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2016 Fiscal Year Annual Research Report

リチウム系水素貯蔵物質の水素吸蔵放出速度とリチウムイオン電導度に関する研究

Research Project

Project/Area Number 15J00752
Research InstitutionHokkaido University

Principal Investigator

張 騰飛  北海道大学, 工学研究院, 特別研究員(PD)

Project Period (FY) 2015-04-24 – 2017-03-31
KeywordsLi2TiO3 / MgTiO3 / LiAlH4 / TEM / DFT
Outline of Annual Research Achievements

During this year (2016),I have done the experiment on the desorption properties of lithium alanate (LiAlH4) doped with lithium metatitanate (Li2TiO3). Transmission electron microscopy (TEM) observations help understand the catalytic effect of Li2TiO3 in the nanoscale. I have set the equipment of AC-impedance for investigated the lithium ionic conductivity of different samples, such as LiAlH4/ Li2TiO3, LiBH4/ Li2TiO3, LiNH2/ Li2TiO3, and LiH/Li2TiO3.
I have investigated geikielite (MgTiO3) as catalyst in the complex hydrides, which shows good catalytic effect in LiAlH4 and MgH2.
I have already published two papers in international journal. Another one manuscript has already been prepared and will submit soon.

Research Progress Status

28年度が最終年度であるため、記入しない。

Strategy for Future Research Activity

28年度が最終年度であるため、記入しない。

  • Research Products

    (6 results)

All 2017 2016

All Journal Article (2 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 2 results,  Acknowledgement Compliant: 2 results) Presentation (3 results) (of which Int'l Joint Research: 2 results,  Invited: 1 results) Funded Workshop (1 results)

  • [Journal Article] Enhancement of hydrogen desorption kinetics inmagnesium hydride by doping with lithium metatitanate2017

    • Author(s)
      Tengfei Zhang, Shigehito Isobe, Ankur Jain, Yongming Wang, Shotaro Yamaguchi, Hiroki Miyaoka, Takayuki Ichikawa, Yoshitsugu Kojima, Naoyuki Hashimoto
    • Journal Title

      Journal of Alloys and Compounds

      Volume: 711 Pages: 400-405

    • DOI

      doi.org/10.1016/j.jallcom.2017.03.361

    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Enhanced hydrogen desorption properties of LiAlH4 by doping lithium metatitanate2016

    • Author(s)
      Tengfei Zhang, Shigehito Isobe, Yongming Wang, Chaomei Liu, Naoyuki Hashimoto, Keisuke Takahashi
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 18 Pages: 27623-27629

    • DOI

      10.1039/c6cp05014j

    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Presentation] Effect of Lithium Ion Conduction on Hydrogen Desorption of LiNH2-LiH Solid Composite2016

    • Author(s)
      Tengfei Zhang
    • Organizer
      Seminar in Fudan University
    • Place of Presentation
      Fudan University, Shanghai, China
    • Year and Date
      2016-06-29
    • Int'l Joint Research
  • [Presentation] Hydrogen absorption of Pd thin films observed by in-situ TEM with an environmental cell2016

    • Author(s)
      Tengfei Zhang
    • Organizer
      MGI Seminar of Shanghai University
    • Place of Presentation
      Shanghai University, Shanghai, China
    • Year and Date
      2016-06-27 – 2016-06-28
    • Int'l Joint Research / Invited
  • [Presentation] Effect of Lithium Ion Conduction on Hydrogen Desorption of LiNH2-LiH Solid Composite2016

    • Author(s)
      Tengfei Zhang
    • Organizer
      Seminar in Hiroshima University
    • Place of Presentation
      Hiroshima University, Japan
    • Year and Date
      2016-06-24
  • [Funded Workshop] MGI Seminar of Shanghai University2016

    • Place of Presentation
      Shanghai, China
    • Year and Date
      2016-06-27 – 2016-06-29

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Published: 2018-01-16  

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