1999 Fiscal Year Annual Research Report

「集積型金属錯体」研究の総括

Research Project

Project/Area Number	10149101
Research Institution	Tohoku University
Principal Investigator	伊藤翼東北大学, 大学院・理学研究科, 教授 (90007328)
Co-Investigator(Kenkyū-buntansha)	山口兆大阪大学, 大学院・理学研究科, 教授 (80029537) 山本隆一東京工業大学, 資源化学研究所, 教授 (10016743) 大川尚士九州大学, 大学院・理学研究科, 教授 (00037219) 北川進京都大学, 大学院・工学研究科, 教授 (20140303) 加藤礼三理化学研究所, 主任研究員 (80169531)
Keywords	集積型金属錯体 / 金属クラスター錯体 / 超分子 / 錯体集合体 / 分子集合体 / 混合原子価錯体 / 協同効果 / 多重機能
Research Abstract	(1)総括班会議の開催 : 研究方針,研究実施計画,予算配分・執行に関する打ち合わせ. 第1回(東京,平成11年6月26日),第2回(京都,平成11年11月30日),第3回(大阪,平成12年1月24日) (2)研究会の開催 (a)平成11年度研究計画発表会(東京,平成11年6月24-26日) :研究実施班員79名全員による研究計画概要の発表. (b)A03/A05合同班会議(和光市,平成11年8月16-17日). (c)A04班会議(北海道,平成11年9月27日). (d)国際シンポジウム"Molecular Design and Functionality of Assembled Metal Complexes"(京都,平成11年11月30日-12月2日) :外国人11名,日本人11名による講演,ポスター発表117件.参加者185名. (e)公開シンポジウム平成11年度研究成果報告会(大阪,平成12年1月24-25日) :2件の招待講演を含む12件の講演」,並びに研究実施班員全員の研究成果豊国発表. (3)出版物の発行 (a)広報,ニュースレター:第4号(班員名簿・班員の研究概要,平成11年6月),第5号(ニュースレター,平成11年9月),第6号(ニュースレター,平成12年3月). (b)講演要旨集:A03/A05合同班会議講演要旨集(平成11年8月),A04班会議要旨集(平成11年9月),国際シンポジウム"Molecular Design and Functionality of Assembled Metal Complexes"要旨集(平成11年11月),公開シンポジウム要旨集(平成12年1月) (c)平成11年度研究成果報告書(平成12年3月)

Research Products
(28 results)

All Other

All Publications (28 results)

[Publications] 大川尚士: "Teracopperassemblry Complexes Comprised of One Dimetallic and Two Monometallic Auxiliaries : Intramolecular Electron-Transfer Relevant to Multicopper Oxidases"Inorg. Chem.. 38. 1825-1830 (1999)
[Publications] 大川尚士: "Template Syntheses and Properties of Copper(II)-Lanthanide(III)Complexes of Phenol-Based Symmetric and Unsymmetric Dinucleating Macrocycles"Inorg. Chem.. 48. 1-13 (1999)
[Publications] 大川尚士: "Oxygenation of Heterodinuclear Di(m-phenoxo)CoIIMII(M=Mn, Fe, Co) Complexes Having 'Co(salen)' Entity in A Macrocyclic Framework"J. Chem. Soc., Dalton Trans.. 12. 2197-2203 (1999)
[Publications] 大川尚士: "Di(μ-phenoxo)CoIIMII(M=Mn, Co, Zn)Complexes with 'Co(salen)' Entity in Macrocyclic Framework : Core Structures and Neighboring MII Effect upon Oxygenation at the 'Co(salen)' Center"Inorg. Chem.. 38. 4038-4044 (1999)
[Publications] 大川尚士: "[Mn(en)]_3[Cr(CN)_6]_2・4H_2O : A Three-dimensional Dimetallic Ferrimagnet (Tc=69K) with A Defective Cubane Unit"Angew. Chem. Int. Ed.. 38. 1795-1798 (1999)
[Publications] 大川尚士: "Dinuclear and Tetanuclear Copper(II) Complexes with Bridging (N-N) Diazine Ligands : Variable Magnetic Topologies"J. Chem. Soc. Dalton Trans. 1. 69-77 (2000)
[Publications] 山本隆一: "Synthesis of Ru-and Os-Complexes of pi-Conjugated Oligomers of 2,2'-Bipyridine and 5,5-Bipyrimidine. Optical Properties and Catalytic Activity for Photoevolution of Hydrogen from Aqueous Media"Bull. Chem. Soc. Jpn.. 72. 1153-1162 (1999)
[Publications] 山本隆一: "Ni-Promoted Syntheses of New 3,3'-Dichloro-5,5'-bipyrazoles and Poly(bipyrazole-5,5'-diyl)s and Isolation of Nickel Complexes Relevant to the Synthesis"Bull. Chem. Soc. Jpn.. 72. 1629-1635 (1999)
[Publications] 山本隆一: "Preparation of pi-Conjugated Polymers Composed of Hydroquinone, π-Benzquinone, and π-Diacetoxyphenylene Units, Optical and Redox Properties of the Polymers"Macromolecules. 32. 8886-8896 (1999)
[Publications] 山本隆一: "1 : 2 Polycondensation of 3,3', 4,4'-Biphenyltetramine and 1.1'-Ferrocenedimethanol Catalyzed by Dichlorotris(triphenylphosphine)ruthenium(II) to Give Polybenzimidazole Containing Ferrocenylene Group"Bull. Chem. Soc. Jpn.. 72. 2557-2562 (1999)
[Publications] 山本隆一: "Control of Reductive Elimination and Acidolysis of Diarylnickel(II) Complexes by the Kind of Broensted Acid and the Presence of Oxygen"Chem, Lett.. 419-420 (1999)
[Publications] 山本隆一: "Theoretical Studics on Anomalous Phases in Molecular Systems with External Field : Possibility of Photo-Induced Superconductivity"Int. J. Quant. Chem.. 75. 549-561 (1999)
[Publications] 山口兆: "Formulation and Numerical Approach to Molecular System by the Green Function Method without the Born-Oppenheimer Approximation"J. Chem. Phys.. 111. 6171-6179 (1999)
[Publications] 山口兆: "Dynamics of Photon Phase and Information Entropy for a Two-state Molecular System Interacting with Amplitude- and Phase-squeezed Fields"J. Phys. Chem.. A103. 6036-6048 (1999)
[Publications] 山口兆: "Density Functional Study of Intermolecular Ferromagnetic Interaction Through μ-Phenylene Coupling Unit. III. Possibility of High Spin Polymer"J. Chem. Phys.. 111. 1309-1324 (1999)
[Publications] 山口兆: "Calculation of Frequency-Dependent First Hyperpolsaizabilities Using the Second-Order Moller-Plesset Perturbation Theory"J. Chem. Phys.. 110. 1720-1733 (1999)
[Publications] 山口兆: "Calculation of Frequency-Dependent Second Hyperpolsrizabilities for Electronic Field Induced Second Harmonic Generation in the Second-Order Moller-Plesset Perturbation Theory"J. Chem. Phys.. 111. 842-848 (1999)
[Publications] 伊藤翼: "A Short Platinum to Silver Dative Bond and its Application in the Construction of Extended Structures : Syntheses and Structures of Ag_2[Pt(ox)_2]・2H_2O and [Ag_2(H_2O]_2[Ag_2(CF_2SO_3)_4][Pt(acac)_2]_2"J. Chem. Soc., Dalton Trans.. 273-274 (1999)
[Publications] 伊藤翼: "Electron Transfer on Infrared Vibational Time Scale in the Mixed Valence State of 1,4-Pyrazinc and 4,4'-Bipyridine Bridged Ruthenium Cluster Complexes"J. Am. Chem. Soc.. 121. 4625-4632 (1999)
[Publications] 伊藤翼: "The First Examples of Platinum(II)-Cadmium(II) Bonds : The Role of Strong Field Ligands in Making Dative Pt-M bonds"J. Am. Chem. Soc.. 121. 7405-7406 (1999)
[Publications] 伊藤翼: "Syntheses and Properties of a Series of Oxo-Centered Triruthenium Complexes and Their Bridged Dimers with Isocyanide Ligands at Terminal and Bridging Positions"Inorg. Chem.. 38. 4070-4078 (1999)
[Publications] 伊藤翼: "Syntheses and Structures of Bridge and Chelate Isomers of Tetraplatinum(II) Cluster Complex with Diethydithiophosphate ion (Et_2dtp) at In-planc Sites. [Pt_4(CH_3COO)_4(Et_2dtp)_4]. And Their Mutual Isomerization via Cluster Core Rotation"J. Am. Chem. Soc.. 121. 10738-10742 (1999)
[Publications] 伊藤翼: "Cyanide-Bridged Iron-Copper Molecular Squares with Doublet and Quintet Spin Ground States"Inorg. Chem.. 38. 5686-5689 (1999)
[Publications] 伊藤翼: "Low Temperature Structural Studies in the Molecular β'-Pd(dmit)_2 Conductors"Phys. Rev.. B60. 3113-3119 (1999)
[Publications] 加藤礼三: "Two-band System : A Candidate for New Molecular Materials"Synth. Met.. 103. 2020-2023 (1999)
[Publications] 加藤礼三: "Conductive Copper Salts of 2,5-Disubstituted N,N'Dicyanobenzoquinonediimines (DCNOIs) : Structural and Physical Properties" (Accounts)"Bull, Chem. Soc. Jpn.. 73(in press). (2000)
[Publications] 加藤礼三: "Anomalous Rolr of Carbon and Nitrogen Isotopes in (DMe-DCNQI)_2Cu System"Synth. Met.. 102. 1749-1750 (1999)
[Publications] 加藤礼三: "Low Temperature X-ray Study of Purely One-dimensional Electronic System, Me_4X(CPDT-TCNO)_2(X=As, N)"Synth. Met.. 103. 2212-2213 (1999)

1999 Fiscal Year Annual Research Report

「集積型金属錯体」研究の総括

Principal Investigator

伊藤 翼 東北大学, 大学院・理学研究科, 教授 (90007328)

Research Products

[Publications] 大川 尚士: "Teracopperassemblry Complexes Comprised of One Dimetallic and Two Monometallic Auxiliaries : Intramolecular Electron-Transfer Relevant to Multicopper Oxidases"Inorg. Chem.. 38. 1825-1830 (1999)

[Publications] 大川 尚士: "Template Syntheses and Properties of Copper(II)-Lanthanide(III)Complexes of Phenol-Based Symmetric and Unsymmetric Dinucleating Macrocycles"Inorg. Chem.. 48. 1-13 (1999)

[Publications] 大川 尚士: "Oxygenation of Heterodinuclear Di(m-phenoxo)CoIIMII(M=Mn, Fe, Co) Complexes Having 'Co(salen)' Entity in A Macrocyclic Framework"J. Chem. Soc., Dalton Trans.. 12. 2197-2203 (1999)

[Publications] 大川 尚士: "Di(μ-phenoxo)CoIIMII(M=Mn, Co, Zn)Complexes with 'Co(salen)' Entity in Macrocyclic Framework : Core Structures and Neighboring MII Effect upon Oxygenation at the 'Co(salen)' Center"Inorg. Chem.. 38. 4038-4044 (1999)

[Publications] 大川 尚士: "[Mn(en)]_3[Cr(CN)_6]_2・4H_2O : A Three-dimensional Dimetallic Ferrimagnet (Tc=69K) with A Defective Cubane Unit"Angew. Chem. Int. Ed.. 38. 1795-1798 (1999)

[Publications] 大川 尚士: "Dinuclear and Tetanuclear Copper(II) Complexes with Bridging (N-N) Diazine Ligands : Variable Magnetic Topologies"J. Chem. Soc. Dalton Trans. 1. 69-77 (2000)

[Publications] 山本 隆一: "Synthesis of Ru-and Os-Complexes of pi-Conjugated Oligomers of 2,2'-Bipyridine and 5,5-Bipyrimidine. Optical Properties and Catalytic Activity for Photoevolution of Hydrogen from Aqueous Media"Bull. Chem. Soc. Jpn.. 72. 1153-1162 (1999)

[Publications] 山本 隆一: "Ni-Promoted Syntheses of New 3,3'-Dichloro-5,5'-bipyrazoles and Poly(bipyrazole-5,5'-diyl)s and Isolation of Nickel Complexes Relevant to the Synthesis"Bull. Chem. Soc. Jpn.. 72. 1629-1635 (1999)

[Publications] 山本 隆一: "Preparation of pi-Conjugated Polymers Composed of Hydroquinone, π-Benzquinone, and π-Diacetoxyphenylene Units, Optical and Redox Properties of the Polymers"Macromolecules. 32. 8886-8896 (1999)

[Publications] 山本 隆一: "1 : 2 Polycondensation of 3,3', 4,4'-Biphenyltetramine and 1.1'-Ferrocenedimethanol Catalyzed by Dichlorotris(triphenylphosphine)ruthenium(II) to Give Polybenzimidazole Containing Ferrocenylene Group"Bull. Chem. Soc. Jpn.. 72. 2557-2562 (1999)

[Publications] 山本 隆一: "Control of Reductive Elimination and Acidolysis of Diarylnickel(II) Complexes by the Kind of Broensted Acid and the Presence of Oxygen"Chem, Lett.. 419-420 (1999)

[Publications] 山本 隆一: "Theoretical Studics on Anomalous Phases in Molecular Systems with External Field : Possibility of Photo-Induced Superconductivity"Int. J. Quant. Chem.. 75. 549-561 (1999)

[Publications] 山口 兆: "Formulation and Numerical Approach to Molecular System by the Green Function Method without the Born-Oppenheimer Approximation"J. Chem. Phys.. 111. 6171-6179 (1999)

[Publications] 山口 兆: "Dynamics of Photon Phase and Information Entropy for a Two-state Molecular System Interacting with Amplitude- and Phase-squeezed Fields"J. Phys. Chem.. A103. 6036-6048 (1999)

[Publications] 山口 兆: "Density Functional Study of Intermolecular Ferromagnetic Interaction Through μ-Phenylene Coupling Unit. III. Possibility of High Spin Polymer"J. Chem. Phys.. 111. 1309-1324 (1999)

[Publications] 山口 兆: "Calculation of Frequency-Dependent First Hyperpolsaizabilities Using the Second-Order Moller-Plesset Perturbation Theory"J. Chem. Phys.. 110. 1720-1733 (1999)

[Publications] 山口 兆: "Calculation of Frequency-Dependent Second Hyperpolsrizabilities for Electronic Field Induced Second Harmonic Generation in the Second-Order Moller-Plesset Perturbation Theory"J. Chem. Phys.. 111. 842-848 (1999)

[Publications] 伊藤 翼: "A Short Platinum to Silver Dative Bond and its Application in the Construction of Extended Structures : Syntheses and Structures of Ag_2[Pt(ox)_2]・2H_2O and [Ag_2(H_2O]_2[Ag_2(CF_2SO_3)_4][Pt(acac)_2]_2"J. Chem. Soc., Dalton Trans.. 273-274 (1999)

[Publications] 伊藤 翼: "Electron Transfer on Infrared Vibational Time Scale in the Mixed Valence State of 1,4-Pyrazinc and 4,4'-Bipyridine Bridged Ruthenium Cluster Complexes"J. Am. Chem. Soc.. 121. 4625-4632 (1999)

[Publications] 伊藤 翼: "The First Examples of Platinum(II)-Cadmium(II) Bonds : The Role of Strong Field Ligands in Making Dative Pt-M bonds"J. Am. Chem. Soc.. 121. 7405-7406 (1999)

[Publications] 伊藤 翼: "Syntheses and Properties of a Series of Oxo-Centered Triruthenium Complexes and Their Bridged Dimers with Isocyanide Ligands at Terminal and Bridging Positions"Inorg. Chem.. 38. 4070-4078 (1999)

[Publications] 伊藤 翼: "Cyanide-Bridged Iron-Copper Molecular Squares with Doublet and Quintet Spin Ground States"Inorg. Chem.. 38. 5686-5689 (1999)

[Publications] 伊藤 翼: "Low Temperature Structural Studies in the Molecular β'-Pd(dmit)_2 Conductors"Phys. Rev.. B60. 3113-3119 (1999)

[Publications] 加藤 礼三: "Two-band System : A Candidate for New Molecular Materials"Synth. Met.. 103. 2020-2023 (1999)

[Publications] 加藤 礼三: "Conductive Copper Salts of 2,5-Disubstituted N,N'Dicyanobenzoquinonediimines (DCNOIs) : Structural and Physical Properties" (Accounts)"Bull, Chem. Soc. Jpn.. 73(in press). (2000)

[Publications] 加藤 礼三: "Anomalous Rolr of Carbon and Nitrogen Isotopes in (DMe-DCNQI)_2Cu System"Synth. Met.. 102. 1749-1750 (1999)

[Publications] 加藤 礼三: "Low Temperature X-ray Study of Purely One-dimensional Electronic System, Me_4X(CPDT-TCNO)_2(X=As, N)"Synth. Met.. 103. 2212-2213 (1999)

伊藤翼東北大学, 大学院・理学研究科, 教授 (90007328)

[Publications] 大川尚士: "Teracopperassemblry Complexes Comprised of One Dimetallic and Two Monometallic Auxiliaries : Intramolecular Electron-Transfer Relevant to Multicopper Oxidases"Inorg. Chem.. 38. 1825-1830 (1999)

[Publications] 大川尚士: "Template Syntheses and Properties of Copper(II)-Lanthanide(III)Complexes of Phenol-Based Symmetric and Unsymmetric Dinucleating Macrocycles"Inorg. Chem.. 48. 1-13 (1999)

[Publications] 大川尚士: "Oxygenation of Heterodinuclear Di(m-phenoxo)CoIIMII(M=Mn, Fe, Co) Complexes Having 'Co(salen)' Entity in A Macrocyclic Framework"J. Chem. Soc., Dalton Trans.. 12. 2197-2203 (1999)

[Publications] 大川尚士: "Di(μ-phenoxo)CoIIMII(M=Mn, Co, Zn)Complexes with 'Co(salen)' Entity in Macrocyclic Framework : Core Structures and Neighboring MII Effect upon Oxygenation at the 'Co(salen)' Center"Inorg. Chem.. 38. 4038-4044 (1999)

[Publications] 大川尚士: "[Mn(en)]_3[Cr(CN)_6]_2・4H_2O : A Three-dimensional Dimetallic Ferrimagnet (Tc=69K) with A Defective Cubane Unit"Angew. Chem. Int. Ed.. 38. 1795-1798 (1999)

[Publications] 大川尚士: "Dinuclear and Tetanuclear Copper(II) Complexes with Bridging (N-N) Diazine Ligands : Variable Magnetic Topologies"J. Chem. Soc. Dalton Trans. 1. 69-77 (2000)

[Publications] 山本隆一: "Synthesis of Ru-and Os-Complexes of pi-Conjugated Oligomers of 2,2'-Bipyridine and 5,5-Bipyrimidine. Optical Properties and Catalytic Activity for Photoevolution of Hydrogen from Aqueous Media"Bull. Chem. Soc. Jpn.. 72. 1153-1162 (1999)

[Publications] 山本隆一: "Ni-Promoted Syntheses of New 3,3'-Dichloro-5,5'-bipyrazoles and Poly(bipyrazole-5,5'-diyl)s and Isolation of Nickel Complexes Relevant to the Synthesis"Bull. Chem. Soc. Jpn.. 72. 1629-1635 (1999)

[Publications] 山本隆一: "Preparation of pi-Conjugated Polymers Composed of Hydroquinone, π-Benzquinone, and π-Diacetoxyphenylene Units, Optical and Redox Properties of the Polymers"Macromolecules. 32. 8886-8896 (1999)

[Publications] 山本隆一: "1 : 2 Polycondensation of 3,3', 4,4'-Biphenyltetramine and 1.1'-Ferrocenedimethanol Catalyzed by Dichlorotris(triphenylphosphine)ruthenium(II) to Give Polybenzimidazole Containing Ferrocenylene Group"Bull. Chem. Soc. Jpn.. 72. 2557-2562 (1999)

[Publications] 山本隆一: "Control of Reductive Elimination and Acidolysis of Diarylnickel(II) Complexes by the Kind of Broensted Acid and the Presence of Oxygen"Chem, Lett.. 419-420 (1999)

[Publications] 山本隆一: "Theoretical Studics on Anomalous Phases in Molecular Systems with External Field : Possibility of Photo-Induced Superconductivity"Int. J. Quant. Chem.. 75. 549-561 (1999)

[Publications] 山口兆: "Formulation and Numerical Approach to Molecular System by the Green Function Method without the Born-Oppenheimer Approximation"J. Chem. Phys.. 111. 6171-6179 (1999)

[Publications] 山口兆: "Dynamics of Photon Phase and Information Entropy for a Two-state Molecular System Interacting with Amplitude- and Phase-squeezed Fields"J. Phys. Chem.. A103. 6036-6048 (1999)

[Publications] 山口兆: "Density Functional Study of Intermolecular Ferromagnetic Interaction Through μ-Phenylene Coupling Unit. III. Possibility of High Spin Polymer"J. Chem. Phys.. 111. 1309-1324 (1999)

[Publications] 山口兆: "Calculation of Frequency-Dependent First Hyperpolsaizabilities Using the Second-Order Moller-Plesset Perturbation Theory"J. Chem. Phys.. 110. 1720-1733 (1999)

[Publications] 山口兆: "Calculation of Frequency-Dependent Second Hyperpolsrizabilities for Electronic Field Induced Second Harmonic Generation in the Second-Order Moller-Plesset Perturbation Theory"J. Chem. Phys.. 111. 842-848 (1999)

[Publications] 伊藤翼: "A Short Platinum to Silver Dative Bond and its Application in the Construction of Extended Structures : Syntheses and Structures of Ag_2[Pt(ox)_2]・2H_2O and [Ag_2(H_2O]_2[Ag_2(CF_2SO_3)_4][Pt(acac)_2]_2"J. Chem. Soc., Dalton Trans.. 273-274 (1999)

[Publications] 伊藤翼: "Electron Transfer on Infrared Vibational Time Scale in the Mixed Valence State of 1,4-Pyrazinc and 4,4'-Bipyridine Bridged Ruthenium Cluster Complexes"J. Am. Chem. Soc.. 121. 4625-4632 (1999)

[Publications] 伊藤翼: "The First Examples of Platinum(II)-Cadmium(II) Bonds : The Role of Strong Field Ligands in Making Dative Pt-M bonds"J. Am. Chem. Soc.. 121. 7405-7406 (1999)

[Publications] 伊藤翼: "Syntheses and Properties of a Series of Oxo-Centered Triruthenium Complexes and Their Bridged Dimers with Isocyanide Ligands at Terminal and Bridging Positions"Inorg. Chem.. 38. 4070-4078 (1999)

[Publications] 伊藤翼: "Cyanide-Bridged Iron-Copper Molecular Squares with Doublet and Quintet Spin Ground States"Inorg. Chem.. 38. 5686-5689 (1999)

[Publications] 伊藤翼: "Low Temperature Structural Studies in the Molecular β'-Pd(dmit)_2 Conductors"Phys. Rev.. B60. 3113-3119 (1999)

[Publications] 加藤礼三: "Two-band System : A Candidate for New Molecular Materials"Synth. Met.. 103. 2020-2023 (1999)

[Publications] 加藤礼三: "Conductive Copper Salts of 2,5-Disubstituted N,N'Dicyanobenzoquinonediimines (DCNOIs) : Structural and Physical Properties" (Accounts)"Bull, Chem. Soc. Jpn.. 73(in press). (2000)

[Publications] 加藤礼三: "Anomalous Rolr of Carbon and Nitrogen Isotopes in (DMe-DCNQI)_2Cu System"Synth. Met.. 102. 1749-1750 (1999)

[Publications] 加藤礼三: "Low Temperature X-ray Study of Purely One-dimensional Electronic System, Me_4X(CPDT-TCNO)_2(X=As, N)"Synth. Met.. 103. 2212-2213 (1999)