2017 Fiscal Year Final Research Report
Development of hydrogenation and dehydrogenation catalysts using electride with hydrogen storage ability
Project/Area Number |
15H04183
|
Research Category |
Grant-in-Aid for Scientific Research (B)
|
Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Catalyst/Resource chemical process
|
Research Institution | Tokyo Institute of Technology |
Principal Investigator |
Kitano Masaaki 東京工業大学, 元素戦略研究センター, 准教授 (50470117)
|
Project Period (FY) |
2015-04-01 – 2018-03-31
|
Keywords | エレクトライド / 水素化物 / 選択水素化 / アンモニア合成 |
Outline of Final Research Achievements |
In the present study, we have focused on the hydrogenation or dehydrogenation reactions over electride (or hydride) supported metal nanoparticle catalysts. And the relationship between the catalytic activity and the hydrogen storage ability was investigated. C12A7 supported Ru-Fe bimetallic catalyst exhibited high activity for selective hydrogenation of unsaturated aldehydes. Ca2NH and Ca(NH2)2 supported Ru catalysts showed excellent activity for low-temperature ammonia synthesis.
|
Free Research Field |
触媒化学
|