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2017 Fiscal Year Annual Research Report

Formation and evolution of organic materials in protoplanetary disks

Planned Research

Project AreaEvolution of molecules in space: from interstellar clouds to proto-planetary nebulae
Project/Area Number 25108003
Research InstitutionTokyo Institute of Technology

Principal Investigator

永原 裕子  東京工業大学, 地球生命研究所, フェロー (80172550)

Co-Investigator(Kenkyū-buntansha) 為則 雄祐  公益財団法人高輝度光科学研究センター, 利用研究促進部門, 主席研究員 (10360819)
星野 真人  公益財団法人高輝度光科学研究センター, 利用研究促進部門, 研究員 (30508461)
青木 貞雄  一般財団法人総合科学研究機構(総合科学研究センター(総合科学研究室)及び中性子科学センター(研究開発, 総合科学研究センター, 主任研究員 (50016804)
木村 勇気  北海道大学, 低温科学研究所, その他 (50449542)
高橋 修  広島大学, サステナブル・ディベロップメント実践研究センター, 特任講師 (60253051)
渡辺 紀生  筑波大学, 数理物質系, 講師 (80241793)
Project Period (FY) 2013-06-28 – 2018-03-31
Keywords原始惑星系 / 有機物 / 表面反応 / 軟X線顕微鏡 / 吸着反応
Outline of Annual Research Achievements

最終年度は,基板上における有機物生成反応の網羅的探索と結像型軟X線顕微鏡の完成と解析方法の確立という,A2 班の目標を達成すべく研究をおこなった.基板上の有機物生成反応に関しては,原始惑星系において主要なガスであるH2とCO分子,50-750K の温度条件,前年度までの金属に加え,非晶質ケイ酸塩基板につき系統的な実験をおこなった.その結果,金属上では,500K 以上において,非晶質ケイ酸塩上では750K 以上においてフィッシャー・トロプシュ (FT) 反応によりメタンが形成されることを示すことに成功した.しかし,反応生成物,反応効率の解析から,水性ガスシフト反応,Boudouard 反応が同程度あるいはより効率的におこることから,原始惑星系円盤においてはFT反応による有機物形成は有機物形成の主要反応ではないことが明らかとなった.
軟X線顕微鏡に関しては,広視野においてミクロンの分解能において撮像することに成功した.これを用い,解析のための標準資料分析,FT反応実験の基板物質評価,本領域研究他班の実験結果の解析など多くのデータを得た.In situ において官能基の同定,生成物の結合比等を求めることに成功し,低温有機物生成反応は初期物質により生成する結合が異なるというきわめて重要な知見を得ることに成功した.しかし,リレー光学系を用いた高倍率・高分解能による撮像は,照明光学系のさらなる調整等が必要である.
これらの結果を統合し,原始惑星系円盤における有機物進化の全体像を理解するため,前年度までに作成した円盤物理進化と温度上昇にともなう有機物蒸発反応を統合したモデルを用いた多数のパラメータの見当の結果,円盤初期条件が有機物時空分布に決定的な役割を果たすことを示した.太陽系の場合,初期円盤サイズは数10AU程度,円盤質量は0.02-0.05太陽質量程度であったことが明らかとなった.

Research Progress Status

29年度が最終年度であるため、記入しない。

Strategy for Future Research Activity

29年度が最終年度であるため、記入しない。

  • Research Products

    (40 results)

All 2018 2017

All Journal Article (27 results) (of which Int'l Joint Research: 5 results,  Peer Reviewed: 27 results,  Open Access: 4 results) Presentation (12 results) (of which Int'l Joint Research: 8 results) Book (1 results)

  • [Journal Article] XANES spectra of forsterite in crystal, surface, and amorphous states2018

    • Author(s)
      13.OsamuTakahashi(*), YusukeTamenori, TaigaSuenaga, F. TomokoIkeda, JunyaMatsuno, AkiraTsuchiyama
    • Journal Title

      AIP Advances

      Volume: 8 Pages: 025107~025107

    • DOI

      10.1063/1.5017245

    • Peer Reviewed / Open Access
  • [Journal Article] Lithium, magnesium and sulfur purification from seawater using an ion chromatograph with a fraction collector system for stable isotope measurements2018

    • Author(s)
      Yoshimura Toshihiro、Araoka Daisuke、Tamenori Yusuke、Kuroda Junichiro、Kawahata Hodaka、Ohkouchi Naohiko
    • Journal Title

      Journal of Chromatography A

      Volume: 1531 Pages: 157~162

    • DOI

      10.1016/j.chroma.2017.11.052

    • Peer Reviewed
  • [Journal Article] Development of the full-field imaging microscope for nanoscale analysis with minimal radiation damage2018

    • Author(s)
      Y. Tamenori and M. Hoshino
    • Journal Title

      SPring-8 Section C : Technical Report

      Volume: 2018Early Pages: 印刷中

    • Peer Reviewed
  • [Journal Article] Site-selective bond scission of methylbenzoate following core excitation2018

    • Author(s)
      Takahashi Osamu、Kooser Kuno、Ha Dang Trinh、Myllynen Hanna、Laksman Joakim、Rachlew Elisabeth、Kukk Edwin
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 20 Pages: 9591~9599

    • DOI

      10.1039/c7cp08428e

    • Peer Reviewed
  • [Journal Article] Variation of mineralogy and organic material during the early stages of aqueous activity recorded in Antarctic micrometeorites2017

    • Author(s)
      Noguchi T.、Yabuta H.、Itoh S.、Sakamoto N.、Mitsunari T.、Okubo A.、Okazaki R.、Nakamura T.、Tachibana S.、Terada K.、Ebihara M.、Imae N.、Kimura M.、Nagahara H.
    • Journal Title

      Geochimica et Cosmochimica Acta

      Volume: 208 Pages: 119~144

    • DOI

      10.1016/j.gca.2017.03.034

    • Peer Reviewed
  • [Journal Article] Formation of an ultracarbonaceous Antarctic micrometeorite through minimal aqueous alteration in a small porous icy body2017

    • Author(s)
      Yabuta Hikaru、Noguchi Takaaki、Itoh Shoichi、Nakamura Tomoki、Miyake Akira、Tsujimoto Shinichi、Ohashi Noriaki、Sakamoto Naoya、Hashiguchi Minako、Abe Ken-ichi、Okubo Aya、Kilcoyne A.L. David、Tachibana Shogo、Okazaki Ryuji、Terada Kentaro、Ebihara Mitsuru、Nagahara Hiroko
    • Journal Title

      Geochimica et Cosmochimica Acta

      Volume: 214 Pages: 172~190

    • DOI

      10.1016/j.gca.2017.06.047

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Crystallization and cooling conditions for diogenite formation in the turbulent magma ocean of asteroid 4 Vesta2017

    • Author(s)
      Kawabata Yusuke、Nagahara Hiroko
    • Journal Title

      Icarus

      Volume: 281 Pages: 379~387

    • DOI

      10.1016/j.icarus.2016.08.005

    • Peer Reviewed
  • [Journal Article] X-ray absorption fine structure study of heavily P doped (111) and (001) diamond2017

    • Author(s)
      Shikata Shinichi、Yamaguchi Koji、Fujiwara Akihiko、Tamenori Yusuke、Yahiro Jumpei、Kunisu Masahiro、Yamada Takatoshi
    • Journal Title

      Applied Physics Letters

      Volume: 110 Pages: 072106~072106

    • DOI

      10.1063/1.4975062

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Ligand-free Suzuki-Miyaura coupling using ruthenium(0) nanoparticles and a continuously irradiating microwave system2017

    • Author(s)
      Akiyama Toshiki、Taniguchi Takahisa、Saito Nozomi、Doi Ryohei、Honma Tetsuo、Tamenori Yusuke、Ohki Yuuta、Takahashi Naoyuki、Fujioka Hiromichi、Sato Yoshihiro、Arisawa Mitsuhiro
    • Journal Title

      Green Chemistry

      Volume: 19 Pages: 3357~3369

    • DOI

      10.1039/C7GC01166K

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Operando Soft X-ray Absorption Spectroscopic Study on a Solid Oxide Fuel Cell Cathode during Electrochemical Oxygen Reduction2017

    • Author(s)
      Nakamura Takashi、Oike Ryo、Kimura Yuta、Tamenori Yusuke、Kawada Tatsuya、Amezawa Koji
    • Journal Title

      ChemSusChem

      Volume: 10 Pages: 2008~2014

    • DOI

      10.1002/cssc.201700237

    • Peer Reviewed
  • [Journal Article] Detection of N-Te bonds in the as-deposited amorphous nitrogen-doped GeTe-based phase change alloys using N K-edge XANES spectroscopy and their impact on crystallization2017

    • Author(s)
      Krbal M.、Kolobov A.V.、Fons P.、Mitrofanov K.V.、Tamenori Y.、Hyot B.、Andre B.、Tominaga J.
    • Journal Title

      Journal of Alloys and Compounds

      Volume: 704 Pages: 254~259

    • DOI

      10.1016/j.jallcom.2017.01.322

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] High-energy, high-resolution x-ray imaging for metallic cultural heritages2017

    • Author(s)
      Hoshino Masato、Uesugi Kentaro、Shikaku Ryuji、Yagi Naoto
    • Journal Title

      AIP Advances

      Volume: 7 Pages: 105122~105122

    • DOI

      doi: 10.1063/1.5003162

    • Peer Reviewed / Open Access
  • [Journal Article] Current status of X-ray phase imaging at SPring-8: Toward 4D X-ray phase tomography for biological samples2017

    • Author(s)
      Hoshino Masato、Uesugi Kentaro、Yagi Naoto
    • Journal Title

      Journal of Physics: Conference Series

      Volume: 849 Pages: 012054~012054

    • DOI

      doi: 10.1088/1742-6596/849/1/012054

    • Peer Reviewed / Open Access
  • [Journal Article] Direct Transmission Electron Microscopy Visualization of the Cement Reaction by Colloidal Aggregation of Fumed Silica2017

    • Author(s)
      Satoh Hisao、Kimura Yuki、Furukawa Erika
    • Journal Title

      Industrial & Engineering Chemistry Research

      Volume: 57 Pages: 79~83

    • DOI

      10.1021/acs.iecr.7b04137

    • Peer Reviewed
  • [Journal Article] Experiments on Condensation of Calcium Sulfide Grains To Demarcate Environments for the Formation of Enstatite Chondrites2017

    • Author(s)
      Yokoyama Kaori、Kimura Yuki、Kaito Chihiro
    • Journal Title

      ACS Earth and Space Chemistry

      Volume: 1 Pages: 601~607

    • DOI

      10.1021/acsearthspacechem.7b00076

    • Peer Reviewed
  • [Journal Article] Liquid-like behavior of UV-irradiated interstellar ice analog at low temperatures2017

    • Author(s)
      Tachibana Shogo、Kouchi Akira、Hama Tetsuya、Oba Yasuhiro、Piani Laurette、Sugawara Iyo、Endo Yukiko、Hidaka Hiroshi、Kimura Yuki、Murata Ken-ichiro、Yurimoto Hisayoshi、Watanabe Naoki
    • Journal Title

      Science Advances

      Volume: 3 Pages: eaao2538~2538

    • DOI

      10.1126/sciadv.aao2538

    • Peer Reviewed / Open Access
  • [Journal Article] Self-assembly of MoO3 needles in gas current for cubic formation pathway2017

    • Author(s)
      Ishizuka Shinnosuke、Kimura Yuki、Yokoi Satoki、Yamazaki Tomoya、Sato Rikako、Hama Tetsuya
    • Journal Title

      Nanoscale

      Volume: 9 Pages: 10109~10116

    • DOI

      10.1039/C7NR02613G

    • Peer Reviewed
  • [Journal Article] Fast crystalline ice formation at extremely low temperature through water/neon matrix sublimation2017

    • Author(s)
      Hama Tetsuya、Ishizuka Shinnosuke、Yamazaki Tomoya、Kimura Yuki、Kouchi Akira、Watanabe Naoki、Sugimoto Toshiki、Pirronello Valerio
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 19 Pages: 17677~17684

    • DOI

      10.1039/c7cp03315j

    • Peer Reviewed
  • [Journal Article] XAS and XES studies of carbonate and bicarbonate ions in aqueous solutions2017

    • Author(s)
      Nishida Naohiro、Horikawa Yuka、Tokushima Takashi、Takahashi Osamu
    • Journal Title

      Journal of Electron Spectroscopy and Related Phenomena

      Volume: 220 Pages: 96~100

    • DOI

      10.1016/j.elspec.2016.12.006

    • Peer Reviewed
  • [Journal Article] Theoretical study on X-ray absorption spectra and bond dynamics for core excitation from valence excited benzoic acids2017

    • Author(s)
      Inui H.、Takahashi O.、Hiraya A.
    • Journal Title

      Journal of Electron Spectroscopy and Related Phenomena

      Volume: 220 Pages: 101~104

    • DOI

      10.1016/j.elspec.2016.12.005

    • Peer Reviewed
  • [Journal Article] Relativistic corrections for single- and double-core excitation at the K- and L-edges from Li to Kr2017

    • Author(s)
      Takahashi Osamu
    • Journal Title

      Computational and Theoretical Chemistry

      Volume: 1102 Pages: 80~86

    • DOI

      10.1016/j.comptc.2017.01.007

    • Peer Reviewed
  • [Journal Article] Core-hole-induced dynamical effects in the x-ray emission spectrum of liquid methanol2017

    • Author(s)
      Ljungberg M. P.、Zhovtobriukh I.、Takahashi O.、Pettersson L. G. M.
    • Journal Title

      The Journal of Chemical Physics

      Volume: 146 Pages: 134506~134506

    • DOI

      10.1063/1.4979656

    • Peer Reviewed
  • [Journal Article] X-ray Emission Spectrum of Liquid Ethanol: Origin of Split Peaks2017

    • Author(s)
      Takahashi Osamu、Ljungberg Mathias P.、Pettersson Lars G. M.
    • Journal Title

      The Journal of Physical Chemistry B

      Volume: 121 Pages: 11163~11168

    • DOI

      10.1021/acs.jpcb.7b09262

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] ケイ酸塩鉱物の電子状態及びXANES計算2017

    • Author(s)
      高橋 修、末永 太河
    • Journal Title

      J. Comput. Chem. Jpn

      Volume: 15 Pages: 211~212

    • DOI

      10.2477/jccj.2016-0058

    • Peer Reviewed
  • [Journal Article] スペクトル解析法による固体有機結晶の振動スペクトル計算法2017

    • Author(s)
      末永 太河、高橋 修
    • Journal Title

      J. Comput. Chem. Jpn

      Volume: 16 Pages: 108~109

    • DOI

      10.2477/jccj.2017-0027

    • Peer Reviewed
  • [Journal Article] Cross-sectional particle measurement in the resonance domain on the substrate through scatterometry2017

    • Author(s)
      T. Hoshino, N. Watanabe, S. Aoki, K. Sakurai, and M. Itoh
    • Journal Title

      Opt. Express

      Volume: 25 Pages: 26329-26348

    • DOI

      10.1364/ OE.25.026329

    • Peer Reviewed
  • [Journal Article] Design and Fabrication of Wolter-type 4-mirror system2017

    • Author(s)
      N. Watanabe, S. Aoki and N. Yamaguchi
    • Journal Title

      Journal of Physics: Conf. Series

      Volume: 849 Pages: 012058-012061

    • DOI

      10.1088/1742-6596/849/1/012058

    • Peer Reviewed
  • [Presentation] Mg水素化物中のMg K吸収端のXANESスペクトル2018

    • Author(s)
      小林英一,坂東恭子,奥平幸司,高橋修,岡島敏浩
    • Organizer
      第31回日本放射光学会年会・放射光科学合同シンポジウム
  • [Presentation] Reaction efficiency between hydrogen and carbon monoxide on a catalytic substrate of iron, nickel or its alloy2017

    • Author(s)
      Y. Kimura, R. Sato, A. Tsuchiyama, Y. Nagahara, T. Hama, H. Hidaka, N. Watanabe, A. Kouchi
    • Organizer
      JpGU-AGU Joint Meeting 2017
    • Int'l Joint Research
  • [Presentation] 高輝度軟X線を光源とした散乱・顕微分光観測技術の進展2017

    • Author(s)
      為則雄祐
    • Organizer
      第66回高分子討論会
  • [Presentation] Dynamic application based on X-ray phase tomography using grating interferometer2017

    • Author(s)
      Hoshino, K. Uesugi and N. Yagi
    • Organizer
      4th Conference on X-ray and Neutron Phase Imaging with Grating
    • Int'l Joint Research
  • [Presentation] Simulations of H-bonded liquids2017

    • Author(s)
      O. Takahashi
    • Organizer
      Ut246; XES workshop
    • Int'l Joint Research
  • [Presentation] スペクトル解析法による固体有機結晶の新規振動スペクトル計算法の開発2017

    • Author(s)
      末永太河,高橋修
    • Organizer
      2017年日本コンピュータ化学会春季年会
  • [Presentation] Ⅹ線微分位相コントラスト顕微鏡を用いたAlCuFe準結晶の3次元観察2017

    • Author(s)
      渡辺紀生、青木貞雄
    • Organizer
      第65回応用物理学会春季学術講演会
  • [Presentation] Formation of ice poor comets in the protosolar disk2017

    • Author(s)
      H. Nagahara and K. Ozawa
    • Organizer
      European Geoscience Union
    • Int'l Joint Research
  • [Presentation] The role of initial protostellar disk size on the chemical evolution of the disk2017

    • Author(s)
      H. Nagahara and K. Ozawa
    • Organizer
      Star formation
    • Int'l Joint Research
  • [Presentation] Physico-chemical evolution of protoplanetary disks2017

    • Author(s)
      H. Nagahara and K. Ozawa
    • Organizer
      Current and Future Perspectives of Chemical Modelling in Astrophysics
    • Int'l Joint Research
  • [Presentation] Importance of the early accretion stage of a protoplanetary disk on the chemical evolution of planetesimals and comets2017

    • Author(s)
      H. Nagahara and K. Ozawa
    • Organizer
      European Planetary Science Congress
    • Int'l Joint Research
  • [Presentation] Chemical evolution of protoplanetary disks and its consequence on water and organics contents in planetesimals and comets2017

    • Author(s)
      H. Nagahara and K. Ozawa
    • Organizer
      Planet formation and evolution
    • Int'l Joint Research
  • [Book] XAFSの基礎と応用2017

    • Author(s)
      日本XAFS研究会
    • Total Pages
      352
    • Publisher
      講談社
    • ISBN
      978-4-06-153295-3

URL: 

Published: 2018-12-17  

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