2015 Fiscal Year Annual Research Report
Project Area | Evolution of molecules in space: from interstellar clouds to proto-planetary nebulae |
Project/Area Number |
25108006
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Research Institution | Hokkaido University |
Principal Investigator |
圦本 尚義 北海道大学, 理学(系)研究科(研究院), 教授 (80191485)
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Co-Investigator(Kenkyū-buntansha) |
三田 肇 福岡工業大学, 工学部, 教授 (00282301)
濱瀬 健司 九州大学, 薬学研究科(研究院), 准教授 (10284522)
奈良岡 浩 九州大学, 理学(系)研究科(研究院), 教授 (20198386)
伊藤 正一 京都大学, 理学(系)研究科(研究院), 准教授 (60397023)
高野 淑識 国立研究開発法人海洋研究開発機構, 生物地球科学研究分野, 研究員 (80399815)
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Project Period (FY) |
2013-06-28 – 2018-03-31
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Keywords | 惑星起源・進化 / 有機物 / 同位体 / 構造 / 宇宙化学 |
Outline of Annual Research Achievements |
星間分子雲には複雑な分子の存在が確認され,隕石等の地球外物質中に水素や窒素の重い同位体が濃集した有機物が存在し,これらの関連が指摘されている.しかし,宇宙空間において同位体濃縮がどのようなプロセスでできたかは明らかではなく,生成過程と分子構造との関係についての研究は少ない. 本研究では,難燃性有機物から可溶性有機物まで極微量有機物に対して,網羅的に分子構造を同定し,同位体を含め世界最高感度で分析する手法を開発し,実験班と協力して合成する濃縮同位体をトレーサーとした分子雲・原始惑星系模擬有機物の定性定量分析,有機化合物単位の構造解析・同位体分析を行うことにより,分子雲,原始惑星系での有機物生成過程と分子構造との関係を解明する.地球外物質中の極微量有機化合物に同様の分析方法を適用し,隕石有機物分子と分子雲分子・原始惑星系分子をリンクする新しいマーカー分子・マーカー官能基を探索する.本年度は以下の研究成果が得られた. 1.液体クロマトグラフ質量分析計により各種スタンダードのデータベースを作成し,宇宙有機物の構造解析を進める.この質量分析計と二次元HPLCを組合わせ同位体置換体を区別したアミノ酸分析法を開発した. 2.化学反応性の高いアンモニアガスの吸着・脱着プロセスに着目し,分子レベルでの窒素同位体分別に関する基礎過程の実験を行った. 3.炭素質隕石から検出されるアルデヒドとアンモニアの反応により生成する化合物の構造解析と同位体比分析を行った. 4.隕石抽出有機物を用いて有機構造物の作成実験を行い,実際の隕石中の不均一構造の特徴と比較した.
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Current Status of Research Progress |
Current Status of Research Progress
2: Research has progressed on the whole more than it was originally planned.
Reason
液体クロマトグラフ質量分析計によりスタンダードのデータベースを作成し,2次元HPLCを組合わせ同位体置換体を区別するアミノ酸分析法を開発することに成功した.炭素質隕石から検出したアルデヒドとアンモニアの反応により生成する化合物の構造解析と同位体比分析に成功し,この化合物の生成メカニズムについて考察した.以上のように研究計画に基づき研究が進行しているため.
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Strategy for Future Research Activity |
実験班と合同で作成する宇宙模擬有機物を同位体をドープした原料により合成し,その精密質量分析を開発した分析法により行っていく方策である.これにより隕石有機物と分子雲分子をリンクする新しいマーカー分子・マーカー官能基を探索し,分子雲から原始惑星系円盤に至る有機物生成過程を分子構造進化の観点から解明していく.
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Research Products
(68 results)
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[Journal Article] New constraints on upper mantle creep mechanism inferred from silicon grain-boundary diffusion rates.2016
Author(s)
Fei, H., Koizumi, S., Sakamoto, N., Hashiguchi, M., Yurimoto, H., Marquardt, K., Miyajima, N., Yamazaki, D. and Katsura, T.
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Journal Title
Earth Planet. Sci. Lett.
Volume: 433
Pages: 350-359
DOI
Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
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[Journal Article] P-O-rich sulfide phase in CM chondrites: Constraints on its origin on the CM parent body.2016
Author(s)
Zhang, A. -C., Itoh, S., Yurimoto, H., Hsu, W. -B., Wang, R. -C. and Taylor, L. A.
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Journal Title
Meteorit. Planet. Sci.
Volume: 51
Pages: 56-69
DOI
Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
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[Journal Article] Mineralogical anatomy and implications of a Ti-Sc-rich ultrarefractory inclusion from Sayh al Uhaymir 290 CH3 chondrite.2015
Author(s)
Zhang, A.-C., Ma, C., Sakamoto, N., Wang, R.-C., Hsu, W.-B. and Yurimoto, H.
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Journal Title
Geochim. Cosmochim. Acta
Volume: 163
Pages: 27-39
DOI
Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
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[Journal Article] Synthesis of large and homogeneous single crystals of water-bearing minerals by slow cooling at deep-mantle pressures.2015
Author(s)
Okuchi, T., Purevjav, N., Tomioka, N., Lin, J.-F., Kuribayashi, T., Schoneveld, L., Hwang, H., Sakamoto, N., Kawasaki, N. and Yurimoto, H.
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Journal Title
American Mineralogist
Volume: 100
Pages: 1483-1492
DOI
Peer Reviewed / Open Access / Int'l Joint Research
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[Journal Article] 26Al-26Mg chronology and oxygen isotope distributions of multiple melting for a Type C CAI from Allende.2015
Author(s)
Kawasaki, N., Kato, C., Itoh, S., Wakaki, S., Ito, M. and Yurimoto, H.
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Journal Title
Geochim. Cosmochim. Acta
Volume: 169
Pages: 99-114
DOI
Peer Reviewed / Open Access / Acknowledgement Compliant
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[Journal Article] Depth profiling analysis of solar wind helium collected in diamond-like carbon film from Genesis.2015
Author(s)
Bajo, K., Olinger, C. T., Jurewicz, A. J. G., Burnett, D. S., Sakaguchi, I., Suzuki, T., Itose, S., Ishihara, M., Uchino, K., Wieler, R. and Yurimoto, H.
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Journal Title
Geochem. J.
Volume: 49
Pages: 559-566
DOI
Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
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[Journal Article] Comparative compressibility of hydrous wadsleyite and ringwoodite: Effect of H2O and implications for detecting water in the transition zone.2015
Author(s)
Chang, Y.-Y., Jacobsen, S.D., Bina, C.R., Thomas, S.-M., Smyth, J.R., Frost, D.J., Ballaran, T.B., McCammon, C.A., Hauri, E.H., Inoue, T., Yurimoto, H., Meng, Y. and Dera, P.
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Journal Title
J. Geophys. Res. Solid Earth
Volume: 120
Pages: 8259-8280
DOI
Peer Reviewed / Open Access / Int'l Joint Research
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[Journal Article] ToF-SIMS analysis of carbonaceous particles in the sample catcher of the Hayabusa spacecraft.2015
Author(s)
Naraoka, H., Aoki, D., Fukushima, K., Uesugi, M., Ito, M., Kitajima, F., Mita, H., Yabuta, H., Takano, Y., Yada, T., Ishibashi, Y., Karouji, Y., Okada, T. and Abe, M.
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Journal Title
Earth, Planets and Space
Volume: 67
Pages: 67-67
DOI
Peer Reviewed / Open Access / Acknowledgement Compliant
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[Journal Article] Design and synthesis of a novel pre-column derivatization reagent with a 6-methoxy-4-quinolone moiety for fluorescence and tandem mass spectrometric detection and its application to chiral amino acid analysis2015
Author(s)
Tsubasa OYAMA, Eiichi NEGISHI, Hirohisa ONIGAHARA, Nao KUSANO, Yurika MIYOSHI, Masashi MITA, Manabu NAKAZONO, Sumio OHTSUKI, Akio OJIDA, Wolfgang LINDNER, Kenji HAMASE
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Journal Title
Journal of Pharmaceutical and Biomedical Analysis
Volume: 116
Pages: 71-79
DOI
Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
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[Journal Article] A micro-Raman and infrared study of the several Hayabusa category 3 (organic) particles.2015
Author(s)
Kitajima, F., Uesugi, M., Karouji, Y., Ishibashi, Y., Yada, T., Naraoka, H., Abe, M., Fujimura, A., Ito, M., Yabuta, H., Mita, H., Takano, Y. and Okada, T.
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Journal Title
Earth, Planets and Space
Volume: 67
Pages: 20-20
DOI
Peer Reviewed / Open Access
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[Journal Article] Mineralogy and noble gas isotopes of micrometeorites collected from Antarctic snow2015
Author(s)
Ryuji Okazaki, Takaaki Noguchi, Shin-ichi Tsujimoto, Yu Tobimatsu, Tomoki Nakamura, Mitsuru Ebihara, Shoichi Itoh, Hiroko Nagahara, Shogo Tachibana, Kentaro Terada and Hikaru Yabuta
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Journal Title
Earth, Planets and Space
Volume: 67
Pages: 90-90
DOI
Peer Reviewed / Open Access
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[Presentation] Photochemistry in Molecular Cloud and Protoplanetary Disk: Evolution of Ice and Organic Residues Through Warming and UV-Irradiation.2016
Author(s)
Piani, L.; Tachibana, S.; Hama, T.; Sugawara, I.; Oba, Y.; Tanaka, H.; Kimura, Y.; Miyake, A.; Matsuno, J.; Tsuchiyama, A.; Yurimoto, H.; Kouchi, A.
Organizer
47th Lunar and Planetary Science Conference
Place of Presentation
ウッドランド(アメリカ)
Year and Date
2016-03-21 – 2016-03-25
Int'l Joint Research
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[Presentation] Current Status and Future Prospects of JAXA's Astromaterials Science Research Group.2016
Author(s)
Abe, M.; Okada, T.; Yada, T.; Uesugi, M.; Karouji, Y.; Nakato, A.; Hashiguchi, M.; Matsumoto, T.; Nshimura, M.; Kumagai, K.; Matsui, S.; Nakauchi, Y.; Yurimoto, H.
Organizer
47th Lunar and Planetary Science Conference
Place of Presentation
ウッドランド(アメリカ)
Year and Date
2016-03-21 – 2016-03-25
Int'l Joint Research
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[Presentation] Mass spectrometric studies of organics in the interstellar ice analogs.2015
Author(s)
Nakayama, M., Ishibashi, Y., Mita, H., Naraoka, H., Tachibana, S., Hama, T., Endo, Y., and Kouch A.i
Organizer
The International Chemical Congress of Pacific Basin Societies
Place of Presentation
ホノルル(アメリカ)
Year and Date
2015-12-15 – 2015-12-20
Int'l Joint Research
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[Presentation] HAYABUSA2 SAMPLER: CURRENT STATUS.2015
Author(s)
S. Tachibana, H. Sawada, R. Okazaki, Y. Takano, K. Sakamoto, and Y. Miura.
Organizer
HAYABUSA2015: 3rd Symposium of Solar System Materials
Place of Presentation
JAXA(神奈川県相模原市)
Year and Date
2015-11-18 – 2015-11-18
Int'l Joint Research
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[Presentation] Specification development of Hayabusa2 Curation facilities at JAXA.2015
Author(s)
M. Uesugi, A. Nakato, Y. Karouji, M. Hashiguchi, T. Matsumoto, K. Kumagai, M. Nishimura, T. Yada, T. Okada, M. Abe, K. Hashizume, N. Imae, M. Ito, Y. Kebukawa, F. Kitajima, A. Kouchi, T. Kunihiro, Y. N. Miura, K. Nakamura, T. Nakamura, H. Naraoka, Y. Takano, H. Yurimoto 他13名.
Organizer
HAYABUSA2015: 3rd Symposium of Solar System Materials
Place of Presentation
JAXA(神奈川県相模原市)
Year and Date
2015-11-18 – 2015-11-18
Int'l Joint Research
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[Presentation] Evolution of Organic Molecules in Space: From Ice Deposition to Organic Residues.2015
Author(s)
Piani L, Tachibana S, Hama T, Kimura Y, Endo Y, Fujita K, Nakatsubo S, Fukushi H, Mori S, Chigai T, Yurimoto H & Kouchi A
Organizer
Goldschmidt2015
Place of Presentation
プラハ(チェコ)
Year and Date
2015-08-16 – 2015-08-21
Int'l Joint Research
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[Presentation] Evolution of organic molecules in space: characteristics and properties of experimental organic residues.2015
Author(s)
Laurette PIANI, Shogo TACHIBANA, Tetsuya HAMA, Yuki KIMURA, Y. ENDO, K. FUJITA, S. NAKATSUBO, H. FUKUSHI, S. MORI, T. CHIGAI, Hisayoshi YURIMOTO, Akira KOUCHI
Organizer
Japan Geoscience Union Meeting 2015
Place of Presentation
幕張メッセ国際会議場(千葉県千葉市)
Year and Date
2015-05-24 – 2015-05-28
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