置換基によるカチオンの不安定化は、置換基効果の共鳴要求度の変化に明らかに現われ、その効果は溶液相におけるベンジル位ソルボリシスと全く同一の関係則(湯川-都野式)に従うことを見出した。これは200kcalにおよぶ溶媒和安定化が、遷移状態の相対座標位置にはほとんど変化を与えないことを意味し、従来の反応機構論からは想像できない重要な事実である。 2.分子間相互作用・溶媒効果:アミンを求核種とする芳香族求核置換反応において、非極性溶媒中では、基質-試薬間会合錯体が、反応座標に乗る真の中間体として介在し、イオン性中間体がイオン対として溶存する系では主反応が結果的に促進され、極性非プロトン性溶媒よりも加速されることを見出した。またプロトン移動が律速に関与するが、これは直接の律速関与ではなく、律速アニオン脱離の逆反応を抑えるF因子の制御と同じ意義を持つことを初めて示した。4.遷移状態構造・反応経路:トロポロンのベンジルエーテル及び複素環類似体は加熱によりラジカル転位を起すが、この反応の駆動力がトロポノイドの特異的共役構造による「1,9-シグマトロピー」という新概念で説明できることを証明した。プロトン移動反応に関して水素結合で相互作用が線形の場合、すなわち、それぞれの水素結合が独立にプロトン移動に関与する場合と、相互作用が非線形の場合、すなわち、それぞれの水素結合が協同的に働いてプロトン移動に関与する場合について研究を行ない、非線形相互作用の場合にはソリトン的プロトンが発生することを発見し、その方程式を導いた。

研究成果
(71件)

すべてその他

すべて文献書誌 (71件)

[文献書誌] Masaaki Mishima;Mizue Fujio;Yuho Tsuno: Tetrahedron Lett.27. 939-942 (1986)
[文献書誌] Masaaki Mishima;Mizue Fujio;Yuho Tsuno: Tetrahedron Lett.27. 951-954 (1986)
[文献書誌] Masami Sawada;Yoshio Takai;Satoshi Kimura;Soichi Misumi;Yuho Tsuno: Tetrahedron Lett.27. 3013-3016 (1986)
[文献書誌] TsunoMasami Sawada;Yoshio Takai;Satoshi Kimura;Satoshi Yamano;Soichi Misumi;Terukiyo Hanafusa;Yuho: Tetrahedron Lett.27. 5649-5650 (1986)
[文献書誌] Mizue Fujio;Kimito Funatsu;Mutsuo Goto;Masaaki Mishima;Yuho Tsuno: Bull.Chem.Soc.Jpn.60. 1091-1095 (1987)
[文献書誌] Mizue Fujio;Mutsuo Goto;Yoji Seki;Masaaki Mishima;Yuho Tsuno;Masami Sawada;Yoshio Takai: Bull.Chem.Soc.Jpn.60. 1097-1101 (1987)
[文献書誌] Takahiro Tezuka;Setsuo Ando;Toshinori Wada: Chemistry Letters. 1667-1670 (1986)
[文献書誌] Takahiro Tezuka;Setsuo Ando: Chemistry Letters. 1671-1674 (1986)
[文献書誌] Takahiro Tezuka;Takashi Otsuka;Pi-Chao Wang;Mie Murata: Tetrahedron Letters. 27. 3627-3630 (1986)
[文献書誌] Takahiro Tezuka;Takashi Otsuka: Tetrahedron Letters,submitted. (1987)
[文献書誌] J.Hayami;S.Otani;F.Yamaguchi;Y.Nishikawa: Chemistry Letters. 4 (1987)
[文献書誌] J.Hayami;K.Kinoshita: Chemistry Letters,to be submitted. 4 (1987)
[文献書誌] Kichisuke NISHIMOTO;H.FUKUNAGA;K.YAGI: J.Biochem.100. 1647-1653 (1986)
[文献書誌] Yoshiki KASHIMORI;F.CHIEN;K.NISHIMOTO: Chem.Phys.107. 389-396 (1986)
[文献書誌] Katsunori SAKURAI;K.KITAMURA;K.NISHIMOTO: Theor.Chim.Acta. 69. 23-34 (1986)
[文献書誌] Yoshihisa OHTA;H.TANAKA;Y.BABA;A.KAGEMOTO;N.NISHIMOTO: J.Phys.Chem.90. 4438-4442 (1986)
[文献書誌] Takae TAKEUCHI;M.YAMAMOTO;K.NISHIMOTO: Mass Spectrometry. 34. 267-298 (1986)
[文献書誌] M.Fujio;K.Funatsu;M.Goto;M.Mishima;Y.Tsuno: Tetrahedron. (1987)
[文献書誌] Kazuhiro Maruyama;Hiroyuki Furuta;Atsuhiro Osuka: Chemistry Letters. 475-478 (1986)
[文献書誌] Atsuhiro Osuka;Hiroyuki Furuta;Kazuhiro Maruyama: Chemistry Letters. 479-482 (1986)
[文献書誌] Kazuhiro Maruyama;Hiroyuki Furuta;Atsuhiro Osuka: Tetrahedron. 42. 6149-6155 (1986)
[文献書誌] Atsuhiro Osuka;Kazuhiro Maruyama: Chemistry Letters. 1853-1856 (1986)
[文献書誌] Atsuhiro Osuka;Soichi Morikawa;Kazuhiro Maruyama: J.Chemical Society,Chemical Communication. (1987)
[文献書誌] Tomomi KINOSHITA;Keizo IKAI;Tsugunori KASHIMURA;Masataka FUJIWARA;Kunio OKAMOTO: Bull.Chem.Soc.Jpn.59. 2843-2849 (1986)
[文献書誌] T.Fueno;T.Okuyama;H.Nagamatsu;M.Kitano: J.Org.Chem.51. 1516-1521 (1986)
[文献書誌] T.Fueno;T.Okuyama;M.Toyoda: Can.J.Chem.64. 1116-1123 (1986)
[文献書誌] T.Fueno: Applied Quantum Chemistry. 33-41 (1986)
[文献書誌] T.Fueno;H.Yamaguchi;Y.Takahara: Applied Quantum Chemistry. 155-184 (1986)
[文献書誌] T.Tsuji;S.Nishida: Chem.Lett.1389 (1986)
[文献書誌] R.Gleiter;G.Krennrich;P.Bischof;T.Tsuji;S.Nishida: Helv.Chim.Acta.69. 962 (1986)
[文献書誌] M.Murakami;T.Tsuji;M.Oda;S.Nishida: Chem.Lett.(1987)
[文献書誌] T.Tsuji;S.Nishida: J.Chem.Soc.,Chem.Commun.(1987)
[文献書誌] K.Ohta;G.L.Closs;K.Morokuma;N.J.Green: J.Am.Chem.Soc.108. 1319 (1986)
[文献書誌] Z.Latajka;W.B.Person;K.Morokuma: J.Mol.Str.135. 253 (1986)
[文献書誌] S.Sakai;K.Morokuma: J.Phys.Chem.(1987)
[文献書誌] N.Koga;T.Ozawa;K.Morokuma: J.Am.Chem.Soc.,submitted. 109. (1987)
[文献書誌] Masao OKUBO;Shunsei Yoshida;Yoshiji EGAMI;Koji MATSUO;Shigeru NAGASE: Bull.Chem.Soc.Jpn.,Vol.60,in press.
[文献書誌] Masao OKUBO;Toshiki TSUTSUMI;Koji MATSUO: Bull.Chem.Soc.Jpn.,Vol.60,in press.
[文献書誌] Masao OKUBO;Toshiki TSUTSUMI;Noritake YASUOKA;Yukiteru KATSUBE: Bull.Chem.Soc.Jpn.,in preparation.
[文献書誌] Masao OKUBO;Keiko ASAO;Hiroyuki HYAKUTAKE;Koji MATSUO.: Bull.Chem.Soc.Jpn.,in preparation.
[文献書誌] Y.Suezawa;Minoru Hirota;Y.Shibata;I.Takeuchi;Y.Hamada: Bull.Chem.Soc.Jpn.59. 2362-2364 (1986)
[文献書誌] K.Abe;K.Ito;Y.Suezawa;M.Hirota;M.Nishita: Bull.Chem.Soc.Jpn.59. 3125-3130 (1986)
[文献書誌] M.Karatsu;Y.Suezawa;K.Abe;M.Hirota;M.Nishio: Bull.Chem.Soc.Jpn.59. 3529-3534 (1986)
[文献書誌] K.Murofushi;K.Abe;M.Hirota: J.Chem.Soc.Perkin 【II】. (1987)
[文献書誌] H.Satonaka,K.Abe,M.Hirota: Bull.Chem.Soc.Jpn.60. (1987)
[文献書誌] K.Akiba;K.Takee;Y.Shimizu;K.Ohkata: J.Am.Chem.Soc.108. 6320-6327 (1986)
[文献書誌] K.Akiba;K.Okada;K.Ohkata: Tetrahedron Lett.27. 5221-5224 (1986)
[文献書誌] K.Akiba;H.Fujikawa;Y.Sunaguchi;Y.Yamamoto: J.Am.Chem.Soc.109. (1987)
[文献書誌] Hiroshi Yamataka;Terukiyo Hanafusa: J.Am.Chem.Soc.108. 6643-6646 (1986)
[文献書誌] Hiroshi Yamataka;Toyoki Matsuyama;Terukiyo Hanafusa: Chem.Lett.
[文献書誌] Terukiyo Hanafusa;Junko Ichihara;Tetsuya Ashida: Chem.Lett.
[文献書誌] T.Kawashima;Y.Miki;T.Tomita;N.Inamoto: Chem.Lett.501-504 (1986)
[文献書誌] N.Inamoto;S.Masuda: Chem.Lett.1287-1290 (1986)
[文献書誌] T.Kawashima;Y.Miki;N.Inamoto: Chem.Lett.1883-1884 (1986)
[文献書誌] Y.Nakadaira;T.Kobayashi;H.Sakurai: Bull.Chem.Soc.Jpn.59. 1509-1513 (1986)
[文献書誌] Y.Nakadaira;K.Oharu;H.Sakurai: J.Organomet.Chem.309. 247-256 (1986)
[文献書誌] A.Hosomi;M.Ando;H.Sakurai: Chem.Lett.365-368 (1986)
[文献書誌] H.Sakurai;M.Ando;N.Kawada;K.Sato;A.Hosomi: Tetrahedron Lett.27. 75-76 (1986)
[文献書誌] M.Kira;H.Nakazawa;H.Sakurai: Chem.Lett.497-450 (1986)
[文献書誌] H.Sakurai: l'actualite chim.26-32 (1986)
[文献書誌] Shigeru SUGIYAMA;Hitoshi TAKESHITA: Chemistry Letters. 1203-1204 (1986)
[文献書誌] Hitoshi Takeshita;Akira Mori;Tomoyuki Kusaba: Synthesis. 578-579 (1986)
[文献書誌] Hitoshi Takeshita;Hiroaki Mametsuka;Hideshi Motomura: Journal of Heterocyclic Chemistry. 23. 1211-1214 (1986)
[文献書誌] Shigeru Sugiyama;Tohru Tsuda;Akira Mori;Hitoshi Takeshita;Mitsuaki Kodama: Chemistry Letters. 1315-1318 (1986)
[文献書誌] Hitoshi Takeshita;Shigeru Sugiyama;Toshihide Hatsui: Journal of Chemical Society,Perkin Transaction,【II】. 1491-1493 (1986)
[文献書誌] Nobuo Kato;Shinya Tanaka;Hitoshi Takeshita: Chemistry Letters. 1989-1992 (1986)
[文献書誌] Yoho Tsuno;Akihisa Murata;Mutsuo Goto;Mizue Fujio: "Proceedings of the 8th IUPAC Conference on Physical Organic Chemistry,Tokyo 1986 Substituent Effect on the Solvolysis of 1-Aryl-1-(trifluoromethyl)ethyl Tosylates" Elsvier Publishers, 8 (1987)
[文献書誌] Yuho Tsuno: "Proceedings of the 1st International Symposium on Physical Organic Chemistry,Korea 1986 Varying Resonance Demands in Carbocationic Solvolyses" Korean Chemical Society, 14 (1987)
[文献書誌] Takahiro Tezuka;Setsuo Ando;Toshinori Wada: "8th IUPAC Conference on Physical Organic Chemistry(Tokyo),1986(Reaction of diazonium ions generated from α-azohydroperoxide)" Elsevier Science Publshers B.V., (1987)
[文献書誌] J.Hayami;S.Otani;S.Hashimoto: "Solute-Solvent Interactions in the Finkelstein Reaction System-Characterization of Chloride and Perchlorate Anion-" Elsevier Publishers, 6 (1987)
[文献書誌] T.Ando;T.Kimura;T.Yamataka: ""Variation in the Transistion-State Structure of Aliphatic Nucleophilic Substitution"in"Nucleophilicity"ed by J.M.Harris and S.P.McManus,Chapter7." American Chemical Society,

1986 年度 実績報告書

有機化学における反応理論の体系化

研究代表者

都野 雄甫 九大, 理学部, 教授 (10029845)

研究成果

[文献書誌] Masaaki Mishima;Mizue Fujio;Yuho Tsuno: Tetrahedron Lett.27. 939-942 (1986)

[文献書誌] Masaaki Mishima;Mizue Fujio;Yuho Tsuno: Tetrahedron Lett.27. 951-954 (1986)

[文献書誌] Masami Sawada;Yoshio Takai;Satoshi Kimura;Soichi Misumi;Yuho Tsuno: Tetrahedron Lett.27. 3013-3016 (1986)

[文献書誌] TsunoMasami Sawada;Yoshio Takai;Satoshi Kimura;Satoshi Yamano;Soichi Misumi;Terukiyo Hanafusa;Yuho: Tetrahedron Lett.27. 5649-5650 (1986)

[文献書誌] Mizue Fujio;Kimito Funatsu;Mutsuo Goto;Masaaki Mishima;Yuho Tsuno: Bull.Chem.Soc.Jpn.60. 1091-1095 (1987)

[文献書誌] Mizue Fujio;Mutsuo Goto;Yoji Seki;Masaaki Mishima;Yuho Tsuno;Masami Sawada;Yoshio Takai: Bull.Chem.Soc.Jpn.60. 1097-1101 (1987)

[文献書誌] Takahiro Tezuka;Setsuo Ando;Toshinori Wada: Chemistry Letters. 1667-1670 (1986)

[文献書誌] Takahiro Tezuka;Setsuo Ando: Chemistry Letters. 1671-1674 (1986)

[文献書誌] Takahiro Tezuka;Takashi Otsuka;Pi-Chao Wang;Mie Murata: Tetrahedron Letters. 27. 3627-3630 (1986)

[文献書誌] Takahiro Tezuka;Takashi Otsuka: Tetrahedron Letters,submitted. (1987)

[文献書誌] J.Hayami;S.Otani;F.Yamaguchi;Y.Nishikawa: Chemistry Letters. 4 (1987)

[文献書誌] J.Hayami;K.Kinoshita: Chemistry Letters,to be submitted. 4 (1987)

[文献書誌] Kichisuke NISHIMOTO;H.FUKUNAGA;K.YAGI: J.Biochem.100. 1647-1653 (1986)

[文献書誌] Yoshiki KASHIMORI;F.CHIEN;K.NISHIMOTO: Chem.Phys.107. 389-396 (1986)

[文献書誌] Katsunori SAKURAI;K.KITAMURA;K.NISHIMOTO: Theor.Chim.Acta. 69. 23-34 (1986)

[文献書誌] Yoshihisa OHTA;H.TANAKA;Y.BABA;A.KAGEMOTO;N.NISHIMOTO: J.Phys.Chem.90. 4438-4442 (1986)

[文献書誌] Takae TAKEUCHI;M.YAMAMOTO;K.NISHIMOTO: Mass Spectrometry. 34. 267-298 (1986)

[文献書誌] M.Fujio;K.Funatsu;M.Goto;M.Mishima;Y.Tsuno: Tetrahedron. (1987)

[文献書誌] Kazuhiro Maruyama;Hiroyuki Furuta;Atsuhiro Osuka: Chemistry Letters. 475-478 (1986)

[文献書誌] Atsuhiro Osuka;Hiroyuki Furuta;Kazuhiro Maruyama: Chemistry Letters. 479-482 (1986)

[文献書誌] Kazuhiro Maruyama;Hiroyuki Furuta;Atsuhiro Osuka: Tetrahedron. 42. 6149-6155 (1986)

[文献書誌] Atsuhiro Osuka;Kazuhiro Maruyama: Chemistry Letters. 1853-1856 (1986)

[文献書誌] Atsuhiro Osuka;Soichi Morikawa;Kazuhiro Maruyama: J.Chemical Society,Chemical Communication. (1987)

[文献書誌] Tomomi KINOSHITA;Keizo IKAI;Tsugunori KASHIMURA;Masataka FUJIWARA;Kunio OKAMOTO: Bull.Chem.Soc.Jpn.59. 2843-2849 (1986)

[文献書誌] T.Fueno;T.Okuyama;H.Nagamatsu;M.Kitano: J.Org.Chem.51. 1516-1521 (1986)

[文献書誌] T.Fueno;T.Okuyama;M.Toyoda: Can.J.Chem.64. 1116-1123 (1986)

[文献書誌] T.Fueno: Applied Quantum Chemistry. 33-41 (1986)

[文献書誌] T.Fueno;H.Yamaguchi;Y.Takahara: Applied Quantum Chemistry. 155-184 (1986)

[文献書誌] T.Tsuji;S.Nishida: Chem.Lett.1389 (1986)

[文献書誌] R.Gleiter;G.Krennrich;P.Bischof;T.Tsuji;S.Nishida: Helv.Chim.Acta.69. 962 (1986)

[文献書誌] M.Murakami;T.Tsuji;M.Oda;S.Nishida: Chem.Lett.(1987)

[文献書誌] T.Tsuji;S.Nishida: J.Chem.Soc.,Chem.Commun.(1987)

[文献書誌] K.Ohta;G.L.Closs;K.Morokuma;N.J.Green: J.Am.Chem.Soc.108. 1319 (1986)

[文献書誌] Z.Latajka;W.B.Person;K.Morokuma: J.Mol.Str.135. 253 (1986)

[文献書誌] S.Sakai;K.Morokuma: J.Phys.Chem.(1987)

[文献書誌] N.Koga;T.Ozawa;K.Morokuma: J.Am.Chem.Soc.,submitted. 109. (1987)

[文献書誌] Masao OKUBO;Shunsei Yoshida;Yoshiji EGAMI;Koji MATSUO;Shigeru NAGASE: Bull.Chem.Soc.Jpn.,Vol.60,in press.

[文献書誌] Masao OKUBO;Toshiki TSUTSUMI;Koji MATSUO: Bull.Chem.Soc.Jpn.,Vol.60,in press.

[文献書誌] Masao OKUBO;Toshiki TSUTSUMI;Noritake YASUOKA;Yukiteru KATSUBE: Bull.Chem.Soc.Jpn.,in preparation.

[文献書誌] Masao OKUBO;Keiko ASAO;Hiroyuki HYAKUTAKE;Koji MATSUO.: Bull.Chem.Soc.Jpn.,in preparation.

[文献書誌] Y.Suezawa;Minoru Hirota;Y.Shibata;I.Takeuchi;Y.Hamada: Bull.Chem.Soc.Jpn.59. 2362-2364 (1986)

[文献書誌] K.Abe;K.Ito;Y.Suezawa;M.Hirota;M.Nishita: Bull.Chem.Soc.Jpn.59. 3125-3130 (1986)

[文献書誌] M.Karatsu;Y.Suezawa;K.Abe;M.Hirota;M.Nishio: Bull.Chem.Soc.Jpn.59. 3529-3534 (1986)

[文献書誌] K.Murofushi;K.Abe;M.Hirota: J.Chem.Soc.Perkin 【II】. (1987)

[文献書誌] H.Satonaka,K.Abe,M.Hirota: Bull.Chem.Soc.Jpn.60. (1987)

[文献書誌] K.Akiba;K.Takee;Y.Shimizu;K.Ohkata: J.Am.Chem.Soc.108. 6320-6327 (1986)

[文献書誌] K.Akiba;K.Okada;K.Ohkata: Tetrahedron Lett.27. 5221-5224 (1986)

[文献書誌] K.Akiba;H.Fujikawa;Y.Sunaguchi;Y.Yamamoto: J.Am.Chem.Soc.109. (1987)

[文献書誌] Hiroshi Yamataka;Terukiyo Hanafusa: J.Am.Chem.Soc.108. 6643-6646 (1986)

[文献書誌] Hiroshi Yamataka;Toyoki Matsuyama;Terukiyo Hanafusa: Chem.Lett.

[文献書誌] Terukiyo Hanafusa;Junko Ichihara;Tetsuya Ashida: Chem.Lett.

[文献書誌] T.Kawashima;Y.Miki;T.Tomita;N.Inamoto: Chem.Lett.501-504 (1986)

[文献書誌] N.Inamoto;S.Masuda: Chem.Lett.1287-1290 (1986)

[文献書誌] T.Kawashima;Y.Miki;N.Inamoto: Chem.Lett.1883-1884 (1986)

[文献書誌] Y.Nakadaira;T.Kobayashi;H.Sakurai: Bull.Chem.Soc.Jpn.59. 1509-1513 (1986)

[文献書誌] Y.Nakadaira;K.Oharu;H.Sakurai: J.Organomet.Chem.309. 247-256 (1986)

[文献書誌] A.Hosomi;M.Ando;H.Sakurai: Chem.Lett.365-368 (1986)

[文献書誌] H.Sakurai;M.Ando;N.Kawada;K.Sato;A.Hosomi: Tetrahedron Lett.27. 75-76 (1986)

[文献書誌] M.Kira;H.Nakazawa;H.Sakurai: Chem.Lett.497-450 (1986)

[文献書誌] H.Sakurai: l'actualite chim.26-32 (1986)

[文献書誌] Shigeru SUGIYAMA;Hitoshi TAKESHITA: Chemistry Letters. 1203-1204 (1986)

[文献書誌] Hitoshi Takeshita;Akira Mori;Tomoyuki Kusaba: Synthesis. 578-579 (1986)

[文献書誌] Hitoshi Takeshita;Hiroaki Mametsuka;Hideshi Motomura: Journal of Heterocyclic Chemistry. 23. 1211-1214 (1986)

[文献書誌] Shigeru Sugiyama;Tohru Tsuda;Akira Mori;Hitoshi Takeshita;Mitsuaki Kodama: Chemistry Letters. 1315-1318 (1986)

[文献書誌] Hitoshi Takeshita;Shigeru Sugiyama;Toshihide Hatsui: Journal of Chemical Society,Perkin Transaction,【II】. 1491-1493 (1986)

[文献書誌] Nobuo Kato;Shinya Tanaka;Hitoshi Takeshita: Chemistry Letters. 1989-1992 (1986)

[文献書誌] Yoho Tsuno;Akihisa Murata;Mutsuo Goto;Mizue Fujio: "Proceedings of the 8th IUPAC Conference on Physical Organic Chemistry,Tokyo 1986 Substituent Effect on the Solvolysis of 1-Aryl-1-(trifluoromethyl)ethyl Tosylates" Elsvier Publishers, 8 (1987)

[文献書誌] Yuho Tsuno: "Proceedings of the 1st International Symposium on Physical Organic Chemistry,Korea 1986 Varying Resonance Demands in Carbocationic Solvolyses" Korean Chemical Society, 14 (1987)

[文献書誌] Takahiro Tezuka;Setsuo Ando;Toshinori Wada: "8th IUPAC Conference on Physical Organic Chemistry(Tokyo),1986(Reaction of diazonium ions generated from α-azohydroperoxide)" Elsevier Science Publshers B.V., (1987)

[文献書誌] J.Hayami;S.Otani;S.Hashimoto: "Solute-Solvent Interactions in the Finkelstein Reaction System-Characterization of Chloride and Perchlorate Anion-" Elsevier Publishers, 6 (1987)

[文献書誌] T.Ando;T.Kimura;T.Yamataka: ""Variation in the Transistion-State Structure of Aliphatic Nucleophilic Substitution"in"Nucleophilicity"ed by J.M.Harris and S.P.McManus,Chapter7." American Chemical Society,

1986 年度実績報告書

都野雄甫九大, 理学部, 教授 (10029845)