2002 Fiscal Year Annual Research Report

二酸化炭素を用いる新しい有機反応と新規高分子合成

Research Project

Project/Area Number	13450376
Research Institution	Yamagata University
Principal Investigator	遠藤剛山形大学, 工学部, 教授 (40016738)
Co-Investigator(Kenkyū-buntansha)	羽場修山形大学, 工学部, 助教授 (70261328)
Keywords	二酸化炭素 / 第三級アミン / 環境保護 / 有機合成化学 / 高分子合成 / 固定化反応
Research Abstract	二酸化炭素の化学的な回収、利用は環境、資源問題につながる重要な分野である。これまでに知られている二酸化炭素を用いた有機反応には第一級、第二級アミンとの反応によるカルバミン酸アンモニウム塩の生成が知られているが、第三級アミンと二酸化炭素が直接反応する例は報告されていない。これらの観点から我々は二酸化炭素と第三級アミンの反応に着目し、各種の第三級アミンとの反応の検討により、N, N, N'-トリアルキルアミジンが二酸化炭素と反応し双性イオンを与えることを見出している。さらに、生成した双性イオンは加熱により二酸化炭素を脱着し原料のアミンに戻り、可逆的に二酸化炭素をトラップ、脱着出来ることを見出している。平成14年度では、この新しく見出したアミジン類による二酸化炭素トラップ系を高分子材料へ応用することを目的に、測鎖にアミジン構造を有するポリマーを合成し、その二酸化炭素トラップ挙動について検討を行った。アミジン構造を持つポリマーとに酸化炭素の反応を溶媒中で行ったところ、低分子の場合と同様に効率良く二酸化炭素をトラップできることが分かった。さらに材料への応用を見据え、固相での二酸化炭素トラップ反応について検討した結果、アミジン構造を持つポリマーは固体状態でも二酸化炭素をトラップできることが分かった。また本ポリマーは良好な成膜性を有していたため、ポリマーフィルムを作成し同様に二酸化炭素との反応を検討したところ、ポリマーがフィルム状であっても反応が進行することが分かった。さらに、ポリマーフィルムについて反応の可逆性について検討したところ、加熱により二酸化炭素の脱着反応が進行し、可逆的に二酸化炭素をトラップできることが分かった。以上のことから、アミジン構造を持つポリマーはリサイクル性を有する二酸化炭素トラップ材料としての応用が期待され、現在工業化に向けてさらなる展開を検討中である。

Research Products

(16 results)

All Other

All Publications (16 results)

[Publications] 三田文雄: "Stepwise Synthesis of γ-Glutamic Acid 16-Mer"Macromolecular Chemistry and Physics. 203巻. 727-734 (2002)
[Publications] 須藤篤: "Selective Reduction of Main-Chain 2-Azetidinone Moieties into Azetidines for Polymer Reaction"Journal of Polymer Science Part A : Polymer Chemistry. 40巻. 1912-1917 (2002)
[Publications] 根本修克: "Cationic Ring-Opening Polymerization of Monothiocarbonate with a Norbornene Group"Journal of Polymer Science Part A : Polymer Chemistry. 40巻. 1698-1705 (2002)
[Publications] 遠藤剛: "Controlled Ring-Opening Polymerization of Cyclic Carbonate and Lactones by an Activated Mechanism"Journal of Polymer Science Part A : Polymer Chemistry. 40巻. 2190-2198 (2002)
[Publications] 三田文雄: "Synthesis and Reduction of β-Hydroxyaspartic Acid-Based Polymethacrylate"Journal of Polymer Science Part A : Polymer Chemistry. 40巻. 2782-2788 (2002)
[Publications] 亀島久光: "Cationic Ring-Opening Polymerization of Five-Membered Cyclic Thiocarbonate Bearing an Adamantane Moiety via Selective Ring-Opening Direction"Macromolecules. 35巻. 5769-5773 (2002)
[Publications] 永井大介: "Novel Approach to Well-Defined Synthesis of a Polyester Bearing Phenol Moiety : Anionic Altenating Copolymerization of Ethylphenylketene with 4-(tert-Butyldimethylsilyloxy)benzaldehyde"Macromolecules. 35巻. 6149-6153 (2002)
[Publications] 西田治男: "Analysis of the Initial Process in Pyrolysis of Poly(p-dioxanone)"Polymer Degradation and Stability. 78巻. 129-135 (2002)
[Publications] 須藤篤: "Formation of a Living Anionic Oligomer of Ethylphenylketene on Polystyrene Beads and Its Application to the Solid-Supported Synthesis of Poly(methyl methacrylate)"Journal of Polymer Science Part A : Polymer Chemistry. 40巻. 3455-3459 (2002)
[Publications] 大塚英幸: "Pinacol Rearrangement in the Polymer Backone : Synthesis of Novel Reactive Polymers with Condensed Benzopinacol Units in the Main Chain and Their Complete Rearrangement of Poly(benzopinacolone)s"Macromolecular Chemistry and Physics. 203巻. 1824-1832 (2002)
[Publications] 高橋栄治: "アンモニウム塩によるネットワークポリマーの合成新規キノリニウム塩によるエポキシドのカチオン重合の基礎研究"ネットワークポリマー. 23巻. 170-177 (2002)
[Publications] 森川全章: "New Colorimetric Detection of Glucose by Means of Electron-Accepting Initiators"Chemistry A European Journal. 8巻. 5580-5584 (2002)
[Publications] 須藤篤: "Solid-Supported Well-Defined Synthesis of Telechelic Polyester by Acid-Promoted Ring-Opening Polymerization of ε-Caprolactone"Journal of Polymer Science Part A : Polymer Chemistry. 41巻. 116-118 (2003)
[Publications] 根本修克: "Cationic Ring-Opening Polymerization Behavior of a Five-Membered Cyclic Thiocarbonate Having a Spiro-Linked Adamantane Moiety"Journal of Polymer Science Part A : Polymer Chemistry. 41巻. 699-707 (2003)
[Publications] 田中正剛: "Samarium Enolate on Crosslinked Polystyrene Beads. An Anionic Initiator for the Well-Defined Synthesis of Poly(allyl methacrylate) on a Solid Support"Journal of Polymer Science Part A : Polymer Chemistry. 41巻. 853-860 (2003)
[Publications] 三田文雄: "A Novel Thermally Latent Anionic Initiator. Polymerization of Epoxide with Hydroxylamide Based on Thermal Dissociation"Macromolecules. 36巻. 967-968 (2003)

2002 Fiscal Year Annual Research Report

二酸化炭素を用いる新しい有機反応と新規高分子合成

Principal Investigator

遠藤 剛 山形大学, 工学部, 教授 (40016738)

Research Products

[Publications] 三田 文雄: "Stepwise Synthesis of γ-Glutamic Acid 16-Mer"Macromolecular Chemistry and Physics. 203巻. 727-734 (2002)

[Publications] 須藤 篤: "Selective Reduction of Main-Chain 2-Azetidinone Moieties into Azetidines for Polymer Reaction"Journal of Polymer Science Part A : Polymer Chemistry. 40巻. 1912-1917 (2002)

[Publications] 根本 修克: "Cationic Ring-Opening Polymerization of Monothiocarbonate with a Norbornene Group"Journal of Polymer Science Part A : Polymer Chemistry. 40巻. 1698-1705 (2002)

[Publications] 遠藤 剛: "Controlled Ring-Opening Polymerization of Cyclic Carbonate and Lactones by an Activated Mechanism"Journal of Polymer Science Part A : Polymer Chemistry. 40巻. 2190-2198 (2002)

[Publications] 三田 文雄: "Synthesis and Reduction of β-Hydroxyaspartic Acid-Based Polymethacrylate"Journal of Polymer Science Part A : Polymer Chemistry. 40巻. 2782-2788 (2002)

[Publications] 亀島 久光: "Cationic Ring-Opening Polymerization of Five-Membered Cyclic Thiocarbonate Bearing an Adamantane Moiety via Selective Ring-Opening Direction"Macromolecules. 35巻. 5769-5773 (2002)

[Publications] 永井 大介: "Novel Approach to Well-Defined Synthesis of a Polyester Bearing Phenol Moiety : Anionic Altenating Copolymerization of Ethylphenylketene with 4-(tert-Butyldimethylsilyloxy)benzaldehyde"Macromolecules. 35巻. 6149-6153 (2002)

[Publications] 西田 治男: "Analysis of the Initial Process in Pyrolysis of Poly(p-dioxanone)"Polymer Degradation and Stability. 78巻. 129-135 (2002)

[Publications] 須藤 篤: "Formation of a Living Anionic Oligomer of Ethylphenylketene on Polystyrene Beads and Its Application to the Solid-Supported Synthesis of Poly(methyl methacrylate)"Journal of Polymer Science Part A : Polymer Chemistry. 40巻. 3455-3459 (2002)

[Publications] 大塚 英幸: "Pinacol Rearrangement in the Polymer Backone : Synthesis of Novel Reactive Polymers with Condensed Benzopinacol Units in the Main Chain and Their Complete Rearrangement of Poly(benzopinacolone)s"Macromolecular Chemistry and Physics. 203巻. 1824-1832 (2002)

[Publications] 高橋 栄治: "アンモニウム塩によるネットワークポリマーの合成 新規キノリニウム塩によるエポキシドのカチオン重合の基礎研究"ネットワークポリマー. 23巻. 170-177 (2002)

[Publications] 森川 全章: "New Colorimetric Detection of Glucose by Means of Electron-Accepting Initiators"Chemistry A European Journal. 8巻. 5580-5584 (2002)

[Publications] 須藤 篤: "Solid-Supported Well-Defined Synthesis of Telechelic Polyester by Acid-Promoted Ring-Opening Polymerization of ε-Caprolactone"Journal of Polymer Science Part A : Polymer Chemistry. 41巻. 116-118 (2003)

[Publications] 根本 修克: "Cationic Ring-Opening Polymerization Behavior of a Five-Membered Cyclic Thiocarbonate Having a Spiro-Linked Adamantane Moiety"Journal of Polymer Science Part A : Polymer Chemistry. 41巻. 699-707 (2003)

[Publications] 田中 正剛: "Samarium Enolate on Crosslinked Polystyrene Beads. An Anionic Initiator for the Well-Defined Synthesis of Poly(allyl methacrylate) on a Solid Support"Journal of Polymer Science Part A : Polymer Chemistry. 41巻. 853-860 (2003)

[Publications] 三田 文雄: "A Novel Thermally Latent Anionic Initiator. Polymerization of Epoxide with Hydroxylamide Based on Thermal Dissociation"Macromolecules. 36巻. 967-968 (2003)

遠藤剛山形大学, 工学部, 教授 (40016738)

[Publications] 三田文雄: "Stepwise Synthesis of γ-Glutamic Acid 16-Mer"Macromolecular Chemistry and Physics. 203巻. 727-734 (2002)

[Publications] 須藤篤: "Selective Reduction of Main-Chain 2-Azetidinone Moieties into Azetidines for Polymer Reaction"Journal of Polymer Science Part A : Polymer Chemistry. 40巻. 1912-1917 (2002)

[Publications] 根本修克: "Cationic Ring-Opening Polymerization of Monothiocarbonate with a Norbornene Group"Journal of Polymer Science Part A : Polymer Chemistry. 40巻. 1698-1705 (2002)

[Publications] 遠藤剛: "Controlled Ring-Opening Polymerization of Cyclic Carbonate and Lactones by an Activated Mechanism"Journal of Polymer Science Part A : Polymer Chemistry. 40巻. 2190-2198 (2002)

[Publications] 三田文雄: "Synthesis and Reduction of β-Hydroxyaspartic Acid-Based Polymethacrylate"Journal of Polymer Science Part A : Polymer Chemistry. 40巻. 2782-2788 (2002)

[Publications] 亀島久光: "Cationic Ring-Opening Polymerization of Five-Membered Cyclic Thiocarbonate Bearing an Adamantane Moiety via Selective Ring-Opening Direction"Macromolecules. 35巻. 5769-5773 (2002)

[Publications] 永井大介: "Novel Approach to Well-Defined Synthesis of a Polyester Bearing Phenol Moiety : Anionic Altenating Copolymerization of Ethylphenylketene with 4-(tert-Butyldimethylsilyloxy)benzaldehyde"Macromolecules. 35巻. 6149-6153 (2002)

[Publications] 西田治男: "Analysis of the Initial Process in Pyrolysis of Poly(p-dioxanone)"Polymer Degradation and Stability. 78巻. 129-135 (2002)

[Publications] 須藤篤: "Formation of a Living Anionic Oligomer of Ethylphenylketene on Polystyrene Beads and Its Application to the Solid-Supported Synthesis of Poly(methyl methacrylate)"Journal of Polymer Science Part A : Polymer Chemistry. 40巻. 3455-3459 (2002)

[Publications] 大塚英幸: "Pinacol Rearrangement in the Polymer Backone : Synthesis of Novel Reactive Polymers with Condensed Benzopinacol Units in the Main Chain and Their Complete Rearrangement of Poly(benzopinacolone)s"Macromolecular Chemistry and Physics. 203巻. 1824-1832 (2002)

[Publications] 高橋栄治: "アンモニウム塩によるネットワークポリマーの合成新規キノリニウム塩によるエポキシドのカチオン重合の基礎研究"ネットワークポリマー. 23巻. 170-177 (2002)

[Publications] 森川全章: "New Colorimetric Detection of Glucose by Means of Electron-Accepting Initiators"Chemistry A European Journal. 8巻. 5580-5584 (2002)

[Publications] 須藤篤: "Solid-Supported Well-Defined Synthesis of Telechelic Polyester by Acid-Promoted Ring-Opening Polymerization of ε-Caprolactone"Journal of Polymer Science Part A : Polymer Chemistry. 41巻. 116-118 (2003)

[Publications] 根本修克: "Cationic Ring-Opening Polymerization Behavior of a Five-Membered Cyclic Thiocarbonate Having a Spiro-Linked Adamantane Moiety"Journal of Polymer Science Part A : Polymer Chemistry. 41巻. 699-707 (2003)

[Publications] 田中正剛: "Samarium Enolate on Crosslinked Polystyrene Beads. An Anionic Initiator for the Well-Defined Synthesis of Poly(allyl methacrylate) on a Solid Support"Journal of Polymer Science Part A : Polymer Chemistry. 41巻. 853-860 (2003)

[Publications] 三田文雄: "A Novel Thermally Latent Anionic Initiator. Polymerization of Epoxide with Hydroxylamide Based on Thermal Dissociation"Macromolecules. 36巻. 967-968 (2003)