2003 Fiscal Year Annual Research Report

陽電子ビームによる金属基板上のエポキシ樹脂薄膜自由体積の研究

Research Project

Project/Area Number	14550853
Research Institution	High Energy Accelerator Research Organization
Principal Investigator	鈴木健訓高エネルギー加速器研究機構, 放射線科学センター, 教授 (40162961)
Co-Investigator(Kenkyū-buntansha)	沼尻正晴高エネルギー加速器研究機構, 放射線科学センター, 助手 (20189385) 三浦太一高エネルギー加速器研究機構, 放射線科学センター, 助手 (80209717) 近藤健次郎高エネルギー加速器研究機構, 共通研究施設, 教授 (20004434)
Keywords	陽電子消滅 / ポジトロニウム / パルス化 / 薄膜 / 高分子 / 多層膜 / 多層膜境界面 / 低速陽電子
Research Abstract	本研究のテーマは、陽電子の持つ反粒子としての特徴を使い、高分子材料の特性解析を行うことである。陽電子は、電子と相互作用をして消滅するか、或いは、ポジトロニウム(Ps)という水素元素に似た構造の結合状態を形成した後で消滅する。Psは高分子空孔に捕捉されると、空孔の大きさに相関した寿命で消滅する。この寿命を測定することにより、高分子材料の空隙の大きさを定量的に決定することが出来るという特徴を持っている。陽電子消滅法の手法の中で陽電子寿命測定法(PALS)は、一般的に行われており、数100μm〜1mmのような厚い高分子材料を解析する場合は、Na-22のような放射性同位元素(RI)から発生する陽電子を使い、高分子空孔の大きさを定量的に評価している。数10nm〜μmのような高分子薄膜や表面の特性を解析する場合、薄膜中で停止するようなエネルギーの低速陽電子ビーム装置を用いる必要がある。このような装置を用いると薄膜中や表面近傍に存在する高分子空隙を測定することが出来るので、半導体技術に欠かせない半導体表面の被膜特性を測定することが可能である。半導体などの金属表面に被覆した高分子膜の自由体積を測定する場合、非破壊で測定することは困難であるが、本研究を通して開発した短パルス化低速陽電子ビーム装置を用いると、非破壊で、基板(Si等)表面上に塗布した50ナノメータ(nm)〜数ミクロン厚さのエポキシ樹脂薄膜の自由体積を求めることができる。本研究では、この装置を用いて、基板上の薄膜の温度特性を求めた。本装置は、放射性同位元素を用いた短パルス化低速陽電子発生装置で、ビームの半値幅が0.5〜0.9nsであり、金属のPALSには不十分であるが、高分子材料の表面の研究を行なうには十分な性能である。

Research Products
(34 results)

All Other

All Publications (34 results)

[Publications] 松生勝, 鈴木健訓, 他: "Characteristics of ultra-drawn polyethylene films as a function of temperature estimated by the positron annihilation lifetime method"Macromolecules. 35. 3059-3065 (2002)
[Publications] 何春清, 鈴木健訓, 他: "Molecular motions at low temperature observed by positron annihilation"Physics Letters. A304. 49-53 (2002)
[Publications] 熊木尚, 鈴木健訓, 他: "低速陽電子短パルス化装置を用いた表面自由体積の研究"ネットワークポリマー. 23. 24-31 (2002)
[Publications] Goworek T., 鈴木健訓, 他: "On possible deviations of experimental PALS data from positronium pick-off model estimates"Chemical Physics. 280. 295-307 (2002)
[Publications] H.Uchiyama, T.Suzuki: "The study of 1/1-AlCuRuSi approximate phase by positron annihilation method"Journal of Alloys and Compounds. 342. 153-155 (2002)
[Publications] V.Shantarovich, T.Suzuki, 他: "Positron annihilation study of hyper-cross-linked polystylene networks"Macromolecules. 35. 9723-9729 (2002)
[Publications] 鈴木健訓, 近藤健次郎, 他: "The influence of radiation and light on Ps formation in PMMA and PE studied by coincidence Doppler-broadening spectroscopy"Radiation Physics and Chemistry. 66. 161-166 (2003)
[Publications] 鈴木健訓, 近藤健次郎, 他: "The influence of radiation on Ps formation in PE studied by coincidence Doppler-broadening spectroscopy"Radiation Physics and Chemistry. 68. 489-492 (2003)
[Publications] 鈴木健訓, 近藤健次郎, 他: "Relaxation Behavior of Polymers Probed by Positron Annihilation Life time Spectroscopy"Material Research Innovations. 7. 31-36 (2003)
[Publications] Shantarovich, 鈴木健訓, 他: "Positron annihilation study of hyper-crosslinked sorbents"Radiation Physics and Chemistry. 68. 639-641 (2003)
[Publications] Shantarovich, 鈴木健訓, 他: "A possibility to study substance properties using positronium as the simplest "Labeled" atom"Journal of Radioanalytical and Nuclear Chemistry. 255. 165-170 (2003)
[Publications] Shantarovich, 鈴木健訓, 他: "Inhibition of positronium formation by polar groups in polymers-relation with TSL experiments"Radiation Physics and Chemistry. 67. 15-23 (2003)
[Publications] N.Djourelov, 鈴木健訓, 他: "Positron Annihilation in Polypropylene studied by Lifetime and Coincidence Doppler-Broadening Spectroscopy"Radiation Physics and Chemistry. 68. 689-695 (2003)
[Publications] 伊藤泰男, 鈴木健訓: "Effects of electric field on positronium formation in polystyrene at various temperature"Radiation Physics and Chemistry. 66. 343-347 (2003)
[Publications] 何春清, 鈴木健訓, 近藤健次郎, 他: "Development on a pulsed slow-positron beam : Moderator and bunching signal waveform"Nuclear Instruments and Methods. B211. 571-576 (2003)
[Publications] 何春清, 鈴木健訓, 近藤健次郎, 他: "Positronium formation in low-density polyethylene (LDPE)"Physics Letters. A313. 223-230 (2003)
[Publications] 何春清, 鈴木健訓, 近藤健次郎, 他: "Temperature dependence of ortho-positronium annihilation in hypercrosslinked polystyrene"Radiation Physics and Chemistry. 68. 511-514 (2003)
[Publications] 何春清, 鈴木健訓, 近藤健次郎, 他: "Characterization of polymer sub-surface using slow positron beam"Journal of Radioanalytical and Nuclear Chemistry. 255. 431-435 (2003)
[Publications] 何春清, 鈴木健訓, 近藤健次郎, 他: "Positron annihilation in liypercrosslinked polystyrenes"Chemical Physics. 286. 249-256 (2003)
[Publications] 何春清, 鈴木健訓, 近藤健次郎, 他: "Characterization of polymer films using a slow positron beam"Material Research Innovations. 7. 37-41 (2003)
[Publications] M.Debowska, 鈴木健訓, 他: "Polyamide, acrylic rubber and their blends studied by positron annihilation and other methods"Radiation Physics and Chemistry. 68. 471-473 (2003)
[Publications] M.Debowska, 鈴木健訓, 他: "Free volume studies in polyamide, acrylic rubber and their blends"FIBRES & TEXTILES in Eastern Europe. 11. 120-125 (2003)
[Publications] J.Kansy, 鈴木健訓: "Positronium fraction in polymer spectra determined by ETLA model"Radiation Physics and Chemistry. 68. 497-500 (2003)
[Publications] Lin Ma, 鈴木健訓, 他: "Molecular Mobility of Amorphous Chain Segments of Ethylene-Methyl Methacylate Copolymer Films as a Function of Temperature Estimated by Positron Annihilation, X-ray Diffraction, and C-13 NMR"Macromolecules. 36. 8056-8065 (2003)
[Publications] 松生勝, 鈴木健訓, 他: "Relaxation mechanism in several kinds of polyethylene estimated by dynamic mechanical measurements, positron annihilation, X-ray and 13C solid-state NMR"Polymer. 44. 4325-4340 (2003)
[Publications] 何春清, 鈴木健訓, 近藤健次郎, 他: "Pulsed slow-positron beam for polymer films"Applied Surface Science. 221. 444-449 (2004)
[Publications] 東真美, 鈴木健訓, 他: "Ultradrawing of blend films of ethylene-dimethyl-aminoethyl methacrylate copolymer and ultra-high molecular weight polyethylene prepared by gelation/crystallization from solutions"Polymer. 45. 409-421 (2004)
[Publications] N.Djourelov, 鈴木健訓, 他: "Carbon-implanted ultra-high molecular-weight polyethylene studied by a pulsed slow-positron beam"Nuclear Instruments and Methods. B215. 83-89 (2004)
[Publications] N.Djourelov, 鈴木健訓, 他: "Application of coincidence Doppler broadening spectroscopy to simple hydrocarbons"Chemical Physics. 298. 183-187 (2004)
[Publications] M.Debowska, 鈴木健訓, 他: "Looking for positive mixing volume detected in polyamide/acrylic rubber blends by positron annihilation lifetime spectroscopy and other methods"Materials Science Forum. 445-446. 277-279 (2004)
[Publications] 船越, 鈴木健訓, 他: "Positron annihilation lifetime measurement in supercritical fluid of N20"Materials Science Forum. 445-446. 295-297 (2004)
[Publications] 伊藤寛, 鈴木健訓, 他: "Application of coincidence Doppler-broadening spectroscopy to different carbon phases"Materials Science Forum. 445-446. 310-312 (2004)
[Publications] V.P.Shantarovich, 鈴木健訓, 他: "Positron annihilation in polymers with highly developed specific surface"Materials Science Forum. 445-446. 346-348 (2004)
[Publications] N.Djourelov, 鈴木健訓, 他: "Carbon Implanted Polyethylene characterized by a Pulsed Slow-Positron Beam"Materials Science Forum. 445-446. 280-282 (2004)

2003 Fiscal Year Annual Research Report

陽電子ビームによる金属基板上のエポキシ樹脂薄膜自由体積の研究

Principal Investigator

鈴木 健訓 高エネルギー加速器研究機構, 放射線科学センター, 教授 (40162961)

Research Products

[Publications] 松生勝, 鈴木健訓, 他: "Characteristics of ultra-drawn polyethylene films as a function of temperature estimated by the positron annihilation lifetime method"Macromolecules. 35. 3059-3065 (2002)

[Publications] 何春清, 鈴木健訓, 他: "Molecular motions at low temperature observed by positron annihilation"Physics Letters. A304. 49-53 (2002)

[Publications] 熊木尚, 鈴木健訓, 他: "低速陽電子短パルス化装置を用いた表面自由体積の研究"ネットワークポリマー. 23. 24-31 (2002)

[Publications] Goworek T., 鈴木健訓, 他: "On possible deviations of experimental PALS data from positronium pick-off model estimates"Chemical Physics. 280. 295-307 (2002)

[Publications] H.Uchiyama, T.Suzuki: "The study of 1/1-AlCuRuSi approximate phase by positron annihilation method"Journal of Alloys and Compounds. 342. 153-155 (2002)

[Publications] V.Shantarovich, T.Suzuki, 他: "Positron annihilation study of hyper-cross-linked polystylene networks"Macromolecules. 35. 9723-9729 (2002)

[Publications] 鈴木健訓, 近藤健次郎, 他: "The influence of radiation and light on Ps formation in PMMA and PE studied by coincidence Doppler-broadening spectroscopy"Radiation Physics and Chemistry. 66. 161-166 (2003)

[Publications] 鈴木健訓, 近藤健次郎, 他: "The influence of radiation on Ps formation in PE studied by coincidence Doppler-broadening spectroscopy"Radiation Physics and Chemistry. 68. 489-492 (2003)

[Publications] 鈴木健訓, 近藤健次郎, 他: "Relaxation Behavior of Polymers Probed by Positron Annihilation Life time Spectroscopy"Material Research Innovations. 7. 31-36 (2003)

[Publications] Shantarovich, 鈴木健訓, 他: "Positron annihilation study of hyper-crosslinked sorbents"Radiation Physics and Chemistry. 68. 639-641 (2003)

[Publications] Shantarovich, 鈴木健訓, 他: "A possibility to study substance properties using positronium as the simplest "Labeled" atom"Journal of Radioanalytical and Nuclear Chemistry. 255. 165-170 (2003)

[Publications] Shantarovich, 鈴木健訓, 他: "Inhibition of positronium formation by polar groups in polymers-relation with TSL experiments"Radiation Physics and Chemistry. 67. 15-23 (2003)

[Publications] N.Djourelov, 鈴木健訓, 他: "Positron Annihilation in Polypropylene studied by Lifetime and Coincidence Doppler-Broadening Spectroscopy"Radiation Physics and Chemistry. 68. 689-695 (2003)

[Publications] 伊藤泰男, 鈴木健訓: "Effects of electric field on positronium formation in polystyrene at various temperature"Radiation Physics and Chemistry. 66. 343-347 (2003)

[Publications] 何春清, 鈴木健訓, 近藤健次郎, 他: "Development on a pulsed slow-positron beam : Moderator and bunching signal waveform"Nuclear Instruments and Methods. B211. 571-576 (2003)

[Publications] 何春清, 鈴木健訓, 近藤健次郎, 他: "Positronium formation in low-density polyethylene (LDPE)"Physics Letters. A313. 223-230 (2003)

[Publications] 何春清, 鈴木健訓, 近藤健次郎, 他: "Temperature dependence of ortho-positronium annihilation in hypercrosslinked polystyrene"Radiation Physics and Chemistry. 68. 511-514 (2003)

[Publications] 何春清, 鈴木健訓, 近藤健次郎, 他: "Characterization of polymer sub-surface using slow positron beam"Journal of Radioanalytical and Nuclear Chemistry. 255. 431-435 (2003)

[Publications] 何春清, 鈴木健訓, 近藤健次郎, 他: "Positron annihilation in liypercrosslinked polystyrenes"Chemical Physics. 286. 249-256 (2003)

[Publications] 何春清, 鈴木健訓, 近藤健次郎, 他: "Characterization of polymer films using a slow positron beam"Material Research Innovations. 7. 37-41 (2003)

[Publications] M.Debowska, 鈴木健訓, 他: "Polyamide, acrylic rubber and their blends studied by positron annihilation and other methods"Radiation Physics and Chemistry. 68. 471-473 (2003)

[Publications] M.Debowska, 鈴木健訓, 他: "Free volume studies in polyamide, acrylic rubber and their blends"FIBRES & TEXTILES in Eastern Europe. 11. 120-125 (2003)

[Publications] J.Kansy, 鈴木健訓: "Positronium fraction in polymer spectra determined by ETLA model"Radiation Physics and Chemistry. 68. 497-500 (2003)

[Publications] Lin Ma, 鈴木健訓, 他: "Molecular Mobility of Amorphous Chain Segments of Ethylene-Methyl Methacylate Copolymer Films as a Function of Temperature Estimated by Positron Annihilation, X-ray Diffraction, and C-13 NMR"Macromolecules. 36. 8056-8065 (2003)

[Publications] 松生勝, 鈴木健訓, 他: "Relaxation mechanism in several kinds of polyethylene estimated by dynamic mechanical measurements, positron annihilation, X-ray and 13C solid-state NMR"Polymer. 44. 4325-4340 (2003)

[Publications] 何春清, 鈴木健訓, 近藤健次郎, 他: "Pulsed slow-positron beam for polymer films"Applied Surface Science. 221. 444-449 (2004)

[Publications] 東真美, 鈴木健訓, 他: "Ultradrawing of blend films of ethylene-dimethyl-aminoethyl methacrylate copolymer and ultra-high molecular weight polyethylene prepared by gelation/crystallization from solutions"Polymer. 45. 409-421 (2004)

[Publications] N.Djourelov, 鈴木健訓, 他: "Carbon-implanted ultra-high molecular-weight polyethylene studied by a pulsed slow-positron beam"Nuclear Instruments and Methods. B215. 83-89 (2004)

[Publications] N.Djourelov, 鈴木健訓, 他: "Application of coincidence Doppler broadening spectroscopy to simple hydrocarbons"Chemical Physics. 298. 183-187 (2004)

[Publications] M.Debowska, 鈴木健訓, 他: "Looking for positive mixing volume detected in polyamide/acrylic rubber blends by positron annihilation lifetime spectroscopy and other methods"Materials Science Forum. 445-446. 277-279 (2004)

[Publications] 船越, 鈴木健訓, 他: "Positron annihilation lifetime measurement in supercritical fluid of N20"Materials Science Forum. 445-446. 295-297 (2004)

[Publications] 伊藤寛, 鈴木健訓, 他: "Application of coincidence Doppler-broadening spectroscopy to different carbon phases"Materials Science Forum. 445-446. 310-312 (2004)

[Publications] V.P.Shantarovich, 鈴木健訓, 他: "Positron annihilation in polymers with highly developed specific surface"Materials Science Forum. 445-446. 346-348 (2004)

[Publications] N.Djourelov, 鈴木健訓, 他: "Carbon Implanted Polyethylene characterized by a Pulsed Slow-Positron Beam"Materials Science Forum. 445-446. 280-282 (2004)

鈴木健訓高エネルギー加速器研究機構, 放射線科学センター, 教授 (40162961)