2003 Fiscal Year Annual Research Report

ナノ構造配列を基盤とする分子ナノ工学の構築とマイクロシステムへの展開

Research Project

Project/Area Number	13CE2003
Research Institution	Waseda University
Principal Investigator	大泊巌早稲田大学, 理工学部, 教授 (30063720)
Co-Investigator(Kenkyū-buntansha)	堀越佳治早稲田大学, 理工学部, 教授 (60287985) 西出宏之早稲田大学, 理工学部, 教授 (90120930) 逢坂哲彌早稲田大学, 理工学部, 教授 (20097249) 船津高志東京大学, 大学院・薬学系研究科, 教授 (00190124) 松本和子早稲田大学, 理工学部, 教授 (60111457)
Keywords	ナノ理工学研究機構 / プロトタイプ / 生体分子 / 一分子観察 / 酵素センサ / 磁気記録 / 酸素富化膜 / マイクロ流路
Research Abstract	拠点の整備状況本拠点を中核として、ナノテクファウンドリ、21世紀COEに係る実践ナノ化学および自己組織化物理の2拠点などを統合した「ナノ理工学研究機構」が、平成15年12月に設立され、文字通りの中核的処点としての体制が整った。研究成果各個研究に加えて、チーム内外の共同研究を督励し、また、成果をプロトタイプ(PT)として形にする研究課題5件を選定して、第3回公開シンポジウムにおいて発表した。以下、グループ(G)毎に共同研究を中心に成果をまとめる。 <ナノ物性G> 大泊研:・Siの酸化過程を原子スケールで再現するシミュレータを開発し(PT研究)、熱成長SiO_2膜に存在する未知の秩序性の実体の解明、に成功。・ナノ構造と発光蛋白質の相互作用の解析(共同-星野研)。・ナノ構造配列形成工程の簡素化によりナノ電子銃配列形成(PT研究)。・100nmの精度で生体分子を基板上に配列させる技術を開発し、従来不可能な条件下で蛋白質間相互作用の一分子観察に成功(共同-船津研)。・世界のオンリーワン技術であるシングルイオン注入法を用いて、分析機器の絶対感度較正用標準試料作成を開始(企業との共同研究)。川原田研:・ダイヤモンド上への酵素やDNA固定化技術を応用した電解質溶液ゲートFET酵素センサ開発に成功し、DNAハイブリダイゼーションによる電位検出(世界初)。・カーボンナノチューブ厚膜(50μm以上)配向成長技術を開発し、触媒金属の厚み制御により、単層、多層の構造制御にも成功(共同-大泊研、世界初)。星野研:・ナノ構造配列による分子認識の基礎として、蛋白質とナノ構造基板間の相互作用を理論的に計算し、基板の疎/親水性と水溶性蛋白質の吸着過程を解析(共同-大泊研)。 <ケミカルナノプロセスG> 逢坂研:・磁気記録材料の研究開発において,高飽和磁束密度を有する電析CoFe膜の保磁力低減に成功。また、Co/Pd垂直媒体のPdシード層を置換めっき法により形成し、その記録再生特性を改善(PT研究)。・超小型燃料電池の試作セルによる発電試験に成功し、最大出力密度0.78mW/cm^2を達成(共同-庄子研)。黒田研:・高規則性の金属骨格メソポーラス材料の研究開発を行い、メソ構造の規則性を左右する因子(還元剤の種類、金属の触媒活性および反応速度)を解明、高規則性メソ構造の作製プロセスを確立(共同-逢坂研)。西出研:・有機分子のシリコン基板上への規則配置を目指し、ナノ寸法ポリスチレン微粒子や有機ラジカル高分子の配列に成功(共同-大泊研)。・高分子ポルフィリン錯体を用いた酸素富化膜マスクの実用化を目指し、大面積・大流量での酸素富化空気の取り出しを実証(PT研究)。 <バイオマイクロシステムG> 松本研:・DNA等の生体関連物質の分析システムのマイクロシステム化を目指して、検出装置としてのチップスキャナーの開発を行い、目標感度をクリアーした。庄子研/船津研:・化学反応や生化学反応の状態を計測して精密に制御するマイクロセルの試作、機能評価を行い、実際の用途を意識したシステム設計の基礎を確立。・生体分子やオルガネラを、蛍光顕微鏡を使って高感度に検出し、チップ内のマイクロ流路を使って分離する装置の開発。・ナノホールを用いて1分子レベルの生体分子間相互作用を検出する技術の開発(共同-大泊研)。・温感性ハイドロゲルのゾルゲル変換を利用した流体の制御を可能にする2次元のマトリックス型可変マイクロ流路を作製(PT研究)。 <ナノ理工学基礎G> 堀越研:・化合物半導体ナノ構造製作技術の開発を進め、寸法精度のきわめて高い量子ドット格子および量子細線の実現、実験結果に整合する励起子モデルの構築、ガラス基板上へのGaN多結晶成長とその紫外領域の光電子放出用陰極としての応用、などに成功。・新しいナノ構造林料としてのC_<60>のエピタキシャル薄膜の研究をすすめ、Alの添加により応用上重要な機械的強度の著しい増大に成功。大場研:・基礎理論として、ナノデバイスの置かれている実状況をモデル化した環境中の量子系を量子化する問題を分析。・Siに数10nm間隔でリン原子配列を構成する核スピン量子コンピュータ実現への基礎的分析として、この量子系におけるデコヒーレンスの問題、及びq-bits演算の可能性を解析。

Research Products

(103 results)

All Other

All Publications (103 results)

[Publications] 大泊巌, 品田賢宏: "シングルイオン注入技術と評価"応用物理学会結晶工学分科会第8回結晶工学セミナー. 47-52 (2003)
[Publications] K.Tatsumura, T.Watanabe, D.Yamasaki, T.Shimura, M.Umeno, I.Ohdomari: "Effects of Thermal History on Residual Order of Thermally Grown Silicon Dioxide"Jpn.J.Appl.Phys.. Vol.42. 7250-7255 (2003)
[Publications] K.Tatsumura, T.Watanabe, D.Yamasaki, T.Shimura, M.Umeno, I.Ohdomari: "Large-Scale Atomistic Modeling of Thermally Grown SiO2 on Si(111) Substrate"Jpn.J.Appl.Phys.. Vol.43. 492-497 (2003)
[Publications] Meishoku Masahara, Takashi Matsukawa, Kenichi Ishii, Yongxun Liu, Masayoshi Nagao, Hisao Tanoue, Takashi Tanii, Iwao Ohdomari, Seigo Kanemaru, Eiichi Suzuki: "Fabrication of Ultrathin Si Channel Wall For Vertical Double-Gate Metal-Oxide-Semiconductor Field-Effect Transistor (DG MOSFET) by Using Ion-Bombardment-Retarded Etching (IBRE)"Jpn.J.Appl.Phys.. Vol.42. 1916-1918 (2003)
[Publications] G.-J.Zhang, T.Tanii, T.Zako, T.Funatsu, I.Ohdomari: "The Immobilization of DNA on Microstructure Patterns Fabricated by Maskless Lithography"Sens.Actuat B. 97(2-3). 243-248 (2004)
[Publications] K.Tatsumura, T.Watanabe, D.Yamasaki, T.Shimura, M.Umeno, I.Ohdomari: "Residual Order within Thermally-Grown Amorphous SiO2 on Crystalline Silicon"Phys.Rev.B.. 69. 085212 (2004)
[Publications] G.-J.Zhang, T.Tanii, T.Funatsu, I.Ohdomari: "Patterning of DNA Nanostructures on Silicon surface by Electron Beam Lithography of Self-assembled Monolayer"ChemComm. (Accepted)(未定). (2004)
[Publications] T.Watanabe, K.Tatsumura, I.Ohdomari: "SiO_2/Si Interface Structure and its Formation Studied by Large-scale Molecular Dynamics Simulation"Appl.Surf.Sci.. (Accepted)(未定). (2004)
[Publications] S.Miyamoto, H.Ishizaka, H.Taniuchi, H.Umezawa, M.Tachiki, H.Kawarada: "High Performance Diamond MISFETs using CaF_2 Gate Insulator"Diam.Relat.Mater.. 12. 399-402 (2003)
[Publications] T.Fujisaki, M.Tachiki, M.Kudo, N.Taniyama, H.Kawarada: "Initial Growth of Heteroepitaxial Diamond on Ir(001)/MgO(001) Substrate using Antenna-Edge Type Microwave Plasma Assisted Chemical Vapor Deposition"Diam.Relat.Mater.. 12. 246-250 (2003)
[Publications] H.Kanazawa, K.S.Song, T.Sakai, H.Umezawa, M.Tachiki, H.Kawarada 他1名: "Effect of Iodide Ions on the Hydrogen-Terminated and Oxygen-Terminated Diamond Surface"Diam.Relat.Mater.. 12. 618-622 (2003)
[Publications] Y.Kaibara, K.Sugata, M.Tachiki, H.Umezawa, H.Kawarada: "Control Wettability of the Hydrogen-Terminated Diamond Surface and the Oxidized Diamond Surface using the Atomic Force Microscope"Diam.Relat.Mater.. 12. 560-564 (2003)
[Publications] T.Banno, M.Tachiki, K.Nakazawa, Y.Sumikawa, H.Umezawa, H.Kawarada: "Fabrication of Diamond In-Plane-Gate Field-Effect Transistors using Oxygen Plasma Etching"Diam.Relat.Mater.. 12. 408-412 (2003)
[Publications] M.Tachiki, Y.Kaibara, K.S.Song, H.Umezawa, H.Kawarada 他3名: "Diamond Nanofabrication and Characterization for Biosensing Application"Phys.Stat.Sol.(a). 199. 39-43 (2003)
[Publications] K.S.Song, T.Sakai, H.Kanazawa, Y.Araki, H.Umezawa, M.Tachiki, H.Kawarada: "Cl^-Sensitive Biosensor used Electrolyte-Gate Diamond FETs"Biosens.Bioelectron. 19. 137-140 (2003)
[Publications] H.Umezawa, S.Miyamoto, K.S.Song, M.Tachiki, H.Kawarada 他2名: "RF Performance of Diamond Surface-Channel Field-Effect Transistors"IEICE Trans.Electr.. E86C. 1949-1954 (2003)
[Publications] K.Nakazawa, H.Umezawa, M.Tachiki, H.Kawarada: "Nonlinear Increase of Excitonic Emission in Synthetic Type IIa Diamond"Diam.Relat.Mater.. 12. 1995-1998 (2003)
[Publications] H.Ishizaka, M.Tachiki, K.S.Song, H.Umezawa, H.Kawarada: "Cryogenic Operation of Diamond Field-Effect Transistors"Diam.Relat.Mater.. 12. 1800-1803 (2003)
[Publications] H.Matsudaira, T.Arima, H.Umezawa, M.Tachiki, H.Kawarada 他2名: "Deep Sub-micron Gate Diamond MISFETs"Diam.Relat.Mater.. 12. 1814-1818 (2003)
[Publications] T.Sakai, K.S.Song, H.Kanazawa, Umezawa, M.Tachiki, H.Kawarada: "Ozone-Treated Channel Diamond Field-Effect Transistors"Diam.Relat.Mater.. 12. 1971-1975 (2003)
[Publications] S.Kono, T.Takano, M.Shimomura, T.Goto, M.Tachiki, H.Kawarada 他2名: "Electron-Spectroscopy and -Diffraction Study of the Conductivity of CVD Diamond (001) 2x1 Surface"Surf.Sci.. 529. 180-188 (2003)
[Publications] 梅沢仁, 石坂博明, 宮本真吾, 宋光燮, 立木実, 川原田洋: "水素終端表面伝導層を用いた高周波ダイヤモンドFET"電子情報通信学会論文誌C. J86-C. 419-425 (2003)
[Publications] H.Matsudaira, S.Miyamoto, H.Ishizaka, H.Umezawa, H.Kawarada: "Over 20 GHz Cut-Off Frequency Deep Sub-micron Gate Diamond MISFET"IEEE Elect.Dev.Lett.. (in press). (2004)
[Publications] H.Umezawa, T.Arima, S.Miyamoto, H.Matsudaira, H.Kawarada: "70 nm Channel Diamond MISFET and Suppression of Short Channel Effect"IEEE Elect.Dev.Lett.. (in press). (2004)
[Publications] Y.Sumikawa, K.Kobayashi, Y.Itoh, H.Umezawa: "Current-Voltage Hysteresis Behavior of Diamond In-Plane-Gated Field-Effect Transistors"Appl.Phys.Lett.. (in press). (2004)
[Publications] 川原田洋, 梅沢仁: "ダイヤモンドにおけるキャリア輸送特性とFETへの応用"応用物理. 73(in press). (2004)
[Publications] N.Okimoto, T.Hoshino, 他12名: "Molecular Dynamics Simulations of Prion Proteins - Effect of Ala^<117>→Val mutation"Chem-Bio Informatics Journal. 3. 1-11 (2003)
[Publications] S.Neya 他9名: "Ion hemiporphycene as a functional prosthetic group for myoglobin"Inorganic Chemistry. 42. 1456-1461 (2003)
[Publications] D.Katagiri, M.Hata, T.Itoh, S.Neya, T.Hoshino: "Atomic-scale mechanism of the GTP->GDP hydrolysis reaction by Gia1 protein"Journal of Physical Chemistry B. 107. 3278-3283 (2003)
[Publications] Y.Fujii, T.Hoshino 他12名: "Molecular dynamics study on Class A β-lactamase"Journal of Physical Chemistry B. 107. 10274-10283 (2003)
[Publications] K.Murata, Y.Sato, M.Hata, T.Hoshino, M.Tsuda: "Unidirectional proton transfer mechanism in the L-M N sequence of Bacteriorhodopsin"Journal of Molecular Structure. 664/665. 125-133 (2003)
[Publications] D.Niwa, N.Takano, T.Yamada, T.Osaka: "Nickel electroless deposition process on chemically pretreated Si(100) wafers in aqueous alkaline solution"Electrochimica Acta. 48. 1295-1300 (2003)
[Publications] K.-K.Choi, T.Murase, T.Yokoshima, T.Osaka, Y.Kitamoto, Y.Yamazaki: "High-frequency Properties of CoZrNb/Fe-C Multilayer Films"Transactions of the Magnetics Society of Japan. 3(2). 55-58 (2003)
[Publications] T.Osaka, N.Takano, T.Kurokawa, T.Kaneko, K.Ueno: "Characterization of chemically-deposited NiB and NiWB thin films as a capping layer for ULSI application"Surface and Coatings Technology. 169-170. 124-127 (2003)
[Publications] T.Osaka, N.Takano, T.Yokoshima: "Microfabrication of electro- and electroless-deposition and its application in the electronic field"Surface and Coatings Technology. 169-170. 1-7 (2003)
[Publications] 川治純, 北泉太士, 本間敬之, 逢坂哲彌: "無電解めっき法による磁性ナノドットアレイの作製"電子情報通信学会技術研究報告[磁気記録]. MR2003-6. 1-5 (2003)
[Publications] T.Osaka, S.Nakade, M.Rajamaki, T.Momma: "Influence of capacity fading on commercial lithium-ion battery impedance"Journal of Power Sources. 119-121. 929-933 (2003)
[Publications] H.Mukaibo, A.Yoshizawa, T.Momma, T.Osaka: "Particle size and performance of SnS2 anodes for rechargeable lithium batteries"Journal of Power Sources. 119-121. 60-63 (2003)
[Publications] T.Osaka, T.Yokoshima, D.Shiga, K.Imai, K.Takashima: "A High Moment CoFe Soft Magnetic Thin Film Prepared by Electrodeposition"Electrochemical and Solid-State Letters. 6. C53-C55 (2003)
[Publications] H.Mukaibo, T.Sumi, T.Yokoshima, T.Momma, T.Osaka: "Electrodeposited Sn-Ni Alloy Film as a High Capacity Anode Material for Lithium Ion Secondary Battery"Electrochemical and Solid-State Letters. 6. 1-10 (2003)
[Publications] T.Yamada, T.Inoue, K.Yamada, N.Takano, T Osaka, H.Harada, K.Nishiyama, I.Taniguchi: "Detection of C-Si Covalent Bond in CH_3 Adsorbate Formed by Chemical Reaction of CH_3MgBr and H:Si(111)"Journal of the American Chemical Society. 125(26). 8039-8042 (2003)
[Publications] 川治純, 朝日透, 田中睦美, 木村公治, 本間敬之, 逢坂哲彌: "電気化学的手法を用いた垂直二層膜媒体用下地層の作成"電子情報通信学会技術研究報告[磁気記録]. MR2003-28. 7-11 (2003)
[Publications] I.Matsuda, F.Asa, T.Osaka: "Simulation on the Optimum Conditions for Propargyl Alcohol to Function as a Shape Control Agent in the Process of Nickel Electrodeposition onto a Micropatterned Substrate"Electrochemistry. 71(11). 912-919 (2003)
[Publications] T.Nakanishi, H.Iida, T.Osaka: "Preparation of Iron Oxide Nanoparticles via Successive Reduction-Oxidation in Reverse Micelles"Chemistry Letters. 32(12). 1166-1167 (2003)
[Publications] T.Osaka, T.Yokoshima, T.Nakanishi: "All-Wet Barrier-Layer Fabricating Process on SiO_2 for ULSI Cu Interconnections"Proceedings of 2002 ECS International Semiconductor Technology Conference (ISTC2002), The Electrochemical Society. (in press). (2003)
[Publications] T.Yokoshima, A.Kawashima, T.Nakanishi, T.Osaka, M.Saito, K.Ohashi: "Influence of Carbon Inclusion on Properties of Electrodeposited CoNiFeMo Thin Films"Proceedings of International Symposium, The Electrochemical Society. PV2002-27. 365-375 (2003)
[Publications] T.Homma, H.Sato, H.Kobayashi, T.Arakawa, H.Kudo, T.Osaka, S.Shoji, et al.: "Sn electrodeposition process for fabricating microabsorber arrays for an X-ray microcalorimeter"Journal of Electroanalytical Chemistry. 559. 143-148 (2003)
[Publications] N.Banno, T.Nakanishi, M.Matsunaga, T.Asahi, T.Osaka: "Enantioselective Crystal Growth of Leucine on a Self-Assembled Monolayer with Covalently Attached Leucine Molecules"Journal of the American Chemical Society. 126(2). 428-429 (2003)
[Publications] D.Niwa, T.Homma, T.Osaka: "Fabrication of Organic Monolayer Modified Ion-Sensitive Field Transistors with High Chemical Durability"Japanese Journal of Applied Physics. 43(1A/B). L105-L107 (2004)
[Publications] D.Niwa, K.Omichi, N.Motohashi, T.Homma, T.Osaka: "Formation of Micro and Nanoscale Patterns of Monolayer Templates for Position Selective Immobilization of Oligonucleotide Using Ultraviolet and Electron Beam Lithography"Chemistry Letters. 33(2). 176-177 (2003)
[Publications] T.Momma, H.Ito, H.Nara, H.Mukaibo, S.Passerini, T.Osaka: "Characteristics of Interpenetrated Polymer Network System made of Polyethylene Oxide-LiBF_4 Complex and Polystyrene as Electrolyte for Lithium Secondary Battery"Electrochemistry. 71(12). 1182-1186 (2003)
[Publications] M.Chemla, T.Homma, V.Bertagna, R.Erre, N.Kubo, T.Osaka: "Survey of the metal nucleation processes on silicon surfaces in fluoride solutions : from dilute HF to concentrated NH_4F solutions"Journal of Electroanalytical Chemistry. 559. 111-123 (2003)
[Publications] J.Sayama, M.Tanaka, J.Kawaji, T.Asahi, S.Matsunuma, T.Osaka: "Effects of Sputtering Conditions on Magnetic Properties of Co/Pd Multilayered Films"Transactions of the Materials Research Society of Japan. 28(4). 1165-1168 (2003)
[Publications] J.Kawaji, M.Tanaka, K.Kimura, T.Asahi, T.Homma, T.Osaka: "Formation of Pd nanocluster seed by electrochemical process for control of magnetic properties in Co/Pd multilayered film"IEEE Transactions on Magnetics. (in press). (2004)
[Publications] J.Kawaji, F.Kitaizumi, T.Homma, T.Osaka: "Fabrication of CoNiP Dot Arrays for Patterned Magnetic Recording Media with Electroless Deposition Process"Proceedings of International Symposium, The Electrochemical Society. PV2002-27. 473-482 (2003)
[Publications] J.Sayama, T.Asahi, K.Mizutani, T.Osaka: "Newly developed SmCo_5 thin film with perpendicular magnetic anisotropy"Journal of Physics D : Applied Physics. 37(1). L1-L4 (2004)
[Publications] M.Yoshino, T.Yokoshima, Tetsuya Osaka: "The Proposal of All-Wet Fabrication Process for ULSI Interconnections Technologies & Application of Electroless NiB Deposition to Capping and Barrier"Proceedings of International Symposium, The Electrochemical Society. PV2003-10. 137-145 (2003)
[Publications] Michinobu T, Inui J, Nishide H: "Magnetic force microscopic images of nanometer-sized polyradical particles"POLYMER JOURNAL. 35. 71-75 (2003)
[Publications] Michinobu T, Inui J, Nishide H: "m-phenylene-linked aromatic poly(aminium cationic radical)s : Persistent high-spin organic polyradicals"ORGANIC LETTER. 5. 2165-2168 (2003)
[Publications] Kurata T, Pu YJ, Kido J, Nishide H: "Charge-transporting property of polymer films doped with organic stable radicals"JOURNAL OF PHOTOPOLYMER SCIENCE AND TECHNOLOGY. 16. 297-298 (2003)
[Publications] Michinobu T, Inui J, Nishide H: "Preparation of non-Kekule- and nondisjoint-type aromatic polyamines by palladium-catalyzed polycondensation and their poly(cationic radical)s"POLYHEDRON. 22. 1945-1949 (2003)
[Publications] Tagami K, Tsukada M, Wada Y, Iwasaki T, Nishide H: "Electronic transport of benzothiophene-based chiral molecular solenoids studied by theoretical simulations"JOURNAL OF CHEMICAL PHYSICS. 119. 7491-7497 (2003)
[Publications] Shentu BQ, Nishide H: "Facilitated oxygen transport membranes of picket-fence cobaltporphyrin complexed with various polymer matrixes"INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH. 42. 5954-5958 (2003)
[Publications] Hah H, Sakai T, Asai K, Nishide H: "Synthesis of poly(ethynylplatinumporphyrin) and its application as an oxygen pressure-sensitive paint"MACROMOLECULAR SYMPOSIA. 204. 27-35 (2003)
[Publications] Murata H, Takahashi M, Namba K, Nishide H: "A high-spin and durable polyradicals : Poly(4-diphenylaminium-1,2-phenylenevinylene)"Journal of Organic Chemistry. 69. 631-638 (2004)
[Publications] R.Kaito, K.Kuroda, M.Ogawa: "Unidirectional Orientation of Methylene Blue Intercalated in K_4Nb_6O_<17> Single Crystal"J.Phys.Chem.B. 107(17). 4043-4047 (2003)
[Publications] M.Ogawa, T.Ishii, N.Miyamoto, K.Kuroda: "Intercalation of a Cationic Azobenzene into Montmorillonite"Appl.Clay Sci.. 22(4). 179-185 (2003)
[Publications] T.Itagaki, K.Kuroda: "Organic modification of the interlayer surface of kaolinite with propanediols by transesterification"J Mater.Chem.. 13(5). 1064-1068 (2003)
[Publications] T.Shigeno, K.Inoue, T.Kimura, N.Katada, M.Niwa, K.Kuroda: "Synthesis of Al-containing mesoporous silica (KSW-2) with semi-squared channels by incorporation of Al into the framework of kanemite"J.Mater.Chem.. 13(4). 883-887 (2003)
[Publications] I.Fujita, K.Kuroda, M.Ogawa: "Synthesis of interlamellar silylated derivatives of magadiite and the adsorption behavior for aliphatic alcohols"Chem.Mater.. 15(16). 3134-3141 (2003)
[Publications] A.Shimojima, K.Kuroda: "Direct formation of mesostructured silica-based hybrids from novel siloxane oligomers with long alkyl chains"Angew.Chem.Int.Ed.. 42(34). 4057-4060 (2003)
[Publications] H.Furukawa, K.Kuroda: "Effective inclusion of chlorophyllous pigments into mesoporous silica for the energy transfer between the chromophores"Stud.Surf.Sci.Catal.. 146. 577-580 (2003)
[Publications] N.Umeda, A.Shimojima, K.Kuroda: "Synthesis of multilayered silica-based hybrid films from difunctional organosilanes by co-hydrolysis and polycondensation with tetraalkoxysilane"J.Organomet.Chem.. 686(1-2). 223-227 (2003)
[Publications] Y.Fujimoto, A.Shimojima, K.Kuroda: "Formation of Layered Silica-Alcohol Nanostructured Materials from Alkoxytrichlorosilanes"Chem.Mater.. 15(25). 4768-4774 (2003)
[Publications] N.Miyamoto, K.Kuroda, M.Ogawa: "Exfoliation and film preparation of a layered titanate, Na_2Ti_3O_7, and intercalation of pseudoisocyanine dye"J.Mater.Chem.. 14(2). 165-170 (2004)
[Publications] W.Chen, K.Matsumoto: "Pivalamidate-Bridged Dinuclear Platinum and Platinum-Palladium Complexes : Synthsis, NMR, and X-ray Structural Characterization of cis-[Pt(NH_3)_2(NHCO^tBu)_2]・2H_2O and cis-[Pt(NH_3)_2(NHCO^tBu)_2MLL'] Xn (X=Pt, LL'=cod ; L=L'=dmso ; L=Cl, L'=dmso ; M=pd, L=L'=NH_3; X=ClO_4, NO_3)"Inog.Chim Acta. 342. 88-96 (2003)
[Publications] N.Saeki, N.Nakamura, T.Ishibashi, M.Arime, H.Sekiya, K.Ishihara, K.Matsumoto: "Mechanism of Ketone and Alcohol Formations from Alkenes and Alkynes on the Head-to-head 2-Pyridonato-Bridged cis-Diammineplatinum(III)"J.Am.Chem.Soc.. 125(12). 3605-3616 (2003)
[Publications] K.Matsumoto, J.Yuan: "Lanthanide Chelates as Fluorescence Labels for Diagnostics and Biotechnology"Metal Ions in Biological Systems. 40. 191-232 (2003)
[Publications] J.Yuan, S.Sueda, R.Somazawa, K.Matsumoto, K.Matsumoto: "Structure and Luminescence Properties of the Tetradentate β-Diketonate-Europium (III) Complexes"Chem.Lett.. (6). 492-493 (2003)
[Publications] K.Shimazaki, H.Sekiya, H.Inoue, N.Saeki, K.Ishihara, K.Matumoto: "Mechanisms of the Axial Ligand Substitution Reactions of Dinuclear Head-to-Head α-Pyrrolidonato- and Pivalamidato-Bridged cis-Diammineplatinum(III) Complexes with Halide Ions"Eur.J.Inorg.Chem.. (9). 1785-1793 (2003)
[Publications] W.Chen, F.Liu, T.Nishioka, K.Matsumoto: "Heterotrimetallic Complexes [{Pt(RNH_2)_2(μ-NHCOtBu)_2}_2M] (ClO_4)_n(M=Mn, Co, Cu, Ni, Cd, and Zn, n=2; M=In, n=3), [{Pt(NH_3)(μ-DACHCOtBu)(μ-NHCOtBu)}_2Ni](ClO_4)_2,and [{Pt(RNH_2)_2(NHCOtBu)_2}_3Ag_3](ClO_4)_3 Bridged by Amidate Ligands : A Novel Amidate-Amine Interligand Reaction During the Pt-Ni Bond Formation"Eur.J.Chem.. (23). 4234-4243 (2003)
[Publications] M.Arime, K.Ishihara K.Matsumoto: "Mechanism of the Axial Ligand Substitution Reactions on the Head-to-Tail α-Pyridonato-Bridged cis-Diammineplatinum(III) Dinuclear Complex with Olefins"Inorg.Chem. 43(1). 309-316 (2004)
[Publications] M.Ochiai, Y.-S.Lin, J.Yamada, H.Misawa, S.Arai, K.Matsumoto: "Reactions of a Platinum(III) Dimeric Complex with Alkynes in Water : Novel Approach to α-Aminoketone, α-Iminoketone, and α,β-Diimine via Ketonyl-Pt(III) Dinuclear Complexes"J.Am.Chem.Soc.. 126(8). 2536-2545 (2004)
[Publications] J.S.Go, S.Shoji: "Digital sorting of flow-through droplet phase microfluid"Jpn.J.Appl.Phys.. Vol.42. L449-L450 (2003)
[Publications] J.S.Go, S.Shoji: "Micromechanical characterization of self-oscillating microcantilever using piezoresistive microsensors"IEEJ Trans.SM. Vol.123,No.11. 510-512 (2003)
[Publications] M.Kanai, H.Abe, T.Munaka, Y.Fujiyama, D.Uchida, A.Yamayoshi, H.Nakanishi, A.Murakami, S.Shoji: "Integrated micro chamber for living cell analysis with negligible dead volume sample injector"12^<th> Int.Conf.On Solid-State Sensors, Actuators and Microsystems : Transducers'03. Vol.1. 288-291 (2003)
[Publications] M.Ishizuka, M.Abe, H.Houjou, S.Shoji, J.Mizuno, Y.Wada: "Design and fabrication of multi-metal electrodes implanted PDMS structures for micro flow devices using 3-D assembly"12^<th> Int.Conf.On Solid-State Sensors, Actuators and Microsystems : Transducers'03. Vol.2. 999-1002 (2003)
[Publications] N.Honda, K.Emi, T.Katagiri, T.Irita, S.Shoji, H.Sato, T.Homma, T.Osaka, M.Saito, J.Mizuno, Y.Wada: "3-D comb electrodes for amperometric immuno sensors"12^<th> Int.Conf.On Solid-State Sensors, Actuators and Microsystems : Transducers'03. Vol.2. 1132-1135 (2003)
[Publications] H, Kudo, T.Nakamura, T.Arakawa, T.Izumi, S.Shoji: "Prototype of the multi-poxel X-ray microcalorimeter"12^<th> Int.Conf.On Solid-State Sensors, Actuators and Microsystems : Transducers'03. Vol.2. 1108-1111 (2003)
[Publications] J.S.Go, M.Kanai, S.Shoji: "A novel in-plane digitalization of multiphase microfluids"12^<th> Int.Conf.On Solid-State Sensors, Actuators and Microsystems : Transducers'03. Vol.1. 643-646 (2003)
[Publications] J.S.Go, M.Kanai, S.Shoji: "A novel in-plane digitalization of multiphase microfluids"12^<th> Int.Conf.On Solid-State Sensors, Actuators and Microsystems : Transducers'03. Vol.2. 1808-1811 (2003)
[Publications] J.S.Go, E.H.Jeong, K.C.Kim, S.Y.Yoon, S.Shoji: "In-plane digital sorting of flow-through droplet phase microfluidics"7^<th> Int.Conf.On Micro Total Analysis Systems : μ-TAS2003. Vol.2. 1275-1278 (2003)
[Publications] M.Kanai, D.Uchida, S.Sugiura, Y.Shirasaki, J.S.Go, H.Nakanishi, T.Funatsu, S.Shoji: "PDMS microfluidic devices with PTFE passivated channels"7^<th> Int.Conf.On Micro Total Analysis Systems : μ-TAS2003. Vol.1. 429-432 (2003)
[Publications] H.Sato, S.Ito, K.Tajima, N.Orimoto, S.Shoji: "Functional 3-D PDMS microchannel having slanted grooves embedded walls realizing spiral flow"17^<th> IEEE Int.Conf.On Micro Electro Mechanical Systems : MEMS 2004. 693-696 (2004)
[Publications] T.Homma, H.Sato, K.Mori, T.Osaka, S.Shoji: "High aspect ratio nanovolume glass cell array fabricated by area-selective silicon electrochemical etching process"17^<th> IEEE Int.Conf.On Micro Electro Mechanical Systems : MEMS 2004. 705-708 (2004)
[Publications] Zhang, G., T.Tanii, T.Zako, T.Funatsu, I.Ohdomari: "The immobilization of DNA on microstructured patterns fabricated by maskless lithography"Sensors and Actuators B.. 97. 243-248 (2004)
[Publications] Kanai, M., D.Uchida, S.Sugiura, Y.Shirasaki, J.S.Go, H.Nakanishi, T.Funatsu, S.Shoji.: "PDMS microfluidics devices with PTFE passivated channels."Micro Total Analysis System 2003. 429-432 (2003)
[Publications] 船津高志: "単一分子計測とバイオフォトニクス"応用物理. 72. 727-730 (2003)
[Publications] 多田隈尚史, 船津高志, 谷時雄: "mRNA核外輸送の可視化"蛋白質核酸酵素. 48. 421-429 (2003)
[Publications] 大泊巌(編集委員および執筆), 谷井孝至: "川合知二監修「ナノテクノロジー大事典」"工業調査会. 989 (2003)
[Publications] 逢坂哲彌, 尾上貴弘: "21世紀版薄膜作製応用ハンドブック第2編第5章第4節"エヌ・ティー・エス. 8 (2003)
[Publications] 堀越佳治執筆: "ナノテクノロジー大事典(川知二監修)"工業調査会. 989 (2003)
[Publications] 庄子習一: "「ナノボリューム流体制御デバイス・システム」,ナノテクノロジーハンドブック,IVバイオ・化学に使う編修"オーム社. 213 (2003)

2003 Fiscal Year Annual Research Report

ナノ構造配列を基盤とする分子ナノ工学の構築とマイクロシステムへの展開

Principal Investigator

大泊 巌 早稲田大学, 理工学部, 教授 (30063720)

Research Products

[Publications] 大泊巌, 品田賢宏: "シングルイオン注入技術と評価"応用物理学会結晶工学分科会第8回結晶工学セミナー. 47-52 (2003)

[Publications] K.Tatsumura, T.Watanabe, D.Yamasaki, T.Shimura, M.Umeno, I.Ohdomari: "Effects of Thermal History on Residual Order of Thermally Grown Silicon Dioxide"Jpn.J.Appl.Phys.. Vol.42. 7250-7255 (2003)

[Publications] K.Tatsumura, T.Watanabe, D.Yamasaki, T.Shimura, M.Umeno, I.Ohdomari: "Large-Scale Atomistic Modeling of Thermally Grown SiO2 on Si(111) Substrate"Jpn.J.Appl.Phys.. Vol.43. 492-497 (2003)

[Publications] G.-J.Zhang, T.Tanii, T.Zako, T.Funatsu, I.Ohdomari: "The Immobilization of DNA on Microstructure Patterns Fabricated by Maskless Lithography"Sens.Actuat B. 97(2-3). 243-248 (2004)

[Publications] K.Tatsumura, T.Watanabe, D.Yamasaki, T.Shimura, M.Umeno, I.Ohdomari: "Residual Order within Thermally-Grown Amorphous SiO2 on Crystalline Silicon"Phys.Rev.B.. 69. 085212 (2004)

[Publications] G.-J.Zhang, T.Tanii, T.Funatsu, I.Ohdomari: "Patterning of DNA Nanostructures on Silicon surface by Electron Beam Lithography of Self-assembled Monolayer"ChemComm. (Accepted)(未定). (2004)

[Publications] T.Watanabe, K.Tatsumura, I.Ohdomari: "SiO_2/Si Interface Structure and its Formation Studied by Large-scale Molecular Dynamics Simulation"Appl.Surf.Sci.. (Accepted)(未定). (2004)

[Publications] S.Miyamoto, H.Ishizaka, H.Taniuchi, H.Umezawa, M.Tachiki, H.Kawarada: "High Performance Diamond MISFETs using CaF_2 Gate Insulator"Diam.Relat.Mater.. 12. 399-402 (2003)

[Publications] T.Fujisaki, M.Tachiki, M.Kudo, N.Taniyama, H.Kawarada: "Initial Growth of Heteroepitaxial Diamond on Ir(001)/MgO(001) Substrate using Antenna-Edge Type Microwave Plasma Assisted Chemical Vapor Deposition"Diam.Relat.Mater.. 12. 246-250 (2003)

[Publications] H.Kanazawa, K.S.Song, T.Sakai, H.Umezawa, M.Tachiki, H.Kawarada 他1名: "Effect of Iodide Ions on the Hydrogen-Terminated and Oxygen-Terminated Diamond Surface"Diam.Relat.Mater.. 12. 618-622 (2003)

[Publications] Y.Kaibara, K.Sugata, M.Tachiki, H.Umezawa, H.Kawarada: "Control Wettability of the Hydrogen-Terminated Diamond Surface and the Oxidized Diamond Surface using the Atomic Force Microscope"Diam.Relat.Mater.. 12. 560-564 (2003)

[Publications] T.Banno, M.Tachiki, K.Nakazawa, Y.Sumikawa, H.Umezawa, H.Kawarada: "Fabrication of Diamond In-Plane-Gate Field-Effect Transistors using Oxygen Plasma Etching"Diam.Relat.Mater.. 12. 408-412 (2003)

[Publications] M.Tachiki, Y.Kaibara, K.S.Song, H.Umezawa, H.Kawarada 他3名: "Diamond Nanofabrication and Characterization for Biosensing Application"Phys.Stat.Sol.(a). 199. 39-43 (2003)

[Publications] K.S.Song, T.Sakai, H.Kanazawa, Y.Araki, H.Umezawa, M.Tachiki, H.Kawarada: "Cl^-Sensitive Biosensor used Electrolyte-Gate Diamond FETs"Biosens.Bioelectron. 19. 137-140 (2003)

[Publications] H.Umezawa, S.Miyamoto, K.S.Song, M.Tachiki, H.Kawarada 他2名: "RF Performance of Diamond Surface-Channel Field-Effect Transistors"IEICE Trans.Electr.. E86C. 1949-1954 (2003)

[Publications] K.Nakazawa, H.Umezawa, M.Tachiki, H.Kawarada: "Nonlinear Increase of Excitonic Emission in Synthetic Type IIa Diamond"Diam.Relat.Mater.. 12. 1995-1998 (2003)

[Publications] H.Ishizaka, M.Tachiki, K.S.Song, H.Umezawa, H.Kawarada: "Cryogenic Operation of Diamond Field-Effect Transistors"Diam.Relat.Mater.. 12. 1800-1803 (2003)

[Publications] H.Matsudaira, T.Arima, H.Umezawa, M.Tachiki, H.Kawarada 他2名: "Deep Sub-micron Gate Diamond MISFETs"Diam.Relat.Mater.. 12. 1814-1818 (2003)

[Publications] T.Sakai, K.S.Song, H.Kanazawa, Umezawa, M.Tachiki, H.Kawarada: "Ozone-Treated Channel Diamond Field-Effect Transistors"Diam.Relat.Mater.. 12. 1971-1975 (2003)

[Publications] S.Kono, T.Takano, M.Shimomura, T.Goto, M.Tachiki, H.Kawarada 他2名: "Electron-Spectroscopy and -Diffraction Study of the Conductivity of CVD Diamond (001) 2x1 Surface"Surf.Sci.. 529. 180-188 (2003)

[Publications] 梅沢 仁, 石坂 博明, 宮本 真吾, 宋 光燮, 立木 実, 川原田 洋: "水素終端表面伝導層を用いた高周波ダイヤモンドFET"電子情報通信学会論文誌C. J86-C. 419-425 (2003)

[Publications] H.Matsudaira, S.Miyamoto, H.Ishizaka, H.Umezawa, H.Kawarada: "Over 20 GHz Cut-Off Frequency Deep Sub-micron Gate Diamond MISFET"IEEE Elect.Dev.Lett.. (in press). (2004)

[Publications] H.Umezawa, T.Arima, S.Miyamoto, H.Matsudaira, H.Kawarada: "70 nm Channel Diamond MISFET and Suppression of Short Channel Effect"IEEE Elect.Dev.Lett.. (in press). (2004)

[Publications] Y.Sumikawa, K.Kobayashi, Y.Itoh, H.Umezawa: "Current-Voltage Hysteresis Behavior of Diamond In-Plane-Gated Field-Effect Transistors"Appl.Phys.Lett.. (in press). (2004)

[Publications] 川原田 洋, 梅沢 仁: "ダイヤモンドにおけるキャリア輸送特性とFETへの応用"応用物理. 73(in press). (2004)

[Publications] N.Okimoto, T.Hoshino, 他12名: "Molecular Dynamics Simulations of Prion Proteins - Effect of Ala^<117>→Val mutation"Chem-Bio Informatics Journal. 3. 1-11 (2003)

[Publications] S.Neya 他9名: "Ion hemiporphycene as a functional prosthetic group for myoglobin"Inorganic Chemistry. 42. 1456-1461 (2003)

[Publications] D.Katagiri, M.Hata, T.Itoh, S.Neya, T.Hoshino: "Atomic-scale mechanism of the GTP->GDP hydrolysis reaction by Gia1 protein"Journal of Physical Chemistry B. 107. 3278-3283 (2003)

[Publications] Y.Fujii, T.Hoshino 他12名: "Molecular dynamics study on Class A β-lactamase"Journal of Physical Chemistry B. 107. 10274-10283 (2003)

[Publications] K.Murata, Y.Sato, M.Hata, T.Hoshino, M.Tsuda: "Unidirectional proton transfer mechanism in the L-M N sequence of Bacteriorhodopsin"Journal of Molecular Structure. 664/665. 125-133 (2003)

[Publications] D.Niwa, N.Takano, T.Yamada, T.Osaka: "Nickel electroless deposition process on chemically pretreated Si(100) wafers in aqueous alkaline solution"Electrochimica Acta. 48. 1295-1300 (2003)

[Publications] K.-K.Choi, T.Murase, T.Yokoshima, T.Osaka, Y.Kitamoto, Y.Yamazaki: "High-frequency Properties of CoZrNb/Fe-C Multilayer Films"Transactions of the Magnetics Society of Japan. 3(2). 55-58 (2003)

[Publications] T.Osaka, N.Takano, T.Kurokawa, T.Kaneko, K.Ueno: "Characterization of chemically-deposited NiB and NiWB thin films as a capping layer for ULSI application"Surface and Coatings Technology. 169-170. 124-127 (2003)

[Publications] T.Osaka, N.Takano, T.Yokoshima: "Microfabrication of electro- and electroless-deposition and its application in the electronic field"Surface and Coatings Technology. 169-170. 1-7 (2003)

[Publications] 川治純, 北泉太士, 本間敬之, 逢坂哲彌: "無電解めっき法による磁性ナノドットアレイの作製"電子情報通信学会技術研究報告[磁気記録]. MR2003-6. 1-5 (2003)

[Publications] T.Osaka, S.Nakade, M.Rajamaki, T.Momma: "Influence of capacity fading on commercial lithium-ion battery impedance"Journal of Power Sources. 119-121. 929-933 (2003)

[Publications] H.Mukaibo, A.Yoshizawa, T.Momma, T.Osaka: "Particle size and performance of SnS2 anodes for rechargeable lithium batteries"Journal of Power Sources. 119-121. 60-63 (2003)

[Publications] T.Osaka, T.Yokoshima, D.Shiga, K.Imai, K.Takashima: "A High Moment CoFe Soft Magnetic Thin Film Prepared by Electrodeposition"Electrochemical and Solid-State Letters. 6. C53-C55 (2003)

[Publications] H.Mukaibo, T.Sumi, T.Yokoshima, T.Momma, T.Osaka: "Electrodeposited Sn-Ni Alloy Film as a High Capacity Anode Material for Lithium Ion Secondary Battery"Electrochemical and Solid-State Letters. 6. 1-10 (2003)

[Publications] T.Yamada, T.Inoue, K.Yamada, N.Takano, T Osaka, H.Harada, K.Nishiyama, I.Taniguchi: "Detection of C-Si Covalent Bond in CH_3 Adsorbate Formed by Chemical Reaction of CH_3MgBr and H:Si(111)"Journal of the American Chemical Society. 125(26). 8039-8042 (2003)

[Publications] 川治純, 朝日透, 田中睦美, 木村 公治, 本間敬之, 逢坂哲彌: "電気化学的手法を用いた垂直二層膜媒体用下地層の作成"電子情報通信学会技術研究報告[磁気記録]. MR2003-28. 7-11 (2003)

[Publications] I.Matsuda, F.Asa, T.Osaka: "Simulation on the Optimum Conditions for Propargyl Alcohol to Function as a Shape Control Agent in the Process of Nickel Electrodeposition onto a Micropatterned Substrate"Electrochemistry. 71(11). 912-919 (2003)

[Publications] T.Nakanishi, H.Iida, T.Osaka: "Preparation of Iron Oxide Nanoparticles via Successive Reduction-Oxidation in Reverse Micelles"Chemistry Letters. 32(12). 1166-1167 (2003)

[Publications] T.Osaka, T.Yokoshima, T.Nakanishi: "All-Wet Barrier-Layer Fabricating Process on SiO_2 for ULSI Cu Interconnections"Proceedings of 2002 ECS International Semiconductor Technology Conference (ISTC2002), The Electrochemical Society. (in press). (2003)

[Publications] T.Yokoshima, A.Kawashima, T.Nakanishi, T.Osaka, M.Saito, K.Ohashi: "Influence of Carbon Inclusion on Properties of Electrodeposited CoNiFeMo Thin Films"Proceedings of International Symposium, The Electrochemical Society. PV2002-27. 365-375 (2003)

[Publications] T.Homma, H.Sato, H.Kobayashi, T.Arakawa, H.Kudo, T.Osaka, S.Shoji, et al.: "Sn electrodeposition process for fabricating microabsorber arrays for an X-ray microcalorimeter"Journal of Electroanalytical Chemistry. 559. 143-148 (2003)

[Publications] N.Banno, T.Nakanishi, M.Matsunaga, T.Asahi, T.Osaka: "Enantioselective Crystal Growth of Leucine on a Self-Assembled Monolayer with Covalently Attached Leucine Molecules"Journal of the American Chemical Society. 126(2). 428-429 (2003)

[Publications] D.Niwa, T.Homma, T.Osaka: "Fabrication of Organic Monolayer Modified Ion-Sensitive Field Transistors with High Chemical Durability"Japanese Journal of Applied Physics. 43(1A/B). L105-L107 (2004)

[Publications] D.Niwa, K.Omichi, N.Motohashi, T.Homma, T.Osaka: "Formation of Micro and Nanoscale Patterns of Monolayer Templates for Position Selective Immobilization of Oligonucleotide Using Ultraviolet and Electron Beam Lithography"Chemistry Letters. 33(2). 176-177 (2003)

[Publications] T.Momma, H.Ito, H.Nara, H.Mukaibo, S.Passerini, T.Osaka: "Characteristics of Interpenetrated Polymer Network System made of Polyethylene Oxide-LiBF_4 Complex and Polystyrene as Electrolyte for Lithium Secondary Battery"Electrochemistry. 71(12). 1182-1186 (2003)

[Publications] M.Chemla, T.Homma, V.Bertagna, R.Erre, N.Kubo, T.Osaka: "Survey of the metal nucleation processes on silicon surfaces in fluoride solutions : from dilute HF to concentrated NH_4F solutions"Journal of Electroanalytical Chemistry. 559. 111-123 (2003)

[Publications] J.Sayama, M.Tanaka, J.Kawaji, T.Asahi, S.Matsunuma, T.Osaka: "Effects of Sputtering Conditions on Magnetic Properties of Co/Pd Multilayered Films"Transactions of the Materials Research Society of Japan. 28(4). 1165-1168 (2003)

[Publications] J.Kawaji, M.Tanaka, K.Kimura, T.Asahi, T.Homma, T.Osaka: "Formation of Pd nanocluster seed by electrochemical process for control of magnetic properties in Co/Pd multilayered film"IEEE Transactions on Magnetics. (in press). (2004)

[Publications] J.Kawaji, F.Kitaizumi, T.Homma, T.Osaka: "Fabrication of CoNiP Dot Arrays for Patterned Magnetic Recording Media with Electroless Deposition Process"Proceedings of International Symposium, The Electrochemical Society. PV2002-27. 473-482 (2003)

[Publications] J.Sayama, T.Asahi, K.Mizutani, T.Osaka: "Newly developed SmCo_5 thin film with perpendicular magnetic anisotropy"Journal of Physics D : Applied Physics. 37(1). L1-L4 (2004)

[Publications] M.Yoshino, T.Yokoshima, Tetsuya Osaka: "The Proposal of All-Wet Fabrication Process for ULSI Interconnections Technologies & Application of Electroless NiB Deposition to Capping and Barrier"Proceedings of International Symposium, The Electrochemical Society. PV2003-10. 137-145 (2003)

[Publications] Michinobu T, Inui J, Nishide H: "Magnetic force microscopic images of nanometer-sized polyradical particles"POLYMER JOURNAL. 35. 71-75 (2003)

[Publications] Michinobu T, Inui J, Nishide H: "m-phenylene-linked aromatic poly(aminium cationic radical)s : Persistent high-spin organic polyradicals"ORGANIC LETTER. 5. 2165-2168 (2003)

[Publications] Kurata T, Pu YJ, Kido J, Nishide H: "Charge-transporting property of polymer films doped with organic stable radicals"JOURNAL OF PHOTOPOLYMER SCIENCE AND TECHNOLOGY. 16. 297-298 (2003)

[Publications] Michinobu T, Inui J, Nishide H: "Preparation of non-Kekule- and nondisjoint-type aromatic polyamines by palladium-catalyzed polycondensation and their poly(cationic radical)s"POLYHEDRON. 22. 1945-1949 (2003)

[Publications] Tagami K, Tsukada M, Wada Y, Iwasaki T, Nishide H: "Electronic transport of benzothiophene-based chiral molecular solenoids studied by theoretical simulations"JOURNAL OF CHEMICAL PHYSICS. 119. 7491-7497 (2003)

[Publications] Shentu BQ, Nishide H: "Facilitated oxygen transport membranes of picket-fence cobaltporphyrin complexed with various polymer matrixes"INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH. 42. 5954-5958 (2003)

[Publications] Hah H, Sakai T, Asai K, Nishide H: "Synthesis of poly(ethynylplatinumporphyrin) and its application as an oxygen pressure-sensitive paint"MACROMOLECULAR SYMPOSIA. 204. 27-35 (2003)

[Publications] Murata H, Takahashi M, Namba K, Nishide H: "A high-spin and durable polyradicals : Poly(4-diphenylaminium-1,2-phenylenevinylene)"Journal of Organic Chemistry. 69. 631-638 (2004)

[Publications] R.Kaito, K.Kuroda, M.Ogawa: "Unidirectional Orientation of Methylene Blue Intercalated in K_4Nb_6O_<17> Single Crystal"J.Phys.Chem.B. 107(17). 4043-4047 (2003)

[Publications] M.Ogawa, T.Ishii, N.Miyamoto, K.Kuroda: "Intercalation of a Cationic Azobenzene into Montmorillonite"Appl.Clay Sci.. 22(4). 179-185 (2003)

[Publications] T.Itagaki, K.Kuroda: "Organic modification of the interlayer surface of kaolinite with propanediols by transesterification"J Mater.Chem.. 13(5). 1064-1068 (2003)

[Publications] T.Shigeno, K.Inoue, T.Kimura, N.Katada, M.Niwa, K.Kuroda: "Synthesis of Al-containing mesoporous silica (KSW-2) with semi-squared channels by incorporation of Al into the framework of kanemite"J.Mater.Chem.. 13(4). 883-887 (2003)

[Publications] I.Fujita, K.Kuroda, M.Ogawa: "Synthesis of interlamellar silylated derivatives of magadiite and the adsorption behavior for aliphatic alcohols"Chem.Mater.. 15(16). 3134-3141 (2003)

[Publications] A.Shimojima, K.Kuroda: "Direct formation of mesostructured silica-based hybrids from novel siloxane oligomers with long alkyl chains"Angew.Chem.Int.Ed.. 42(34). 4057-4060 (2003)

[Publications] H.Furukawa, K.Kuroda: "Effective inclusion of chlorophyllous pigments into mesoporous silica for the energy transfer between the chromophores"Stud.Surf.Sci.Catal.. 146. 577-580 (2003)

[Publications] N.Umeda, A.Shimojima, K.Kuroda: "Synthesis of multilayered silica-based hybrid films from difunctional organosilanes by co-hydrolysis and polycondensation with tetraalkoxysilane"J.Organomet.Chem.. 686(1-2). 223-227 (2003)

[Publications] Y.Fujimoto, A.Shimojima, K.Kuroda: "Formation of Layered Silica-Alcohol Nanostructured Materials from Alkoxytrichlorosilanes"Chem.Mater.. 15(25). 4768-4774 (2003)

[Publications] N.Miyamoto, K.Kuroda, M.Ogawa: "Exfoliation and film preparation of a layered titanate, Na_2Ti_3O_7, and intercalation of pseudoisocyanine dye"J.Mater.Chem.. 14(2). 165-170 (2004)

[Publications] N.Saeki, N.Nakamura, T.Ishibashi, M.Arime, H.Sekiya, K.Ishihara, K.Matsumoto: "Mechanism of Ketone and Alcohol Formations from Alkenes and Alkynes on the Head-to-head 2-Pyridonato-Bridged cis-Diammineplatinum(III)"J.Am.Chem.Soc.. 125(12). 3605-3616 (2003)

大泊巌早稲田大学, 理工学部, 教授 (30063720)

[Publications] 梅沢仁, 石坂博明, 宮本真吾, 宋光燮, 立木実, 川原田洋: "水素終端表面伝導層を用いた高周波ダイヤモンドFET"電子情報通信学会論文誌C. J86-C. 419-425 (2003)

[Publications] 川原田洋, 梅沢仁: "ダイヤモンドにおけるキャリア輸送特性とFETへの応用"応用物理. 73(in press). (2004)

[Publications] 川治純, 朝日透, 田中睦美, 木村公治, 本間敬之, 逢坂哲彌: "電気化学的手法を用いた垂直二層膜媒体用下地層の作成"電子情報通信学会技術研究報告[磁気記録]. MR2003-28. 7-11 (2003)

[Publications] 逢坂哲彌, 尾上貴弘: "21世紀版薄膜作製応用ハンドブック第2編第5章第4節"エヌ・ティー・エス. 8 (2003)

[Publications] 堀越佳治執筆: "ナノテクノロジー大事典(川知二監修)"工業調査会. 989 (2003)

[Publications] 庄子習一: "「ナノボリューム流体制御デバイス・システム」,ナノテクノロジーハンドブック,IVバイオ・化学に使う編修"オーム社. 213 (2003)