2017 Fiscal Year Final Research Report
Development of doubly-bonded species between heavier group 14 elements and oxygen and their application for activation of small molecules
| Project/Area Number |
15H03788
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Kindai University |
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Principal Investigator |
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| Project Period (FY) |
2015-04-01 – 2018-03-31
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| Keywords | 高周期14族元素 / シラノン / ゲルマノン / スタンナノン / シリレン / ゲルミレン / スタンニレン / 立体保護基 |
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| Outline of Final Research Achievements |
Doubly-bonded species between heavier group 14 elements and oxygen atom have been studied by the introduction of the fused-ring bulky "Rind" groups. A series of diaryltetrylenes have been synthesized, whose molecular structures and electronic properties have been elucidated by the experimental and computational studies. Novel tin-oxygen doubly-bonded species, stannanone, have been successfully obtained by the reaction of the corresponding stannylene with nitrous oxide gas. The reactions of stannanone with small molecules such as water and carbon dioxide have been investigated.
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| Free Research Field |
無機化学
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