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2006 Fiscal Year Final Research Report Summary

Physical properties of deep Earth minerals and the effect of water

Research Project

Project/Area Number 15340150
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Solid earth and planetary physics
Research InstitutionEhime University

Principal Investigator

INOUE Toru  Ehime University, Geodynamics Research Center, Associate Professor, 地球深部ダイナミクス研究センター, 助教授 (00291500)

Co-Investigator(Kenkyū-buntansha) IRIFUNE Tetsuo  Ehime University, Geodynamics Research Center, Professor, 地球深部ダイナミクス研究センター, 教授 (80193704)
ANDO Jun-ichi  Hiroshima University, Department of Earth and Planetary Systems Science, Assistant Professor, 大学院・理学研究科, 助手 (50291480)
HIGO Yuji  Ehime University, Geodynamics Research Center, Postdoctoral Fellow, 地球深部ダイナミクス研究センター, 研究機関研究員 (10423435)
OHFUJI Hiroaki  Ehime University, Geodynamics Research Center, Assistant Professor, 地球深部ダイナミクス研究センター, 助手 (80403864)
YAMAZAKI Daisuke  Okayama University, Institute for study of the Earth's interior, Associate Professor, 地球物質科学研究センター, 助教授 (90346693)
Project Period (FY) 2003 – 2006
Keywordsmantle mineral / elastic wave velocity / ultrasonic measurement / water partitioning / hydrous magma / high pressure hydrous phase / high pressure apparatus / water in the mantle
Research Abstract

We have clarified the physical properties of deep Earth mantle minerals and the effect of water. Experiments were conducted by in situ X-ray measurements in addition to quench experiments.
From our previous studies, it has been clarified that high pressure polymorphs of olivine, wadsleyite and ringwoodite, can contain 2-3 wt% of H_2O in their crystal structures, but the partitioning of H_2O among these minerals has not been clarified yet. In the present study, we have clarified the partitioning of H_2O to synthesize these coexisting phases, and found that mantle transition zone should be a strong water reservoir in the Earth's interior.
In addition, the measurements of thermal expansion and elastic properties of hydrous wadsleyite and hydrous ringwoodite were conducted to clarify the H_2O content in the mantle. Combined these results with seismic observation, we estimated the H_2O content in the mantle. Further extensive studies have been conducted with seismologist.
We also tried to observe dehydration and physical properties of high pressure hydrous phase with capsulation using relatively light metal capsule by in situ X-ray observation. We succeeded to get X-ray spectra of superhydrous phase B using AgPd capsule, and further improved capsule, which were made by a single crystal diamond sleeve and metal caps, were designed for in situ X-ray experiment. The capsule is quite successful, and the effective acquisition of X-ray spectra under high pressure has been achieved by in situ X-ray experiment. This technique has been adopted to determine hydrous melt structure and time-resolved experiment of dehydration.

  • Research Products

    (49 results)

All 2007 2006 2005 2004 2003

All Journal Article (49 results)

  • [Journal Article] In-situ X-ray experiment on the structure of hydrous Mg-silicate melt under high pressure and high temperature2007

    • Author(s)
      Yamada, A., T.Inoue, S.Urakawa, K.Funakoshi, N.Funamori, T.Kikegawa, T.Irifune
    • Journal Title

      Geophys. Res. Lett. 34

      Pages: L10303

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] In-situ X-ray experiment on the structure of hydrous Mg-silicate melt under high pressure and high temperature2007

    • Author(s)
      Yamada, A., T.Inoue, S.Urakawa, K.Funakoshi, N.Funamori, T.Kikegawa, T.Irifune
    • Journal Title

      Geophys.Res.Lett. 34

      Pages: L10303

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Electron Conductive Three-Dimensional Polymer of Cuboidal C_<60>2006

    • Author(s)
      Yamanaka, S., A.Kubo, K.Inumaru, K.Komaguchi, N.S.Kini, T.Inoue, T.Irifune
    • Journal Title

      Phys. Rev. Lett. 96

      Pages: 1-4

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] The phase boundary between wadsleyite and ringwoodite in Mg_2SiO_4 determined by in situ X-ray diffraction2006

    • Author(s)
      Inoue, T., T.Irifune, Y.Higo, T.Sanehira, Y.Sueda, A.Yamada, T.Shinmei, D.Yamazaki, J.Ando, K.Funakoshi, W.Utsumi
    • Journal Title

      Phys. Chem. Minerals 33

      Pages: 106-114

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Mechanism of the olivine-ringwoodite transformation in the presence of aqueous fliud2006

    • Author(s)
      Ando, J., N.Tomioka, K.Matsubara, T.Inoue, T.Irifune
    • Journal Title

      Phys. Chem. Minerals 33

      Pages: 377-382

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] High-pressure and high-temperature stability and equation of state of superhydrous phase B2006

    • Author(s)
      Inoue, T., T.Ueda, Y.Higo, A.Yamada, T.Irifune, K.Funakoshi
    • Journal Title

      In "Earth's deep water cycle, Geophysical monograph series 168"(Ed. by Steven D. Jacobsen and Suzan van der Lee)(AGU)

      Pages: 147-157

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Towards mapping the three-dimentional distribution of water in the transition zone from P-velocity tomography and 660-km discontinuity depths2006

    • Author(s)
      Suetsugu, D, T.Inoue, A.Yamada, D.Zhao, M.Obayashi
    • Journal Title

      In "Earth's deep water cycle, Geophysical monograph series 168"(Ed. by Steven D. Jacobsen and Suzan van der Lee)(AGU)

      Pages: 237-249

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] The phase boundary between CaSiO_3 perovskite and Ca_2SiO_4 + CaSi_2O_5 determined by in situ X-ray observations2006

    • Author(s)
      Sueda, Y., T.Irifune, A.Yamada, T.Inoue, X.Liu, K.Funakoshi
    • Journal Title

      Geophys. Res. Lett. 33

      Pages: L10307

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Generation of pressures to ~60 GPa in Kawai-type apparatus and stability of MnGeO_3 perovskite at high pressure and high temperature2006

    • Author(s)
      Yamazaki, D., T.Shinmei, T.Inoue, T.Irifune, A.Nozawa, K.Funakoshi
    • Journal Title

      Am. Mineral. 91

      Pages: 1342-1345

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] The effect of iron on the elastic properties of ringwoodite at high pressure using ultrasonic interferometry2006

    • Author(s)
      Higo, Y., T.Inoue, B.Li, T.Irifune, R.C.Liebermann
    • Journal Title

      Phys. Earth Planet. Inter. 159

      Pages: 276-285

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Elastic properties of hydrous ringwoodite at high-pressure conditions2006

    • Author(s)
      Wang, J., S.V.Sinogeikin, T.Inoue, J.Bass
    • Journal Title

      Geophys. Res. Lett. 33

      Pages: L14308

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Cation vacancy and possible hydrogen positions in hydrous forsterite Mg_<1.985>Si_<0.993>H_<0.06>O_4 synthesized at 13.5 GPa and 1300 ℃2006

    • Author(s)
      Kudoh, Y., T.Kuribayashi, H.Kagi, T.Inoue
    • Journal Title

      J. Mineral. Petrol. Sci. 101

      Pages: 265-269

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Synchrotron IR study of hydrous ringwoodite (γ-Mg_2SiO_4) up to 30 GPa2006

    • Author(s)
      Chamarro Perez, E.M., I.Daniel, J.-C.Chervin, P.Dumas, J.D.Bass, T.Inoue
    • Journal Title

      Phys. Chem. Minerals 33

      Pages: 502-510

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Conditions and mechanism of formation of nano-polycrystalline diamonds on direct transformation from graphite and non-graphitic carbon at high pressure and temperature2006

    • Author(s)
      Sumiya, H., H.Yuea, T.Inoue, H.Ofuji, T.Irifune
    • Journal Title

      High Pressure Research 26

      Pages: 63-69

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Decomposition of kyanite and solubility of Al_2O_3 in stishovite at high pressure and high temperature conditions2006

    • Author(s)
      Liu, X., N.Nishiyama, T.Sanehira, T.Inoue, Y.Higo, S.Sakamoto
    • Journal Title

      Phys. Chem. Minerals 33

      Pages: 711-721

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Electron Conductive Three-Dimensional Polymer of Cuboidal C_<60>2006

    • Author(s)
      Yamanaka, S., A.Kubo, K.Inumaru, K.Komaguchi, N.S.Kini, T.Inoue, T.Irifune
    • Journal Title

      Phys.Rev.Lett. 96

      Pages: 1-4

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] The phase boundary between wadsleyite and ringwoodite in Mg_2SiO_4 determined by in situ X-ray diffraction2006

    • Author(s)
      Inoue, T., T.Irifune, Y.Higo, T.Sanehira, Y.Sueda, A.Yamada, T.Shinmei, D.Yamazaki, J.Ando, K.Funakoshi, W.Utsumi
    • Journal Title

      Phys.Chem.Minerals 33

      Pages: 106-114

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Mechanism of the olivine-ringwoodite transformation in the presence of aqueous fliud2006

    • Author(s)
      Ando, J., N.Tomioka, K.Matsubara, T.Inoue, T.Irifune
    • Journal Title

      Phys.Chem.Minerals 33

      Pages: 377-382

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] High-pressure and high-temperature stability and equation of state of superhydrous phase B2006

    • Author(s)
      Inoue, T., T.Ueda, Y.Higo, A.Yamada, T.Irifune, K.Funakoshi
    • Journal Title

      Earth's deep water cycle, Geophysical monograph series 168(Ed.by Steven D.Jacobsen, Suzan van der Lee)(AGU)

      Pages: 147-157

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Towards mapping the three-dimentional distribution of water in the transition zone from P-velocity tomography and 660-km discontinuity depths2006

    • Author(s)
      Suetsugu, D, T.Inoue, A.Yamada, D.Zhao, M.Obayashi
    • Journal Title

      Earth's deep water cycle, Geophysical monograph series 168(Ed.by Steven D.Jacobsen, Suzan van der Lee, AGU)

      Pages: 237-249

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] The phase boundary between CaSiO_3 perovskite and Ca_2SiO_4 + CaSi_2O_5 determined by in situ X-ray observations2006

    • Author(s)
      Sueda, Y., T.Irifune, A.Yamada, T.Inoue, X.Liu, K.Funakoshi
    • Journal Title

      Geophys.Res.Lett. 33, L10307

      Pages: doi:10.1029/2006GL025772

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Generation of pressures to 〜60 GPa in Kawai-type apparatus and stability of MnGeO_3 perovskite at high pressure and high temperature2006

    • Author(s)
      Yamazaki, D., T.Shinmei, T.Inoue, T.Irifune, A.Nozawa, K.Funakoshi
    • Journal Title

      Am.Mineral. 91

      Pages: 1342-1345

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] The effect of iron on the elastic properties of ringwoodite at high pressure using ultrasonic interferometry2006

    • Author(s)
      Higo, Y., T.Inoue, B.Li, T.Irifune, R.C.Liebermann
    • Journal Title

      Phys.Earth Planet.Inter. 159

      Pages: 276-285

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Elastic properties of hydrous ringwoodite at high-pressure conditions2006

    • Author(s)
      Wang, J., S.V.Sinogeikin, T.Inoue, J.Bass
    • Journal Title

      Geophys.Res.Lett. 33, L14308

      Pages: doi:10.1029/2006GL026441

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Cation vacancy and possible hydrogen positions in hydrous forsterite Mg_<1.985>Si_<0.993>H_<0.06>O_4 synthesized at 13.5 GPa and 1300 ℃2006

    • Author(s)
      Kudoh, Y., T.Kuribayashi, H.Kagi, T.Inoue
    • Journal Title

      J.Mineral.Petrol.Sci. 101

      Pages: 265-269

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Synchrotron IR study of hydrous ringwoodite (γ-Mg_2SiO_4) up to 30 GPa2006

    • Author(s)
      Chamarro Perez, E.M., I.Daniel, J.-C.Chervin, P.Dumas, J.D.Bass, T.Inoue
    • Journal Title

      Phys.Chem.Minerals 33

      Pages: 502-510

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Conditions and mechanism of formation of nano-polycrystalline diamonds on direct transformation from graphite and non-graphitic carbon at high pressure and temperature2006

    • Author(s)
      Sumiya, H., H.Yusa, T.Inoue, H.Ofuji, T.Irifune
    • Journal Title

      High Pressure Research 26

      Pages: 63-69

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Decomposition of kyanite and solubility of Al_2O_3 in stishovite at high pressure and high temperature conditions2006

    • Author(s)
      Liu, X., N.Nishiyama, T.Sanehira, T.Inoue, Y.Higo, S.Sakamoto
    • Journal Title

      Phys.Chem.Minerals 33

      Pages: 711-721

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Decomposition of brucite up to 20 GPa : evidence for high MgO-solubility in the liquid phase2005

    • Author(s)
      Fukui, H., T.Inoue, T.Yasui, T.Katsura, K.Funakoshi
    • Journal Title

      Eur. J. Mineral 17

      Pages: 261-267

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Grain growth of ringwoodite and its implication for rheology of the subducting slab2005

    • Author(s)
      Yamazaki, D., T.Inoue, M.Okamoto, T.Irifune
    • Journal Title

      Earth Planet. Sci. Lett. 236

      Pages: 871-881

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] High-temperature and high-pressure equation of state for the hexagonal phase in the system NaAlSiO_4-MgAl_2O_42005

    • Author(s)
      Shinmei, T., T.Sanehira, D.Yamazaki, T.Inoue, T.Irifune, K.Funakoshi, A.Nozawa
    • Journal Title

      Phys. Chem. Minerals 32

      Pages: 594-602

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Decomposition of brucite up to 20 GPa : evidence for high MgO-solubility in the liquid phase2005

    • Author(s)
      Fukui, H., T.Inoue, T.Yasui, T.Katsura, K.Funakoshi
    • Journal Title

      Eur.J.Mineral 17

      Pages: 261-267

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Grain growth of ringwoodite and its implication for rheology of the subducting slab2005

    • Author(s)
      Yamazaki, D., T.Inoue, M.Okamoto, T.Irifune
    • Journal Title

      Earth Planet.Sci.Lett. 236

      Pages: 871-881

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] High-temperature and high-pressure equation of state for the hexagonal phase in the system NaAlSiO_4-MgAl_2O_42005

    • Author(s)
      Shinmei, T., T.Sanehira, D.Yamazaki, T.Inoue, T.Irifune, K.Funakoshi, A.Nozawa
    • Journal Title

      Phys.Chem.Minerals 32

      Pages: 594-602

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Microstructure features of polycrystalline diamond synthesized directly from graphite under static high pressure2004

    • Author(s)
      Sumiya H., T.Irifune, A.Kurio, S.Sakamoto, T.Inoue
    • Journal Title

      J. Mat. Sci. 39

      Pages: 445-450

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Thermal expansion of wadsleyite, ringwoodite, hydrous wadsleyite and hydrous ringwoodite2004

    • Author(s)
      Inoue, T., Y.Tanimoto, T.Irifune, T.Suzuki, H.Fukui, O.Ohtaka
    • Journal Title

      Phys. Earth Planet. Inter. 143-144

      Pages: 279-290

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Precise determination of phase relations in pyrolite across the 660km seismic discontinuity by in situ X-ray diffraction and quench experiments2004

    • Author(s)
      Nishiyama, N., T.Irifune, T.Inoue, J.Ando, K.Funakoshi
    • Journal Title

      Phys. Earth Planet. Inter. 143-144

      Pages: 185-199

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Formation of pure polycrystalline diamond by direct conversion of graphite at high pressure and high temperature2004

    • Author(s)
      Irifune, T., A.Kurio, S.Sakamoto, T.Inoue, H.Sumiya, K.Funakoshi
    • Journal Title

      Phys. Earth Planet. Inter. 143-144

      Pages: 593-600

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Melting of enstatite from 13 to 18 GPa under hydrous conditions2004

    • Author(s)
      Yamada, A., T.Inoue, T.Irifune
    • Journal Title

      Phys. Earth Planet. Inter. 147

      Pages: 45-56

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] 地球内部の水とその分配2004

    • Author(s)
      井上 徹
    • Journal Title

      高圧力の科学と技術 14

      Pages: 242-247

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Microstructure features of polycrystalline diamond synthesized directly from graphite under static high pressure2004

    • Author(s)
      Sumiya H., T.Irifune, A.Kurio, S.Sakamoto, T.Inoue
    • Journal Title

      J.Mat.Sci. 39

      Pages: 445-450

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Thermal expansion of wadsleyite, ringwoodite, hydrous wadsleyite and hydrous ringwoodite2004

    • Author(s)
      Inoue, T., Y.Tanimoto, T.Irifune, T.Suzuki, H.Fukui, 0.Ohtaka
    • Journal Title

      Phys.Earth Planet.Inter. 143-144

      Pages: 279-290

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Precise determination of phase relations in pyrolite across the 660 km seismic discontinuity by in situ X-ray diffraction and quench experiments2004

    • Author(s)
      Nishiyama, N., T.Irifune, T.Inoue, J.Ando, K.Funakoshi
    • Journal Title

      Phys.Earth Planet.Inter. 143-144

      Pages: 185-199

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Formation of pure polycrystalline diamond by direct conversion of graphite at high pressure and high temperature2004

    • Author(s)
      Irifune, T., A.Kurio, S.Sakamoto, T.Inoue, H.Sumiya, K.Funakoshi
    • Journal Title

      Phys.Earth Planet.Inter. 143-144

      Pages: 593-600

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Melting of enstatite from 13 to 18 GPa under hydrous conditions2004

    • Author(s)
      Yamada, A., T.Inoue, T.Irifune
    • Journal Title

      Phys.Earth Planet.Inter. 147

      Pages: 45-56

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Distribution of water in the Earth's interior.2004

    • Author(s)
      Toru Inoue
    • Journal Title

      The review of high pressure science and technology 14

      Pages: 242-247

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Ultrahard polycrystalline diamond from graphite2003

    • Author(s)
      Irifune, T., A.Kurio, S.Sakamoto, T.Inoue, H.Sumiya
    • Journal Title

      Nature 421

      Pages: 599-600

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Elastic properties of hydrous ringwoodite2003

    • Author(s)
      Wang, J., S.V.Sinogeikin, T.Inoue, J.D.Bass
    • Journal Title

      Am. Mineral. 88

      Pages: 1608-1611

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Elastic properties of hydrous ringwoodite2003

    • Author(s)
      Wang, J., S.V.Sinogeikin, T.Inoue, J.D.Bass
    • Journal Title

      Am.Mineral. 88

      Pages: 1608-1611

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 2008-05-27  

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