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2011 Fiscal Year Final Research Report

Development of High Performance Hybrid Ceramics by Atomic Scale Modification

Planned Research

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Project AreaNano Materials Science for Atomic Scale Modification
Project/Area Number 19053009
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research Institution一般財団法人ファインセラミックスセンター (2011)
Japan Fine Ceramics Center (2007-2010)

Principal Investigator

KITAOKA Satoshi  一般財団法人ファインセラミックスセンター, 材料技術研究所, 主席研究員 (80416198)

Co-Investigator(Kenkyū-buntansha) WADA Masashi  (財)ファインセラミックスセンター, 材料技術研究所, 上級研究員補 (30426506)
MATSUDAIRA Tsuneaki  (財)ファインセラミックスセンター, 材料技術研究所, 主席研究員 (10466287)
SASAKI Yukichi  (財)ファインセラミックスセンター, ナノ構造研究所, 主席研究員 (40426507)
MORIWAKE Hiroki  (財)ファインセラミックスセンター, ナノ構造研究所, 主席研究員 (40450853)
Co-Investigator(Renkei-kenkyūsha) SUGAWARA Yoshiyuki  早稲田大学, 理工学術院, 教授 (50196698)
OKAYASU Satoru  日本原子力研究開発機構, 原子力科学研究所, 研究主幹 (50354824)
KITA Hidetoshi  山口大学, 大学院・理工学研究科, 教授 (20304842)
Project Period (FY) 2007 – 2011
Keywords被膜 / アルミナ / 拡散 / 粒界 / ゼオライト / 粒子線照射 / 透過電子顕微鏡
Research Abstract

As a part of development of high performance hybrid ceramics by atomic scale modification, functions of dopants segregated at grain-boundaries of oxide protective layers that were formed on the heat resisting alloys was elucidated. The oxide layers with excellent grain-boundary diffusion barrier were designed to further improve the high-temperature durability of the alloys. Furthermore, a three-dimensional orientation of zeolite crystals that contain dopants acting as catalysts and adsorbents could be performed, and unique nano-structures in the crystals were produced by ion irradiation.

  • Research Products

    (35 results)

All 2012 2011 2010 2009 2008 Other

All Journal Article (10 results) (of which Peer Reviewed: 10 results) Presentation (19 results) Book (1 results) Remarks (1 results) Patent(Industrial Property Rights) (4 results)

  • [Journal Article] Oxygen Permeability in Cation- doped Polycrystalline Alumina under Oxygen Potential Gradients at High Temperatures2011

    • Author(s)
      T. Matsudaira, M. Wada, T. Saitoh, S. Kitaoka
    • Journal Title

      Acta Mater.

      Volume: 59 Pages: 5440-5450

    • DOI

      DOI:10.1016/j.actamat.2011.05.018

    • Peer Reviewed
  • [Journal Article] Mutual Grain-boundary Transport of Aluminum and Oxygen in Polycrystalline Al_2 O_3 under Oxygen Potential Gradients at High Temperatures2011

    • Author(s)
      M. Wada, T. Matsudaira, S. Kitaoka
    • Journal Title

      J. Ceram. Soc. Jpn.

      Volume: 119 Pages: 832-839

    • DOI

      DOI:10.2109/jcersj2.119.832

    • Peer Reviewed
  • [Journal Article] First- principles Calculations of Lattice Dynamics in CdTiO_3 and CaTiO_3 : Phase Stability and Ferroelectricity2011

    • Author(s)
      H. Moriwake, C. A. J. Fisher, A. Kuwabara, H. Taniguchi, M. Itoh, I. Tanaka
    • Journal Title

      Phys. Rev.

      Volume: B84 Pages: 104114

    • DOI

      DOI:10.1103/PhysRevB.84.104114

    • Peer Reviewed
  • [Journal Article] Mass Transfer through a Single Grain Boundary in Alumina Bicrystals under Oxygen Potential Gradients2011

    • Author(s)
      T. Matsudaira, S. Kitaoka, N. Shibata, T. Nakagawa, Y. Ikuhara
    • Journal Title

      J. Mater. Sci.

      Volume: 46 Pages: 4407-4412

    • DOI

      DOI:10.1007/s10853-010-5017-z

    • Peer Reviewed
  • [Journal Article] The Effect of Lutetium Dopant on Oxygen Permeability of Alumina Polycrystals under Oxygen Potential Gradients at Ultra-High Temperatures2010

    • Author(s)
      T. Matsudaira, M. Wada, T. Saitoh, S. Kitaoka
    • Journal Title

      Acta Mater.

      Volume: 58 Pages: 1544-1553

    • DOI

      DOI:10.1016/j.actamat.2009.10.062

    • Peer Reviewed
  • [Journal Article] Control of Polymorphism in Al_2O_3 Scale Formed by Oxidation of Alumina-Forming Alloys2010

    • Author(s)
      S. Kitaoka, T. Kuroyama, M. Matsumoto, R. Kitazawa, Y. Kagawa
    • Journal Title

      Corrosion Science

      Volume: 52 Pages: 429-434

    • DOI

      DOI:10.1016/j.corsci.2009.09.031

    • Peer Reviewed
  • [Journal Article] Mass-Transfer Mechanism of Alumina Ceramics under Oxygen Potential Gradients at High Temperatures2009

    • Author(s)
      S. Kitaoka, T. Matsudaira, M. Wada
    • Journal Title

      Mater. Trans.

      Volume: 50 Pages: 1023-1031

    • DOI

      DOI:10.2320/matertrans.MC200803

    • Peer Reviewed
  • [Journal Article] Formation of Ag Clusters by Election Beam Irradiation of Ag-Zeolites2009

    • Author(s)
      Y. Sasaki, T. Suzuki
    • Journal Title

      Mater. Trans.

      Volume: 50 Pages: 1050-1053

    • DOI

      DOI:10.2320/matertrans.MC200809

    • Peer Reviewed
  • [Journal Article] Modification of Perhydropolysilazane with Aluminum Hydride: Preparation of Poly(aluminasilazane)s and Their Conversion into Si-Al-N-C Ceramics2008

    • Author(s)
      R. Toyoda, S. Kitaoka, Y. Sugahara
    • Journal Title

      J. Eur. Ceram. Soc.

      Volume: 8(1) Pages: 271-277

    • DOI

      DOI:10.1016/j.jeurceramsoc.2007.06.001

    • Peer Reviewed
  • [Journal Article] Isostructural Phase Transitions of Tetragonal Perovskite Titanates under Negative Hydrostatic Pressure2008

    • Author(s)
      H. Moriwake, Y. Koyama, K. Matsunaga, T. Hirayama, I. Tanaka
    • Journal Title

      J. Phys: Condens. Matter

      Volume: 20 Pages: 345207

    • DOI

      DOI:10.1088/0953-8984/20/34/345207

    • Peer Reviewed
  • [Presentation] 多結晶 Al_2O_3中のAlとOの相互粒界拡散に及ぼす微量元素添加効果2012

    • Author(s)
      松平恒昭ら
    • Organizer
      日本セラミックス協会2012年年会
    • Place of Presentation
      京都大学
    • Year and Date
      2012-03-20
  • [Presentation] 高エネルギー重イオン照射を用いたゼオライト内への銀クラスター列の形成2011

    • Author(s)
      佐々木優吉ら
    • Organizer
      日本金属学会2011年秋期(第149回)大会
    • Place of Presentation
      沖縄コンベンションセンター・カルチャーリゾートフェストーネ
    • Year and Date
      2011-11-08
  • [Presentation] 機能元素修飾による酸化保護膜中の物質移動制御2011

    • Author(s)
      北岡諭ら
    • Organizer
      日本金属学会2011年秋期(第149回)大会
    • Place of Presentation
      沖縄コンベンションセンター・カルチャーリゾートフェストーネ
    • Year and Date
      2011-11-07
  • [Presentation] First-Principles Calculations of Ferroelectric Materials2011

    • Author(s)
      H. Moriwake et al.
    • Organizer
      PacRim 9 "The 9th International Meeting of Pacific Rim Ceramic Societies"
    • Place of Presentation
      Cairns, Australia
    • Year and Date
      2011-07-12
  • [Presentation] Mass-Transfer Mechanism of Cation-doped Polycrystalline Alumina under Oxygen Potential Gradients at High Temperatures2011

    • Author(s)
      T. Matsudaira et al.
    • Organizer
      DIMAT 8th Inter. Conf. on Diffusion in Materials
    • Place of Presentation
      Dijon, France
    • Year and Date
      2011-07-07
  • [Presentation] 多結晶アルミナの高温酸素遮蔽性に及ぼす微量元素配置効果2011

    • Author(s)
      松平恒昭ら
    • Organizer
      日本セラミックス協会2011年年会
    • Place of Presentation
      静岡大学
    • Year and Date
      2011-03-16
  • [Presentation] Effect of Dopant Configurations on Oxygen Permeation through Alumina Ceramics under Oxygen Potential Gradients at High Temperatures2010

    • Author(s)
      T. Matsudaira et al.
    • Organizer
      3rd International Congress on Ceramics (ICC3)
    • Place of Presentation
      大阪国際会議場
    • Year and Date
      2010-11-17
  • [Presentation] Grain Boundary Diffusion in alpha-Alumina under Oxygen Potential Gradients at High Temperatures2010

    • Author(s)
      T. Matsudaira et al.
    • Organizer
      iib2010
    • Place of Presentation
      志摩観光ホテル
    • Year and Date
      2010-06-28
  • [Presentation] 水溶性前駆体からの RePO_4(Re=Y, Lu)の合成2010

    • Author(s)
      杉山和宏ら
    • Organizer
      粉体粉末冶金協会平成22年度春季大会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2010-05-15
  • [Presentation] Effects of Doping Elements on Oxygen Permeability of Alumina Ceramics at Ultra-High Temperatures2010

    • Author(s)
      T. Matsudaira et al.
    • Organizer
      34rd Int. Conf. and Exp. on Advanced Ceramics and Composites
    • Place of Presentation
      Florida, USA
    • Year and Date
      2010-01-28
  • [Presentation] Oxygen Permeability of Alumina Ceramics under Oxygen Potential Gradients at Ultra-High Temperatures2009

    • Author(s)
      T. Matsudaira et al.
    • Organizer
      The 9th International Symposium on Ceramic Materials and Components for Energy and Environmental Applications
    • Place of Presentation
      Shanghai, China
    • Year and Date
      2009-11-12
  • [Presentation] 第一原理計算による強誘電体材料設計2009

    • Author(s)
      森分博紀
    • Organizer
      物理学会秋季大会
    • Place of Presentation
      熊本大学
    • Year and Date
      2009-09-26
  • [Presentation] 高温酸素ポテンシャル勾配下における Al_2O_3多結晶体中の物質移動に及ぼす添加元素の影響2009

    • Author(s)
      和田匡史ら
    • Organizer
      日本セラミックス協会第22回秋季シンポジウム
    • Place of Presentation
      愛媛大学
    • Year and Date
      2009-09-18
  • [Presentation] Agイオン交換ゼオライトへの粒子線照射によるAgクラスターの形成2009

    • Author(s)
      佐々木優吉ら
    • Organizer
      日本セラミックス協会秋季シンポジウム
    • Place of Presentation
      愛媛大学
    • Year and Date
      2009-09-18
  • [Presentation] Control of Polymorphism and Mass-transfer in Al_2O_3 Scale on Alumina Forming Alloys2009

    • Author(s)
      S. Kitaoka et al.
    • Organizer
      THERMEC
    • Place of Presentation
      Berlin, Germany
    • Year and Date
      2009-08-26
  • [Presentation] Oxygen Permeability of Undoped and Lutetia-doped Alumina Polycrystals under Oxygen Potential Gradients at Ultra-High Temperatures2009

    • Author(s)
      M. Wada et al.
    • Organizer
      33rd Int. Conf. and Exp. on Advanced Ceramics and Composites
    • Place of Presentation
      Florida, USA
    • Year and Date
      2009-01-19
  • [Presentation] 超高温におけるアルミナセラミックスの酸素透過性に及ぼす微量添加元素の影響2008

    • Author(s)
      松平恒昭ら
    • Organizer
      日本金属学会2008年秋季(第143回)大会
    • Place of Presentation
      熊本大学
    • Year and Date
      2008-09-25
  • [Presentation] TBC 合金結合層の予備酸化により生成するAl_2O_3保護膜の多形制御2008

    • Author(s)
      北岡諭ら
    • Organizer
      日本セラミックス協会第21回秋季シンポジウム
    • Place of Presentation
      北九州国際会議場
    • Year and Date
      2008-09-19
  • [Presentation] 粒子線照射によるゼオライトのナノ加工2008

    • Author(s)
      佐々木優吉
    • Organizer
      日本金属学会2008年春期(第142回)大会
    • Place of Presentation
      武蔵工業大学
    • Year and Date
      2008-03-27
  • [Book] Control of Polymorphism and Mass- Transfer in Al_2O_3 Scale Formed by Oxidation of Alumina-Forming Alloys”, Mass Transfer in Multiphase Systems and its Applications, edited by Mohamed El-Amin2011

    • Author(s)
      S. Kitaoka, T. Matsudaira, M. Wada
    • Total Pages
      343-366
    • Publisher
      InTech.
  • [Remarks]

    • URL

      http://www.jfcc.or.jp/

  • [Patent(Industrial Property Rights)] 金属酸化膜, 酸素センサ, 酸素透過膜及び固体酸化物燃料電池2010

    • Inventor(s)
      松平恒昭, 北岡諭, 和田匡史
    • Industrial Property Rights Holder
      (財)ファインセラミックスセンター
    • Industrial Property Number
      特許,特願 2010-150147
    • Filing Date
      2010-06-30
  • [Patent(Industrial Property Rights)] アルミナ薄膜形成用材料及び耐熱部材2009

    • Inventor(s)
      松平恒昭, 北岡諭, 和田匡史
    • Industrial Property Rights Holder
      (財)ファインセラミックスセンター
    • Industrial Property Number
      特許,特願 2009-152905
    • Filing Date
      2009-06-26
  • [Patent(Industrial Property Rights)] ゼオライト及びその製造方法2009

    • Inventor(s)
      佐々木優吉, 岡安悟
    • Industrial Property Rights Holder
      (財)ファインセラミックスセンター,(独)日本原子力開発機構
    • Industrial Property Number
      特許,特願 2009-213741
    • Filing Date
      2009-09-15
  • [Patent(Industrial Property Rights)] アルミナ薄膜形成用材料、耐熱部材、バリア性能評価方法及びバリア性能評価装置2008

    • Inventor(s)
      松平恒昭, 北岡諭, 和田匡史
    • Industrial Property Rights Holder
      (財)ファインセラミックスセンター
    • Industrial Property Number
      特許,特願 2008-165024
    • Filing Date
      2008-06-24

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Published: 2013-07-31  

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