1994 Fiscal Year Annual Research Report

有機電気化学の新展開

Research Project

Project/Area Number	05235101
Research Institution	Tohoku University
Principal Investigator	長哲郎東北大学, 薬学部, 教授 (10010753)
Co-Investigator(Kenkyū-buntansha)	内本喜一郎京都大学, 工学部, 教授 (90025958) 鳥居滋岡山大学, 工学部, 教授 (70032927) 野中勉東京工業大, 大学院・総合理工学研究科, 教授 (00016528)
Keywords	有機電気化学 / 電極界面 / 超活性反応種 / 不斉合成
Research Abstract	本研究は6名の評価グループと5名の実施グループから構成され、本重点領域研究「有機電気化学の新展開」の実施2年目の総括班として機能した。本年度新たに40名の公募班員が加わり、全組織は118名に拡大したため、反応場としての電極界面の新しい概念の確立と超反応活性種の創世による有機電気化学の格段の飛躍をめざして各研究班内はもちろん研究班相互の連携を緊密化し、研究計画全体の効果的実現を計った。 1.会議の開催平成6年6月30日学士会館において第3回全体会議(各班より2名発表)、7月1日同館において第2回公開シンポジウム(各班より1名と外部から軽部征夫氏の講演)と平成5年度の未発表班員によるポスター発表、班会議、総括班会議を開催した。また、12月9〜10日せとうち児島ホテルにおいて第4回全体会議(各班より2名発表)、第3回公開シンポジウム(各班より1名講演)と平成6年度の新規公募班員全員によるポスター発表、班会議、総括班会議を実施した。一方、各研究班は別時期に班会議を持ち、相互の連携と、目的に沿った研究の推進に努めた。 2.印刷物の発行ニュースレター4回、全体会議および公開シンポジウムの要旨集2回、全班員名簿1回を印刷し、班員等に配布した。ヒアリング資料の作成を班員のデータをもとに行った。また平成6年度の研究成果(和文2ページ、英文2ページ)を平成7年2月に全班員から提出してもらい、前年度と同様に報告書を作成すべく進めている。 3.研究班相互の研究協力この目的を推進するために、班長会議を3回開き、各班員の研究に共通する研究対象物、研究手法を整理し、横断的研究の推進に努めた。特に不斉合成の成果が各班より得られ、当初の予想以上の研究の進展が見られた。

Research Products
(16 results)

All Other

All Publications (16 results)

[Publications] Yoshitomo Kashiwagi: "The Effects of Chain Length of Ferrocene Moicty on Mediator-and Enzymes-Modified Electrode" Denki Kagaku. 62. 1240-1246 (1994)
[Publications] Tetsuo Osa: "Enantioselective,Electrocatalytic Oxidative Couplings of Naphthols,Naphthyl Ether and Phenanthrol on a TEMPO-Modified Graphite Fell Electrode in the Presence of (-)-Sparteine" Journal of Chemical Society,Chemical Communications. 2535-2537 (1994)
[Publications] Mahito Atobe: "Utrasonic Effects on Electroorganic Processes II.Electroreduction of Methyl Halides on a Reactive Tin Cathode" Denki Kagaku. 62. 1298-1299 (1994)
[Publications] Akiko Yoshiyama: "Preparation of PTEE Composite-Plated Hydrophobic β-PbO_2 Electrodes" Chemistry Letters. 1565-1568 (1994)
[Publications] Kazuya Matsuda: "Ultrasonic Effects on Electroorganic Processes.Product-Selectivity in Electroreduction of Benzaldehydes" Chemistry Letters. 1619-1622 (1994)
[Publications] Yasushi Ono: "Electrolysis Using Composite-Plated Electrodes.Preparation of a Binary Type Composite-Plated Nickel Electrode with Poly(terafluoroethylene)and Silica Gel and 1ts Application in Electroreduction of Aldehydes" Chemistry Letters. 1623-1626 (1994)
[Publications] Toshio Fuchigami: "Electrocatalysis of self a Self-Assembled Thiol-modified Electrode Having Immobilized Dopamine for Oxidation of Reduced Nicotinamide-Adenine Dinucleotide(NADH)" Denki Kagaku. 62. 1251-1253 (1994)
[Publications] Yasushi Ono: "Electrolysis Using Composite-plated ElectrodesX Preparation of Hydrophobic Nickel and Zinc Electrodes Composite-plated with Fluorinaated Pitch and Their Application in Electroreduction of Organic Compounds" Denki Kagaku. 62. 1048-1053 (1994)
[Publications] Yasushi Ono: "Electrolysis Using Composite-plated Electrodes XII.Theoretical and Experimental Analysis of Hydrophobic Effect of Ni/PTFE Composite-plated Electrodes on an Electroorganic Process" Denki Kagaku. 62. 1264-1268 (1994)
[Publications] Tsutomu Inokuchi: "Indirect Electrochemical Radical Cyclization of Bromo Acetals by the Combined Use of Cobaloxime and Sacrificial Electrode" Bulletin of the Chemical Society of Japan. 67. 595-598 (1994)
[Publications] Hideo Tanaka: "Use of Aluminium as an Electron Pool.Reductive Coupling of Iodebenzenes Promoted by Electron Transsfer in an Ni/Pb/Al Multi Redox System" Inorganica Chim ica Acta. 222. 323-325 (1994)
[Publications] Hideo Tanaka: "A Facile Access to 3-A1lyl-and 3-Benzyl-3-cephems via Reductive Addition/Cyclization of Allenecarboxylate with Allyl and Benzyl Halides in an Al/Pb/Ni Redox System" Journal of Chemical Society,Chemical Communications. 1461-1462 (1994)
[Publications] Tsutomu Inokuchi: "Oxidations of Dihydroxyalkanoates to Vicinal Tricarbonyl Compounds with a 4-Bzo TEMPO- Sodium Bromite System or by Indirect Electrolysis with 4-Bzo TEMPO and Bromide Ion" Chemistry Letters. 1411-1414 (1994)
[Publications] Kazuhiko Takai: "Stereoselective Preparation of Primary(E)-Allylic Amines by the Reaction of Tantalum-Alkyne Complexes with Metallo-Imines" Tetrahedron Letters. 35. 1893-1896 (1994)
[Publications] Kazuhiko Takai: "A Novel Catalytic Effect of Lead on the Red uction of a Zinc Carbenoid with Zinc Metal Leading to a Geminal Dizinc Compounds Acceleration of the Witting-Type Ole fination with the RCHX_2-TiO_2-Zn Systems by Addition of Lead" Journal of Organic Chemistry. 59. 2668-2670 (1994)
[Publications] Toshiaki Yokoo: "A Room Temperature Preparation of Alkenyl Lithium-Halogen Exchange between Alkenyl Iodides and n-BuLi in Hydrocarbon Solvents" Synlett. 645-647 (1994)

1994 Fiscal Year Annual Research Report

有機電気化学の新展開

Principal Investigator

長 哲郎 東北大学, 薬学部, 教授 (10010753)

Research Products

[Publications] Yoshitomo Kashiwagi: "The Effects of Chain Length of Ferrocene Moicty on Mediator-and Enzymes-Modified Electrode" Denki Kagaku. 62. 1240-1246 (1994)

[Publications] Tetsuo Osa: "Enantioselective,Electrocatalytic Oxidative Couplings of Naphthols,Naphthyl Ether and Phenanthrol on a TEMPO-Modified Graphite Fell Electrode in the Presence of (-)-Sparteine" Journal of Chemical Society,Chemical Communications. 2535-2537 (1994)

[Publications] Mahito Atobe: "Utrasonic Effects on Electroorganic Processes II.Electroreduction of Methyl Halides on a Reactive Tin Cathode" Denki Kagaku. 62. 1298-1299 (1994)

[Publications] Akiko Yoshiyama: "Preparation of PTEE Composite-Plated Hydrophobic β-PbO_2 Electrodes" Chemistry Letters. 1565-1568 (1994)

[Publications] Kazuya Matsuda: "Ultrasonic Effects on Electroorganic Processes.Product-Selectivity in Electroreduction of Benzaldehydes" Chemistry Letters. 1619-1622 (1994)

[Publications] Yasushi Ono: "Electrolysis Using Composite-Plated Electrodes.Preparation of a Binary Type Composite-Plated Nickel Electrode with Poly(terafluoroethylene)and Silica Gel and 1ts Application in Electroreduction of Aldehydes" Chemistry Letters. 1623-1626 (1994)

[Publications] Toshio Fuchigami: "Electrocatalysis of self a Self-Assembled Thiol-modified Electrode Having Immobilized Dopamine for Oxidation of Reduced Nicotinamide-Adenine Dinucleotide(NADH)" Denki Kagaku. 62. 1251-1253 (1994)

[Publications] Yasushi Ono: "Electrolysis Using Composite-plated ElectrodesX Preparation of Hydrophobic Nickel and Zinc Electrodes Composite-plated with Fluorinaated Pitch and Their Application in Electroreduction of Organic Compounds" Denki Kagaku. 62. 1048-1053 (1994)

[Publications] Yasushi Ono: "Electrolysis Using Composite-plated Electrodes XII.Theoretical and Experimental Analysis of Hydrophobic Effect of Ni/PTFE Composite-plated Electrodes on an Electroorganic Process" Denki Kagaku. 62. 1264-1268 (1994)

[Publications] Tsutomu Inokuchi: "Indirect Electrochemical Radical Cyclization of Bromo Acetals by the Combined Use of Cobaloxime and Sacrificial Electrode" Bulletin of the Chemical Society of Japan. 67. 595-598 (1994)

[Publications] Hideo Tanaka: "Use of Aluminium as an Electron Pool.Reductive Coupling of Iodebenzenes Promoted by Electron Transsfer in an Ni/Pb/Al Multi Redox System" Inorganica Chim ica Acta. 222. 323-325 (1994)

[Publications] Hideo Tanaka: "A Facile Access to 3-A1lyl-and 3-Benzyl-3-cephems via Reductive Addition/Cyclization of Allenecarboxylate with Allyl and Benzyl Halides in an Al/Pb/Ni Redox System" Journal of Chemical Society,Chemical Communications. 1461-1462 (1994)

[Publications] Tsutomu Inokuchi: "Oxidations of Dihydroxyalkanoates to Vicinal Tricarbonyl Compounds with a 4-Bzo TEMPO- Sodium Bromite System or by Indirect Electrolysis with 4-Bzo TEMPO and Bromide Ion" Chemistry Letters. 1411-1414 (1994)

[Publications] Kazuhiko Takai: "Stereoselective Preparation of Primary(E)-Allylic Amines by the Reaction of Tantalum-Alkyne Complexes with Metallo-Imines" Tetrahedron Letters. 35. 1893-1896 (1994)

[Publications] Toshiaki Yokoo: "A Room Temperature Preparation of Alkenyl Lithium-Halogen Exchange between Alkenyl Iodides and n-BuLi in Hydrocarbon Solvents" Synlett. 645-647 (1994)

長哲郎東北大学, 薬学部, 教授 (10010753)