1996 Fiscal Year Annual Research Report

有機電気化学の新展開

Research Project

Project/Area Number	05235101
Research Institution	Tohoku University
Principal Investigator	長哲郎東北大学, 名誉教授 (10010753)
Co-Investigator(Kenkyū-buntansha)	鈴木周一東京工業大学, 名誉教授 (20016710) 松岡英明東京農工大学, 工学部, 教授 (10143653) 内本喜一郎京都大学, 工学部, 教授 (90025958) 鳥居滋岡山大学, 工学部, 教授 (70032927) 野中勉東京工業大学, 大学院総合理工学研究科, 教授 (00016528)
Keywords	有機電気化学 / 電子移動反応場 / 超活性反応種 / メディエーター反応 / 錯体電子移動系 / 有機反応 / 生物化学
Research Abstract	平成5〜7年度実施された重点領域研究「有機電気化学の新展開」の総括研究を行った。研究組織はいままでと同じく実施グループ5名、評価グループ6名の計11名で構成された。 1.全期間にわたる研究成果報告冊子の作成単年度ごとの研究報告冊子は作成・配布していたが、改めて本重点領域研究のすべての実施班員(114名)に全研究期間の英文報告書をA4版4ページで5月末までに提出願い、前文3ページを付して454ページの研究成果報告書として12月に完成し、班員等に配布した。 2.研究終了ヒアリングとその資料作成 10月17日に文部省の最終ヒアリングを受けた。7月初旬より実施グループは研究全体の整理を始めた。上記1の班員報告書をもとに、必要に応じて研究内容の不明点を問い合わせるとともに、全班員より本研究に関する論文リストの提出を受けた。これらを纏めて本文30ページ、研究成果公表の状況117ページの報告書を作成し、最終ヒアリング時に文部省に提出した。その前に総括班会議を開き、評価グループの諮問を受けた。その結果は設定した「電子移動反応場の設計と制御」、「超活性反応種の創成」、「メディエーター反応の展開」および「錯体電子移動系の展開」の各研究項目は何れも顕著な成果を挙げ、有機電気化学の格段の発展に繋がるとともに、他の方法では実現できない有機反応系を発展させた。さらに錯体化学、生物化学と有機電気化学との境界領域を築く成果も得られ、初期の目的を充分達成したとの評価であった。 3.一般学術図書の出版準備構成の検討と執筆者の選定を行い、″New Challenges in Organic Electrochemistry″の英文図書としてGordon and Breach, Science Publishers, Inc.より平成10年2月に出版するべく準備を進めている。

Research Products

(14 results)

All Other

All Publications (14 results)

[Publications] Tetsuo Osa: "Preparative, Electroenzymatic Reduction of NAD^+ to NADH on a Thin Poly (Acrylic Acid) Layer-Coaated Graphite Felt Electrode Coimmobilizing Ion-paired Methylviologen-Cation Exchange Polymer and Diaphorase" Chemistry Letter. 1093-1094 (1996)
[Publications] Tetsuo Osa: "Enantioselective, Electrocatalytic Oxidation of Racemic Alcohols on a TEMPO-modified Graphite Felt Electrode by Use of Chiral Base (TEMPO = 2, 2, 6, 6-tetramethylpiperidin-1-yloxyl)" Chemical Communications. 2745-2746 (1996)
[Publications] Tetsuo Osa: "Enantioselective, Electrocatalytic Lactonization of Methyl-substituted Diols on a TEMPO-modified Graphite Felt Electrode in the Presence of (-)-Sparteine" Chemistry Letter. 1043-1044 (1996)
[Publications] Tsutomu Nonaka: "Product-Selectivity Control in an Electroorganic Process by Temperature. Electroreduction of Acetophenone" Chemistry Letter. 862-862 (1995)
[Publications] Tsutomu Nonaka: "Ultrasonic Effects on Electroorganic Processes. Part4. Theeoretical and Experimental Studies on Product-selectivity in Electroreduction of Benzaldehyde and Benzoic Acid" Electroanalysis. (印刷中). (1997)
[Publications] Tsutomu Nonaka: "Ultrasonic Effects on Electroorganic Processes. Part5. Current Efficiency and Product Selectivity in Electroreduction of Alkyl Halides to Alkyl Stannanes at a Reactive Tin Cathode" Electrochimica Acta. (印刷中). (1997)
[Publications] Sigeru Torii: "Chemical and Electrochemical Asymmetric Dihydroxylation of Olefins in I_2-K_2CO_3-K_2OsO_2(OH)_4 and I_2-K_3PO_4/K_2HPO_3-K_2OsO_2(OH)_3Systems with Sharpless' Ligand" Journal of Organic Chemistry. 61. 3055-3061 (1996)
[Publications] Sigeru Torii: "Sythesis of 3-Chloro-Δ^3-cephem-4-caboxylate by Abbition/Cyclization of Allen-carboxylate. C0pper (II)-Promoted Aerobic Oxidatio of Arensulfinic Acids" Bulletin of the Chemical Society of Japan. (1996)
[Publications] Sigeru Torii: "Electrogeneration of Triphenyltin Radical, Anion and Cation. Electrochemical Initiation of Tin Hydride-Promoted Radical Chain Reactions" Journal of Organic Chemistry. 61. 9402-9408 (1996)
[Publications] Kiitiro Uchimoto: "Selective Cyclotrimerization of Acetylenes via Tantalum-Alkyne Complexes" Chemistry Letter. 851-852 (1995)
[Publications] Kiitiro Uchimoto: "Samarium-Mediated Highly Stereoselective Reaction of 1, 1-Dihaloalkanes with Aldehydes. Generation of Chiral a-Iodoethyl Building Block from Aciral 1, 1-Diiodoethane" Angewandte Chemie, International Edition in English. (印刷中). (1997)
[Publications] Hideaki Matsuoka: "Application of Multifunctional Microelectrode to the in vivo Analysis of the K^+ Response to CO_2 Stress" Bioelectrochemistry and Bioenergetcs. 39. 115-118 (1996)
[Publications] Hideaki Matsuoka: "Microinjection of Fluorescence Dye in a Plant Cell and Its Intercellular Translocation with a Multi-channel Microelectrode System" Biochimica Biophysica Acta. 1289. 1-4 (1996)
[Publications] Sigeru Torii: "Novel Trends in Electroorganic Synthesis" Kodansha Ltd., 374 (1995)

1996 Fiscal Year Annual Research Report

有機電気化学の新展開

Principal Investigator

長 哲郎 東北大学, 名誉教授 (10010753)

Research Products

[Publications] Tetsuo Osa: "Preparative, Electroenzymatic Reduction of NAD^+ to NADH on a Thin Poly (Acrylic Acid) Layer-Coaated Graphite Felt Electrode Coimmobilizing Ion-paired Methylviologen-Cation Exchange Polymer and Diaphorase" Chemistry Letter. 1093-1094 (1996)

[Publications] Tetsuo Osa: "Enantioselective, Electrocatalytic Oxidation of Racemic Alcohols on a TEMPO-modified Graphite Felt Electrode by Use of Chiral Base (TEMPO = 2, 2, 6, 6-tetramethylpiperidin-1-yloxyl)" Chemical Communications. 2745-2746 (1996)

[Publications] Tetsuo Osa: "Enantioselective, Electrocatalytic Lactonization of Methyl-substituted Diols on a TEMPO-modified Graphite Felt Electrode in the Presence of (-)-Sparteine" Chemistry Letter. 1043-1044 (1996)

[Publications] Tsutomu Nonaka: "Product-Selectivity Control in an Electroorganic Process by Temperature. Electroreduction of Acetophenone" Chemistry Letter. 862-862 (1995)

[Publications] Tsutomu Nonaka: "Ultrasonic Effects on Electroorganic Processes. Part4. Theeoretical and Experimental Studies on Product-selectivity in Electroreduction of Benzaldehyde and Benzoic Acid" Electroanalysis. (印刷中). (1997)

[Publications] Tsutomu Nonaka: "Ultrasonic Effects on Electroorganic Processes. Part5. Current Efficiency and Product Selectivity in Electroreduction of Alkyl Halides to Alkyl Stannanes at a Reactive Tin Cathode" Electrochimica Acta. (印刷中). (1997)

[Publications] Sigeru Torii: "Chemical and Electrochemical Asymmetric Dihydroxylation of Olefins in I_2-K_2CO_3-K_2OsO_2(OH)_4 and I_2-K_3PO_4/K_2HPO_3-K_2OsO_2(OH)_3Systems with Sharpless' Ligand" Journal of Organic Chemistry. 61. 3055-3061 (1996)

[Publications] Sigeru Torii: "Sythesis of 3-Chloro-Δ^3-cephem-4-caboxylate by Abbition/Cyclization of Allen-carboxylate. C0pper (II)-Promoted Aerobic Oxidatio of Arensulfinic Acids" Bulletin of the Chemical Society of Japan. (1996)

[Publications] Sigeru Torii: "Electrogeneration of Triphenyltin Radical, Anion and Cation. Electrochemical Initiation of Tin Hydride-Promoted Radical Chain Reactions" Journal of Organic Chemistry. 61. 9402-9408 (1996)

[Publications] Kiitiro Uchimoto: "Selective Cyclotrimerization of Acetylenes via Tantalum-Alkyne Complexes" Chemistry Letter. 851-852 (1995)

[Publications] Kiitiro Uchimoto: "Samarium-Mediated Highly Stereoselective Reaction of 1, 1-Dihaloalkanes with Aldehydes. Generation of Chiral a-Iodoethyl Building Block from Aciral 1, 1-Diiodoethane" Angewandte Chemie, International Edition in English. (印刷中). (1997)

[Publications] Hideaki Matsuoka: "Application of Multifunctional Microelectrode to the in vivo Analysis of the K^+ Response to CO_2 Stress" Bioelectrochemistry and Bioenergetcs. 39. 115-118 (1996)

[Publications] Hideaki Matsuoka: "Microinjection of Fluorescence Dye in a Plant Cell and Its Intercellular Translocation with a Multi-channel Microelectrode System" Biochimica Biophysica Acta. 1289. 1-4 (1996)

[Publications] Sigeru Torii: "Novel Trends in Electroorganic Synthesis" Kodansha Ltd., 374 (1995)

長哲郎東北大学, 名誉教授 (10010753)