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2017 Fiscal Year Final Research Report

Synthesis and fabrication of stimulus-convertible materials for single-molecular devices

Planned Research

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Project AreaMolecular Architectonics: Orchestration of Single Molecules for Novel Function
Project/Area Number 25110003
Research Category

Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionEhime University

Principal Investigator

Uno Hidemitsu  愛媛大学, 理工学研究科(理学系), 教授 (20168735)

Co-Investigator(Kenkyū-buntansha) 中江 隆博  京都大学, エネルギー理工学研究所, 助教 (20505995)
奥島 鉄雄  愛媛大学, 理工学研究科(理学系), 准教授 (60359924)
高瀬 雅祥  愛媛大学, 理工学研究科(理学系), 准教授 (90516121)
Co-Investigator(Renkei-kenkyūsha) MORI Shigeki  愛媛大学, 学術支援センター, 講師 (30572028)
Research Collaborator OGAWA Takuji  大阪大学, 理学研究科, 教授
IE Yutaka  大阪大学, 産業科学研究所, 准教授
SUGIMOTO Nobuaki  東京大学, 新領域創成科学研究科, 准教授
Project Period (FY) 2013-06-28 – 2018-03-31
Keywordsチアポルフィリン / ヘキサピロロヘキサアザコロネン / 逆Diels-Alder反応 / 単一分子観測 / ヘリセン
Outline of Final Research Achievements

Electric measurement of single molecules which pi-systems were altered by external stimuli such as heat, light, acid, etc. was planned. Bicyclo[2.2.2]octadiene ring system was chosen as such an external-stimulus-changeable moiety and porphyrin, and hexapyrrolohexaazacoronene (HPHAC) were chosen as such pi-systems. In bisthiaporphyrins fused with BCOD and benzene rings, their macrocyclic ring current routes were altered from on a long axis to on short axes by protonation.

Free Research Field

有機化学

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Published: 2019-03-29  

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