2017 Fiscal Year Final Research Report
Construction of functional molecular arrays using DNA as a structural scaffold
| Project/Area Number |
15H03884
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Device related chemistry
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| Research Institution | University of Hyogo |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
高田 忠雄 兵庫県立大学, 工学研究科, 准教授 (60511699)
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| Project Period (FY) |
2015-04-01 – 2018-03-31
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| Keywords | DNA / 光 / 電子移動 / 機能性色素分子 / デバイス / 光電変換 / バイオセンサー |
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| Outline of Final Research Achievements |
Molecular arrays of functional chromophores placed in a specific and precise manner were constructed exploiting DNA as a structural scaffold, potentially realizing efficient light harvesting, migration, and electron transport. We developed new methods to prepare DNA with molecular array composed of the functional chromophores using conventional DNA synthesis, post-synthetic modification using click reaction, and enzymatic reaction by uracil DNA glycosylase. Photochemical and physical properties of the chromophores in DNA were characterized using spectroscopic methods and (photo)electrochemical measurements.
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| Free Research Field |
生体関連化学
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