2000 Fiscal Year Annual Research Report

「集積型金属錯体」研究の総括

Research Project

Project/Area Number	10149101
Research Institution	Tohoku University
Principal Investigator	伊藤翼東北大学, 大学院・理学研究科, 教授 (90007328)
Co-Investigator(Kenkyū-buntansha)	山口兆大阪大学, 大学院・理学研究科, 教授 (80029537) 山本隆一東京工業大学, 資源化学研究所, 教授 (10016743) 大川尚士九州大学, 大学院・理学研究院, 教授 (00037219) 北川進京都大学, 大学院・工学研究科, 教授 (20140303) 加藤礼三理化学研究所, 主任研究員 (80169531)
Keywords	集積型金属錯体 / 金属クラスター錯体 / 超分子 / 錯体集合体 / 分子集合体 / 混合原子価錯体 / 協同効果 / 多重機能
Research Abstract	(1)総括班会議・班長会議の開催:研究方針,研究実施計画,予算配分・執行に関する打ち合わせ. 第1回(札幌,平成12年7月1日,第2回(東京,平成12年8月12日),第3回(岐阜,平成13年1月16日) (2)研究会の開催 (a)平成12年度研究計画発表会(札幌,平成12年6月30日-7月1日):研究実施班員77名全員による研究計画概要の発表. (b)「集積型金属錯体の合成に関するシンポジウム」(熱海,平成12年10月28-29日). (c)「機能発現をめざした集積型金属錯体の設計戦略」(那覇,平成12年11月11日). (d)D.H.Buschアメリカ化学会長,H.Taube教授講演会(仙台,平成12年9月25日) (e)公開シンポジウム平成12年度研究成果報告会(岐阜,平成13年1月15-16日):2件の招待講演を含む9件の講演,並びに研究実施班員全員の研究成果報告発表. (f)研究会「ナノ金属錯体の展望」〔東京,平成13年2月3-4日):21件の講演 (g)研究会「新世紀の錯体化学」(札幌,平成13年2月17-18日):15件の講演 (3)出版物の発行 (a)広報,ニュースレター:第7号(班員名簿・班員の研究概要,平成12年6月),第8号(ニュースレター,平成12年9月),第9号(ニュースレター,平成13年3月(予定)). (b)講演要旨集:「集積型金属錯体の合成に関するシンポジウム」講演要旨集(平成12年10月),「機能発現をめざした集積型金属錯体の設計戦略」講演要旨集(平成12年11月),「平成12年度研究成果報告会・公開シンポジウム」講演要旨集(平成13年1月) (c)平成12年度研究成果報告書(平成13年3月)

Research Products
(32 results)

All Other

All Publications (32 results)

[Publications] 伊藤翼: "Unusual Redox State Dependent Fermi Resonances in the Infrared Spectra of Trinuclear Ruthenium Clusters with Isocyanide Ligands"Inorg.Chem.. 39. 2696-2698 (2000)
[Publications] 伊藤翼: "A Strongly Coupled Mixed Valence State between Ru_3 Clusters. Intramolecular Electron Transfer on the Infrared Vibrational Time Scale in a Pyrazine (pz) Bridged dimer of Triruthenium Clusters, [{Ru_3 (μ-O)(μ-CH_3CO_2)_6(CO)(abco)}_2(μ-pz)](abco=1-azabicyclo[2,2,2]octane"Bull.Chem.Soc.Jpn.. 73. 1205-1212 (2000)
[Publications] 伊藤翼: "Mixed-Valent Heptairon Complex with a Ground-State Spin of S=12/2 Constructed from a Triiron Cluster Ligand"Angew.Chem.Int.Ed.. 39. 230-233 (2000)
[Publications] 伊藤翼: "Superparamagnetic Behavior in an Alkoxo-Bridged Iron (II) Cube"J.Am.Chem.Soc.. 122. 12602-12603 (2000)
[Publications] 伊藤翼: "Rational Construction of Chiral Octanuclear Metallacycles Consisting of Octahedral Co^<III>, Square-Planar Pd^<II>, and Linear Au^I or Ag^I Ions"Angew.Chem.Int.Ed.. 39. 4098-40101 (2000)
[Publications] 伊藤翼: "A Helical Metal-Metal Bonded Chain via the Pt→Ag Dative Bond"J.Am.Chem.Soc.. 123. 743 (2001)
[Publications] 大川尚士: "A Mixed-metal Cu^<II>_2Ni^<II>_2 Complex Derived from A Phenol-based Heterotetranucleating Macrocyclic Ligand"Chem.Commun.. 4. 817-818 (2000)
[Publications] 大川尚士: "Bimetallic Dioxygen Complexes Derived from 'End-off' Compartmental Ligands"Coord.Chem.Rev.. 105-129 (2000)
[Publications] 大川尚士: "Bimetallic Dioxygen Complexes Derived from 'End-off' Compartmental Ligands"Coord.Chem.Rev.. 200-202 (2000)
[Publications] 大川尚士: "A Heterodinuclear Co^<II>Cu^I Complex with 'Co (salen)' in A Macrocyclic Framework. Oxygenation Studies in Comparison with Analogous Cu^<II>Cu^I and Co^<II>Pb^<II> Complexes"Inorg.Chem.. 39. 4520-4526 (2000)
[Publications] 大川尚士: "Trinuclear Cu^<II>M^<II>Cu^<II> Complexes of an Oxamide/Dioxime Ligand and Extension to A Bimetallic Magnetic Compound"J.Chem.Soc., Dalton Trans.. 1. 64-70 (2001)
[Publications] 大川尚士: "Dinuclear Zinc Complexes of Phenol-based 'End-off' Compartmental Ligands : Synthesis, Structures and Phosphatase-Like Activity"Bull.Chem.Soc.Jpn.. 74. 85-95 (2001)
[Publications] 山本隆一: "New Information on Linear and Stiff π-Conjugated Poly (pyridine-2,5-diyl)"J.Polym.Sci. : B,Polym.Phys.. 38. 1348-1351 (2000)
[Publications] 山本隆一: "π-Conjugated Polymers Prepared by Organometallic Polycondensation and Metal Complexes of the Polymers"Polym.Adv.Tech.. 11. 658-664 (2000)
[Publications] 山本隆一: "Synthesis and Properties of Europium Complex of Poybenzimidazole Containing N-Eu Bond"Mol.Cryst.Liq.Cryst.. 342. 57-62 (2000)
[Publications] 山本隆一: "Poly (pyridine-2,5-diyl)-CuCl_2 Catalyst for Synthesis of Dimethyl Carbonate by Oxidative Carbonylation of Methanol : Catalytic Activity and Corrosion Influence"J.Catalysis. 65. 123-126 (2000)
[Publications] 山本隆一: "Synthesis and Chemical Properties of π-Conjugated Zinc Porphyrin Polymers with Arylene and Aryleneethynylene Groups between Zinc Porphyrin Units"Macromolecules. 33. 5688-5994 (2000)
[Publications] 山口兆: "Quantum-phase and Information-entropy Dynamics of a Two-state Molecular System Interacting with Strongly Amplitude- and Phase- squeezed Fields"J.Chem.Phys.. 112. 2769-2780 (2000)
[Publications] 山口兆: "Density Functional Study of Intramolecular Ferromagnetic Interaction Through μ-Phenylene Coupling Unit (II) : Examination of Functional Dependence"J.Chem.Phys.. 113. 10486-10504 (2000)
[Publications] 山口兆: "Quantum Spin Dynamics by Path Integral Centroid Molecular Dynamics Method"Prog.Theoret.Phys.Suppl.. 138. 533-534 (2000)
[Publications] 山口兆: "Ab initio Computations of Effective Exchange Integrals for H-H, H-He-H and Mn_2O_2 Complex. Comparison of Broken-Symmetry Approaches"Chem.Phys.Lett.. 319. 223-230 (2000)
[Publications] 山口兆: "Theoretical Studies on Superconducting and Other Phases : Triplet Superconductivity, Ferromagnetism and Ferromagnetic Metals"Int.J.Quant.Chem.. 80. 721-732 (2000)
[Publications] 加藤礼三: "N, N'-Dicyanobenzoquinonediimines (DCNQIs) : Structural and Physical Properties"Bull.Chem.Soc.Jpn.. 73. 515-534 (2000)
[Publications] 加藤礼三: "Thermodynamical Study of (DMe-DCNQI) 2Cu System -Mechanism of Reentrant Metal-Insulator Transition-"J.Phys.Soc.Jpn.. 69. 1414-1422 (2000)
[Publications] 加藤礼三: "Design, Preparation, and Characterzation of Novel ET Salts with Supramolecular Assembly -Sheet and Chain Structures Based on Difluorotetraiodobenzene-"Chem.Lett.. 8. 970-971 (2000)
[Publications] 加藤礼三: "Magnetic Susceptibility of (DMe-DCNQI)_2Li_<1-x>CUx,"Solid State Communications. 114. 281-284 (2000)
[Publications] 加藤礼三: "Conducting Properties of Assembled Metal Complexes"Mol.Cryst.Liq.Cryst.. 343. 1-8 (2000)
[Publications] 北川進: "Allosteric Chirality Amplification in Zinc Bilinone Dimer"J.Am.Chem.Soc.. 122. 748-749 (2000)
[Publications] 北川進: "New Methane Adsorbent of Porous Coordination Polymer,[Cu(SiF_6)(4,4'-bipyridine)_2]^n"Angew.Che, Int.Ed.Engl.. 39. 2081-2084 (2000)
[Publications] 北川進: "Synthesis and Molecular Structure of the Amido-bridged Dinuclear rhodium Complex [Cp^*Rh{μ_2-(NH)_2C_<10>H_6-2,3}(μ_2-Cl)RhCp^*](Cp^*=η_5-C_5Me_5)"Mol.Cryst.Liq.Cryst.. 342. 1-6 (2000)
[Publications] 北川進: "Novel Layered Structures Constructed from Metal (II)-Chloranilate Monomer Compounds"J.Chem.Soc.Dalton Trans.. 2409-2417 (2000)
[Publications] 北川進: "New Molecular Assemblies of Redox Isomers,[CrIII (X4SQ)3-n(X4Cat)n]-n(X) Cl and Br, n)0,1, and 2), with Metallocenium Cations,[MIII Cp2]+(M) Co and Fe) : X-ray Crystal Structures and Physical Properties"Inorg.Chem. 40. 146-156 (2000)

2000 Fiscal Year Annual Research Report

「集積型金属錯体」研究の総括

Principal Investigator

伊藤 翼 東北大学, 大学院・理学研究科, 教授 (90007328)

Research Products

[Publications] 伊藤翼: "Unusual Redox State Dependent Fermi Resonances in the Infrared Spectra of Trinuclear Ruthenium Clusters with Isocyanide Ligands"Inorg.Chem.. 39. 2696-2698 (2000)

[Publications] 伊藤翼: "Mixed-Valent Heptairon Complex with a Ground-State Spin of S=12/2 Constructed from a Triiron Cluster Ligand"Angew.Chem.Int.Ed.. 39. 230-233 (2000)

[Publications] 伊藤翼: "Superparamagnetic Behavior in an Alkoxo-Bridged Iron (II) Cube"J.Am.Chem.Soc.. 122. 12602-12603 (2000)

[Publications] 伊藤翼: "Rational Construction of Chiral Octanuclear Metallacycles Consisting of Octahedral Co^<III>, Square-Planar Pd^<II>, and Linear Au^I or Ag^I Ions"Angew.Chem.Int.Ed.. 39. 4098-40101 (2000)

[Publications] 伊藤翼: "A Helical Metal-Metal Bonded Chain via the Pt→Ag Dative Bond"J.Am.Chem.Soc.. 123. 743 (2001)

[Publications] 大川尚士: "A Mixed-metal Cu^<II>_2Ni^<II>_2 Complex Derived from A Phenol-based Heterotetranucleating Macrocyclic Ligand"Chem.Commun.. 4. 817-818 (2000)

[Publications] 大川尚士: "Bimetallic Dioxygen Complexes Derived from 'End-off' Compartmental Ligands"Coord.Chem.Rev.. 105-129 (2000)

[Publications] 大川尚士: "Bimetallic Dioxygen Complexes Derived from 'End-off' Compartmental Ligands"Coord.Chem.Rev.. 200-202 (2000)

[Publications] 大川尚士: "A Heterodinuclear Co^<II>Cu^I Complex with 'Co (salen)' in A Macrocyclic Framework. Oxygenation Studies in Comparison with Analogous Cu^<II>Cu^I and Co^<II>Pb^<II> Complexes"Inorg.Chem.. 39. 4520-4526 (2000)

[Publications] 大川尚士: "Trinuclear Cu^<II>M^<II>Cu^<II> Complexes of an Oxamide/Dioxime Ligand and Extension to A Bimetallic Magnetic Compound"J.Chem.Soc., Dalton Trans.. 1. 64-70 (2001)

[Publications] 大川尚士: "Dinuclear Zinc Complexes of Phenol-based 'End-off' Compartmental Ligands : Synthesis, Structures and Phosphatase-Like Activity"Bull.Chem.Soc.Jpn.. 74. 85-95 (2001)

[Publications] 山本隆一: "New Information on Linear and Stiff π-Conjugated Poly (pyridine-2,5-diyl)"J.Polym.Sci. : B,Polym.Phys.. 38. 1348-1351 (2000)

[Publications] 山本隆一: "π-Conjugated Polymers Prepared by Organometallic Polycondensation and Metal Complexes of the Polymers"Polym.Adv.Tech.. 11. 658-664 (2000)

[Publications] 山本隆一: "Synthesis and Properties of Europium Complex of Poybenzimidazole Containing N-Eu Bond"Mol.Cryst.Liq.Cryst.. 342. 57-62 (2000)

[Publications] 山本隆一: "Poly (pyridine-2,5-diyl)-CuCl_2 Catalyst for Synthesis of Dimethyl Carbonate by Oxidative Carbonylation of Methanol : Catalytic Activity and Corrosion Influence"J.Catalysis. 65. 123-126 (2000)

[Publications] 山本隆一: "Synthesis and Chemical Properties of π-Conjugated Zinc Porphyrin Polymers with Arylene and Aryleneethynylene Groups between Zinc Porphyrin Units"Macromolecules. 33. 5688-5994 (2000)

[Publications] 山口兆: "Quantum-phase and Information-entropy Dynamics of a Two-state Molecular System Interacting with Strongly Amplitude- and Phase- squeezed Fields"J.Chem.Phys.. 112. 2769-2780 (2000)

[Publications] 山口兆: "Density Functional Study of Intramolecular Ferromagnetic Interaction Through μ-Phenylene Coupling Unit (II) : Examination of Functional Dependence"J.Chem.Phys.. 113. 10486-10504 (2000)

[Publications] 山口兆: "Quantum Spin Dynamics by Path Integral Centroid Molecular Dynamics Method"Prog.Theoret.Phys.Suppl.. 138. 533-534 (2000)

[Publications] 山口兆: "Ab initio Computations of Effective Exchange Integrals for H-H, H-He-H and Mn_2O_2 Complex. Comparison of Broken-Symmetry Approaches"Chem.Phys.Lett.. 319. 223-230 (2000)

[Publications] 山口兆: "Theoretical Studies on Superconducting and Other Phases : Triplet Superconductivity, Ferromagnetism and Ferromagnetic Metals"Int.J.Quant.Chem.. 80. 721-732 (2000)

[Publications] 加藤礼三: "N, N'-Dicyanobenzoquinonediimines (DCNQIs) : Structural and Physical Properties"Bull.Chem.Soc.Jpn.. 73. 515-534 (2000)

[Publications] 加藤礼三: "Thermodynamical Study of (DMe-DCNQI) 2Cu System -Mechanism of Reentrant Metal-Insulator Transition-"J.Phys.Soc.Jpn.. 69. 1414-1422 (2000)

[Publications] 加藤礼三: "Design, Preparation, and Characterzation of Novel ET Salts with Supramolecular Assembly -Sheet and Chain Structures Based on Difluorotetraiodobenzene-"Chem.Lett.. 8. 970-971 (2000)

[Publications] 加藤礼三: "Magnetic Susceptibility of (DMe-DCNQI)_2Li_<1-x>CUx,"Solid State Communications. 114. 281-284 (2000)

[Publications] 加藤礼三: "Conducting Properties of Assembled Metal Complexes"Mol.Cryst.Liq.Cryst.. 343. 1-8 (2000)

[Publications] 北川進: "Allosteric Chirality Amplification in Zinc Bilinone Dimer"J.Am.Chem.Soc.. 122. 748-749 (2000)

[Publications] 北川進: "New Methane Adsorbent of Porous Coordination Polymer,[Cu(SiF_6)(4,4'-bipyridine)_2]^n"Angew.Che, Int.Ed.Engl.. 39. 2081-2084 (2000)

[Publications] 北川進: "Synthesis and Molecular Structure of the Amido-bridged Dinuclear rhodium Complex [Cp^*Rh{μ_2-(NH)_2C_<10>H_6-2,3}(μ_2-Cl)RhCp^*](Cp^*=η_5-C_5Me_5)"Mol.Cryst.Liq.Cryst.. 342. 1-6 (2000)

[Publications] 北川進: "Novel Layered Structures Constructed from Metal (II)-Chloranilate Monomer Compounds"J.Chem.Soc.Dalton Trans.. 2409-2417 (2000)

[Publications] 北川進: "New Molecular Assemblies of Redox Isomers,[CrIII (X4SQ)3-n(X4Cat)n]-n(X) Cl and Br, n)0,1, and 2), with Metallocenium Cations,[MIII Cp2]+(M) Co and Fe) : X-ray Crystal Structures and Physical Properties"Inorg.Chem. 40. 146-156 (2000)

伊藤翼東北大学, 大学院・理学研究科, 教授 (90007328)

[Publications] 北川進: "Synthesis and Molecular Structure of the Amido-bridged Dinuclear rhodium Complex [Cp^Rh{μ_2-(NH)_2C_<10>H_6-2,3}(μ_2-Cl)RhCp^](Cp^*=η_5-C_5Me_5)"Mol.Cryst.Liq.Cryst.. 342. 1-6 (2000)