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1996 Fiscal Year Final Research Report Summary

Intercalation-Control and Establishment of Reaction Sites

Research Project

Project/Area Number 08355019
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section企画調査
Research Field 無機工業化学
Research InstitutionTokyo Institute of Technology

Principal Investigator

WAKIHARA Masataka  Tokyo Institute of Technology, Professor, 工学部, 教授 (20016596)

Co-Investigator(Kenkyū-buntansha) ENOKI Toshiaki  Tokyo Institute of Technology, Professor, 理学部, 教授 (10113424)
UCHIDA Takashi  Tokyo Institute of Technology, Associate Professor, 工学部, 助教授 (10126310)
UCHIDA Isamu  Tohoku, University, Professor, 工学部, 教授 (50005302)
INAGAKI Michio  Hokkaido, University, Professor, 工学部, 教授 (20023054)
ATAKE Tooru  Tokyo Institute of Technology, Professor, 応用セラミックス研究所, 教授 (30028229)
Project Period (FY) 1996
KeywordsIntercalation / Control and establishment of reaction sites / energy problem / Catalytic activity / Electrochemical property
Research Abstract

"Intercalation" includes interactions and transfer of ions and/or charge between various guest molecules and host materials which are natural or artificially produced as the results of topotactic reactions, and provides solid-solutions, phase transformation, and catalytic activities. In the present Project, on the basis of the principle of the "Control and Establishment of Reaction Sites", varieties of investigators in wide range of scientific fields have gathered together, and totally discussed about the basic idea to develop highly functional intercalation materials.
The meeting was held on December 26-27,1996 in KKR "Hamayuu" located in Numazu, Shizuoka-Prefecture, with 27 members. In this meeting, following subjects have been discussed : 1) transport of electron in ion-electron mixed conductor, 2) trace of the change in the valence sate of iron using Mossbauer effect, 3) application of hetero-junction between different solid elctrolyte to sensors, 4) intercalation into materials showing strong electron nteraction, 5) photo catalytical activity of layred perovskite type composite oxides, 6) synthesis of metal chalcogenides having low dimensional structure by means of mechanical alloying method, 7) intercalation of lithium or hydrogen into carbon materials, 8) diffusion of lithium in spinel oxides, 9) novel cathode materials related to lithium-manganese oxide, 10) intercalation of lithium into lithium-transition metal nitrides, 11) STM observation of graphite surface intercalated with lithium, and so on.
Among the discussion, varity of mutual relationship between different subjects have been strongly pointed out, and the importance of this kind of discussion have, again, recognized.

  • Research Products

    (25 results)

All Other

All Publications (25 results)

  • [Publications] M.Wakihara et al.: "Chemical diffusion coefficient of lithium in LiM_yMn_<2-y>O_4 (M=Co and Cr)" Solid State Ionics. 86-88. 907-909 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Uchida et al.: "Chemical diffusion coefficient of lithium in carbon fiber" J. Electrochem. Soc.143. 2606-2610 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] I.Uchida et al.: "Detection of Microspotted Carcinoembryonic Antigen on a Glass Substrate by Seanning Electrochemical Microscopy" Anal Chem.68. 1276-1278 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Kudo et al.: "Consideration on the Potential-Composition Relationships Observed with Amorphous Intercalation Systems Such as Li_xWO_3" Solid State Ionics. 184. 65-72 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Osaka et al.: "Magnetic Force Microscopy Analysis of the Micromagnetization Mode of ouble-Layered Perpendicular Magnetic Recording Media" J. Vac. Sci. Technl. B. 14. 1184-1187 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Ohzuku et al.: "Synthesis and Characterization of LiAl_<1/4>Ni_<3/4>O_2(R3M) for Lithium-lon (shuttlecock) Batteries" J. Electrochm. Soc.143. 4033-4039 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] O.Yamamoto et al.: "Synthesis and Electrochemical Studies of a New Anode Material,Li_<3-x>Co_xN" Solid State Ionics. 83. 107-111 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Domen et al.: "Layered Niobium Oxides-Pillaring and Exfoliation" Catalysis Today. 28. 167-174 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Takano et al.: "Hydrothermal Synthesis,Crystal-Structure,and Magnetic-Properties of FeVo_4-II" J.Solid State Chem.123. 54-59 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Morita et al.: "Behavior of the Interface Between Lithium Electrodes and Organic Electrolyte-Solutions" Electrocim. Acta. 41. 1253-1258 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] N.Kumagai et al.: "Physical and Electrochemical Characterization of Quaternary Li-Mn-V-O Spinel as Positive Materials for Rechargeable Lithium Batteries" J. Electrochem. Soc.143. 1007-1013 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] R.Kanno et al.: "Synthesis of ZrF_4-BaF_2LnF(3) Glasses (Ln=la,Ce,Pr,Nd,or Eu) by Combined Processes of Sol-Gel and Fluorination" J. Alloy and Compounds. 232. 53-59 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Miura et al.: "Lithiation Characteristics of Cu_5V_2O_<10>" Electrochim. Acta. 41. 857-861 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Z.Ogumi et al.: "Electrochemical Scanning-Tunneling-Microscopy Observation of Highly Oriented Pyrolytic-Graphite Surface-Reactions in an Ethylene Carbonate-Based Electrolyte Solution" Langmuir. 12. 1535-1540 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 脇原将孝ら: "最新電池ハンドブック" 朝倉書店, 922 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Wakihara et al, T.Uchida: "Chemical Diffusion Coefficients of Lithium in LiM,Mn_<2-y>O_4 (M=Co and Cr)" Solid State Ionics. 86-88. 907-909 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Uchida, Y.Morikawa, H.Ikuta, M.Wakihara: "Chemical Diffusion Coefficients of Lithium in Carbon Fiber" J.Electrochem.Soc.143. 2606-2610 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] I.Uchida et al.: "Detection of Microspotted, Carcinoembryonic Antigen on a Glass Substrate by Scanning Electrochemical Microscopy" Anal Chem.68. 1276-1278 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Kudo et al.: "Consideration on the Potential-Composition Relationships Observed with Amorphous Intercalation Systems Such as Li_xWO_3" Solid State Ionics. 184. 65-72 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Osaka et al.: "Magnetic Force Microscopy Analysis of the Micromagnetization Mode of double-Layred Perpendicular Magnetic Recording Media" J.Vac.Sci.Technl.B. 14. 1184-1187 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Ohzuku et al.: "Synthesis and Characterization of LiAl_<1/4>Ni_<3/4>O_2 (R3M) for Lithium-Ion (Shuttlecock) Batteries" J.Electrochem.Soc.143. 4033-4039 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] O.Yamamoto et al.: "Synthesis and Electrochemical Studies of a New Anode Material, Li_<3-x>Co_xN" Solid State Ionics. 83. 107-111 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Domen et al.: "Layred Niobium Oxides-Pillaring and Exfoliation" Catalysis Today. 28. 167-174 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.Takano et al.: "Hydrothermal Synthesis, Crystal-Structure, and Magnetic-Properties of FeVO_4-II" J.Solid State Chem.123. 54-59 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.Morita et al.: "Behavior of the Interface Between Lithium Electrodes and Organic Electrolyte-Solutions" Electrochim.Acta. 41. 1253-1258 (1996)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 1999-03-09  

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