2017 Fiscal Year Final Research Report
Synthesis of Metal Sheet Sandwich Clusters
| Project/Area Number |
15H03789
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
山本 浩二 分子科学研究所, 大学共同利用機関等の部局等, 助教 (70647198)
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| Project Period (FY) |
2015-04-01 – 2018-03-31
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| Keywords | 金属クラスター / 錯体化学 / 有機金属化学 |
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| Outline of Final Research Achievements |
The sandwich structures is one of the most important molecular designs for transition metal compounds. In this project, we aimed at developing the structural concept of sandwich compounds containing metal sheet clusters. We found that an eight-membered carbocylce, cyclooctatetraene, has the ability to stabilize the metal sheet sandwich clusters with cyclopentadienyl- or vinylarene counter-ligands. Furthermore, we also elucidated the coordination behavior of hetero-arenes to transition metals.
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| Free Research Field |
錯体化学、有機金属化学
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