Construction of carbon p-space by organic synthesis

2010 Fiscal Year Self-evaluation Report

• Project Area: Emergence of highly elaborated pai-space and its function
• Project/Area Number: 20108005
• Research Category: Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
• Allocation Type: Single-year Grants
• Review Section: Science and Engineering
• Research Institution: Institute for Molecular Science
• Principal Investigator: SAKURAI Hidehiro Institute for Molecular Science, 分子スケールナノサイエンスセンター, 准教授 (00262147)
• Project Period (FY): 2008 – 2012
• Keywords: フラーレン / バッキーボウル

Research Abstract

「バッキーボウル」を足がかりとし、精密有機合成の手法を駆使したカーボンπ空間の構築法の確立を目指す。バッキーボウルの自在合成法を開発し、同時に、バッキーボウルをモジュール分子として組み合わせ、原子レベルでの精密且つ高効率なカーボンπ空間構築法を開拓する。

Research Products

• [Journal Article] The Impact of Basis Set Superposition Error on the Structure of π-π Dimers (2011)
  • Author(s): D.Vijay, H.Sakurai, G.N.Sastry
  • Journal Title: Int.J.Quant.Chem. 111 Pages: 1893-1901
  • Peer Reviewed
• [Journal Article] Synthesis of Sumanene and Related Buckybowls (2011)
  • Author(s): S.Higashibayashi, H.Sakurai
  • Journal Title: Chem.Lett. 40 Pages: 122-128
  • Peer Reviewed
• [Journal Article] Optical Resolution of Chiral Buckybowls by Chiral HPLC (2010)
  • Author(s): R.Tsuruoka, S.Higashibayashi, T. Ishikawa, S.Toyota, H.Sakurai
  • Journal Title: Chem.Lett. 39 Pages: 646-647
  • Peer Reviewed
• [Journal Article] Preparation of C3 Symmetric Homochiral syn-Trisnorbornabenzenes through Regio-selective Cyclotrimerization of Enantiopure Iodonorbornenes (2009)
  • Author(s): A.F.G.Masud Reza, S.Higashibayashi, H.Sakurai
  • Journal Title: Chem.Asian J. 4 Pages: 1329-1337
  • Peer Reviewed
• [Journal Article] Asymmetric Synthesis of a Chiral Buckybowl, Trimethylsumanene (2008)
  • Author(s): S.Higashibayashi, H.Sakurai
  • Journal Title: J.Am.Chem.Soc. 130 Pages: 8592-8593
  • Peer Reviewed
• [Presentation] Synthetic Strategy to Construct C_3 Symmetric Buckybowls (2010)
  • Author(s): H.Sakurai
  • Organizer: Bowl-shaped Aromatic Compounds, National Organic Symposium Trust XIV Organic Chemistry Conference
  • Place of Presentation: Goa, India(Invited Lecture)
  • Year and Date: 2010-12-07
• [Presentation] Bowl Chirality (2010)
  • Author(s): H.Sakurai
  • Organizer: 6th IUPAC International Symposium on Novel Materials and their Synthesis and 20th International Symposium on Fine Chemistry and Functional Polymers
  • Place of Presentation: Wuhan, China(Plenary Lecture)
  • Year and Date: 2010-11-11
• [Presentation] Asymmetric Synthesis of Chiral Buckybowls (2010)
  • Author(s): H.Sakurai
  • Organizer: Organic Synthesis and Human Well Being : Emerging Opportunities and Challenges
  • Place of Presentation: Hyderabad, India.(Invited Lecture)
  • Year and Date: 2010-08-02
• [Presentation] Cyclotrimerization of Haloalkenes Catalyzed by Pd Nanoclusters and its Application to Asymmetric Synthesis of Chiral Buckybowls (2010)
  • Author(s): S.Higashibayashi, H.Sakurai
  • Organizer: Inaugural (1st)International Conference on Molecular & Functional Catalysis
  • Place of Presentation: Singapore, Singapore.(Invited Lecture)
  • Year and Date: 2010-07-12
• [Presentation] Asymmetric Synthesis of a Chiral Buckybowl (2009)
  • Author(s): H.Sakurai
  • Organizer: International Symposium on Chiral Compounds and Special Polymers
  • Place of Presentation: Harbin, China.(Invited Lecture)
  • Year and Date: 2009-07-15
• [Remarks] ホームページによる情報発信
  • URL: http://groups.ims.ac.jp/organization/sakuraig/