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2002 Fiscal Year Final Research Report Summary

Creation of Novel Silicon/Carbon Hybrid Materials based on Fullerene as a Key Molecule

Research Project

Project/Area Number 12304038
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Organic chemistry
Research InstitutionUniversity of Tsukuba (2001-2002)
Niigata University (2000)

Principal Investigator

AKASAKA Takeshi  Department of Chemistry, Professor, 化学系, 教授 (60089810)

Co-Investigator(Kenkyū-buntansha) NAGASE Shigeru  Institute for Molecular Science, Professor, 理論化学分野, 教授 (30134901)
WAKAHARA Takatsugu  Department of Chemistry, Assistant Professor, 化学系, 講師 (40303177)
SATO Soichi  Department of Chemistry, Assistant Professor, 化学系, 講師 (90280908)
OKAMURA Mutsuo  Niigata University, Assosiate Professor, 大学院・自然科学研究科, 助教授 (30215503)
Project Period (FY) 2000 – 2002
KeywordsPolsilane / Fullerene / Endohedral metallofullerenes
Research Abstract

Derivatization of fullerenes and endohedral metallofullerenes by the addition of silicon compounds has been developed. It is expected that these silicon derivatives will constitute an important stepping stone on the way to the material, catalytic, and biological applications. The chemical derivatization of endohedral metallofullerenes is especially interesting, since it could lead to new physical and chemical properties which the fullerene derivatives do not have, and provides a new stage in the chemistry of the endohedral metallofullerenes.

  • Research Products

    (12 results)

All Other

All Publications (12 results)

  • [Publications] T.Wakahara, Y.Niino, T.Kato, Y.Maeda, T.Akasaka, M.T.H.Liu, K.Kobayashi, S.Nagase: "A Non-spectroscopic Method to Determine the Photolytic Decomposition Pathways of 3-Chloro-3-alkyldiazirine ; Carbene, Diazo and Rearrangement in Excited State"J. Am. Chem. Soc.. 124. 9465-9468 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Takaguchi, T.Tajima, K.Ohta, J.Motoyoshiya, H.Aoyama, T.Wakahara, T.Akasaka, M.Fujitsuka, O.Ito: "Reversible C60 Binding to Anthracene Having Dendritic Poly(amide amine) Substituent Producing an Acidic Water-soluble Fullerodendrimer"Angew. Chem., Int. Ed. Engl.. 41. 817-819 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Wakahara, S.Ohkubo, M.Kondo, Y.Maeda, T.Akasaka, M.Waelchli, M.Kako, K.Kobayashi, S.Nagase, T.Kato, K.Yamamoto, X.Gao, E.V.Caemelbecke, K.M.Kadish: "Ionization and Structural Determination of the Major Isomer of Pr@C82"Chem. Phys. Lett.. 360. 235-239 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] N.Nakashima, M.Sakai, H.Murakami, T.Sagara, T.Wakahara, T.Akasaka: "Construction of a Metallofullerene La@C82/Artificial Lipid Film-Modified Electrode Device and Its Electron Transfer"J. Phys. Chem. B. 106. 3523-3525 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Wakahara, A.Han, Y.Niino, Y.Maeda, T.Akasaka T.Suzuki, K.Yamamoto, M.Kako, Y.Nakadaira, K.Kobayashi, S.Nagase: "Silylation of higher fullerenes"J. Mater. Chem.. 12. 2061-2064 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Niino, T.Wakahara, T.Akasaka, M.T.H.Liu, K.Kobayashi, S.Nagase: "Photochemical Decomposition of Pyrazoline Produced in the Reaction of C60 with Diazoadamantane"ITE Lett.. 3. C60-C63 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Wakahara, Y.Niino, T.Kato, Y.Maeda, T.Akasaka, M.T.H.Liu, K.Kobayashi, and S.Nagase: "A Non-spectroscopic Method to Determine the Photolytic Decomposition Pathways of 3-Chloro-3-alkyldiazirine ; Carbene, Diazo and Rearrangement in Excited State"J. Am. Chem Soc.. 124. 9465-9468 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Takaguchi, T.Tajima, K.Ohta, J.Motoyoshiya, H.Aoyama T.Wakahara, T.Akasaka, M.Fujitsuka and O.Ito: "Reversible C60 Binding to Anthracene Having Dendritic Poly(amide amine) Substituent Producing an Acidic Water-soluble Fullerodendrimer"Angew. Chem. Int. Ed. Engl.. 41. 817-819 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Wakahara, S.Ohkubo, M.Kondo, Y.Maeda, T.Akasaka, M.Waelchli, M.Kako, K.Kobayashi, S.Nagase, T.Kato, K.Yamamoto, X.Gao, E.V.Caemelbecke, and K.M.Kadish: "Ionization and Structural Determination of the Major Isomer of Pr@C82"Chem. Phys. Lett.. 360. 235-239 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] N.Nakashima, M.Sakai, H.Murakami, T.Sagara, T.Wakahara, and T.Akasaka: "Construction of a Metallofullerene La@C82/Artificial Lipid Film-Modified Electrode Device and Its Electron Transfer"J. Phys. Chem. B. 106. 3523-3525 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Wakahara, A.Han, Y.Niino, Y.Maeda, T.Akasaka, T.Suzuki, K.Yamamoto, M.Kako, Y.Nakadaira, K.Kobayashi, and S.Nagase: "Silylation of higher fullerenes"J. Mater. Chem.. 12. 2061-2064 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Niino, T.Wakahara, T.Akasaka, M.T.H.Liu K.Kobayashi and S.Nagase: "Photochemical Decomposition of Pyrazoline Produced in the Reaction of C60 with Diazoadamantane"ITE Lett.. 3. C60-C63 (2002)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 2004-04-14  

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