2005 Fiscal Year Final Research Report Summary
Development of Highly Functionalized Hybrid Catalysts Aiming Toward Environmentally Friendly Processes for Materials Transformation
| Project/Area Number |
16206078
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| Research Category |
Grant-in-Aid for Scientific Research (A)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Catalyst/Resource chemical process
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| Research Institution | Osaka University |
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Principal Investigator |
KANEDA Kiyotomi Osaka University, Graduate School of Engineering Science, Professor, 大学院・基礎工学研究科, 教授 (90029554)
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| Co-Investigator(Kenkyū-buntansha) |
EBITANI Kohki Osaka University, Graduate School of Engineering Science, Associate Professor, 大学院・基礎工学研究科, 助教授 (50242269)
MIZUGAKI Tomoo Osaka University, Graduate School of Engineering Science, Research Assistant, 大学院・基礎工学研究科, 助手 (50314406)
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| Project Period (FY) |
2004 – 2005
|
| Keywords | Green and Sustainable Chemistry / Catalyst Design / Selective Oxidations / Carbon-Carbon Bond Formations / One-pot Synthesis / Hydroxyapatite / Montmorillonite / Hydrotalcite |
|---|
| Research Abstract |
In this research project, we demonstrated an effective approach to Green and Sustainable Chemistry by designing heterogeneous metal catalysts using inorganic solids as macroligands, and found their outstanding catalytic performances for a variety of material transformations including selective oxidations, carbon-carbon bond-forming reactions, one-pot syntheses, dehalogenation, and fixation of carbon dioxide. Based on the unique properties of hydroxyapatite, montmorillonite, and hydrotalcite as advanced supports, various hybrid catalysts were created with respect to the target reactions.
Catalytic systems incorporating the heterogeneous metal catalysts can offer significant benefits in achieving simple and clean organic transformations because they have the following advantages : (i)they allow the use of non-polluting oxidants, (ii)they possess high catalytic activity and selectivity, (iii)they have high substrate tolerance, (iv)they allow a simple work-up procedure and easy recovery of the catalyst, and (v)they are recyclable. By applying concepts from coordination chemistry, we have developed a preparation for nanostructured metal species that is much simpler than previous synthetic methods for solid-supported metal catalysts and provides a strong protocol for preparing catalytically active compounds that are uniform in composition and distribution on solid surfaces.
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Research Products
(70 results)
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[Book] ファインケミカル2006
Author(s)
金田 清臣
Total Pages
10
Publisher
シーエムシー出版
Description
「研究成果報告書概要(和文)」より
-
[Book] 化学と工業2005
Author(s)
金田 清臣
Total Pages
3
Publisher
日本化学会
Description
「研究成果報告書概要(和文)」より
-
[Book] ファルマシア2005
Author(s)
金田 清臣
Total Pages
4
Publisher
日本薬学会
Description
「研究成果報告書概要(和文)」より
-
[Book] 機能材料2005
Author(s)
金田 清臣
Total Pages
9
Publisher
シーエムシー出版
Description
「研究成果報告書概要(和文)」より
-
[Book] 分離技術2005
Author(s)
本倉 健
Total Pages
6
Publisher
分離技術会
Description
「研究成果報告書概要(和文)」より
-
[Book] ファインケミカル2005
Author(s)
海老谷 幸喜
Total Pages
8
Publisher
シーエムシー出版
Description
「研究成果報告書概要(和文)」より
-
-
-
[Book] ファインケミカル2004
Author(s)
金田 清臣
Total Pages
11
Publisher
シーエムシー出版
Description
「研究成果報告書概要(和文)」より
-
[Book] 触媒2004
Author(s)
金田 清臣
Total Pages
6
Publisher
触媒学会
Description
「研究成果報告書概要(和文)」より
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-
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[Book] 表面2004
Author(s)
金田 清臣
Total Pages
8
Publisher
広信社
Description
「研究成果報告書概要(和文)」より
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