2008 Fiscal Year Final Research Report
Programming Spatial Arrangements and Specific Dynamic Function of Metal Complexes using Artificial Ligands with Multi-Binding Sites
| Project/Area Number |
16105001
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| Research Category |
Grant-in-Aid for Scientific Research (S)
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| Allocation Type | Single-year Grants |
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| Research Field |
Inorganic chemistry
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| Research Institution | The University of Tokyo |
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Principal Investigator |
SHIONOYA Mitsuhiko The University of Tokyo, 大学院・理学系研究科, 教授 (60187333)
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| Co-Investigator(Kenkyū-buntansha) |
TANAKA Kentaro 名古屋大学, 大学院・理学研究科, 教授 (40281589)
HIRAOKA Shuichi 東京大学, 大学院・総合文化研究科, 教授 (10322538)
TASHRO Shohei 東京大学, 大学院・理学系研究科, 助教 (80420230)
SHIRO Motoo , 理学電機・X線研究所, 嘱託研究員
KATO Tatsuhisa 城西大学, 理学部, 教授(現在、京都大学) (80175702)
KIMURA Eiichi 広島大学, 名誉教授 (30034010)
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| Co-Investigator(Renkei-kenkyūsha) |
UBE Hitoshi 東京大学, 大学院・理学系研究科, 助教 (00512138)
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| Project Period (FY) |
2004 – 2008
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| Keywords | 超分子 / 金属イオン配列 / 動的機能 / 人工DNA / 分子運動素子 |
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| Research Abstract |
In this study, we have synthesized a variety of functional metal complexes with the aid of bio-inspired and completely artificial ligands with multi-binding sites which include precisely programmed information on the spatial arrangements of metals, and explored specific properties and dynamic functions based on the modes of metal arrays. As the result, heterologous metal arrays using artificial DNA, nanocapsules with dynamic functions, and molecular motional devices such as molecular ball bearings and a molecular crank mechanism have been successfully constructed.
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