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2018 Fiscal Year Annual Research Report

Light energy conversion system using Bi-based perovskite hybrid compounds

Research Project

Project/Area Number 17J10578
Research InstitutionToin University of Yokohama

Principal Investigator

KULKARNI ASHISH  桐蔭横浜大学, 大学院工学研究科, 特別研究員(PD)

Project Period (FY) 2017-04-26 – 2019-03-31
KeywordsSilver-bismuth iodide / non-toxic / Solar cells / High stable
Outline of Annual Research Achievements

Low stability of organic-inorganic lead halide perovskite and toxicity of lead (Pb) still remains a concern. On the other hand, the performance of non-toxic, high stable bismuth based lower dimensional perovskite and bismuth iodide (BiI3) semiconducting material has been limited due to high intrinsic carrier concentration, high exciton binding energy and poor morphology. To address this, we modulated a solvent-mediated adduct for one-step crystallization of lead-free AgBi2I7 at a lower temperature (90 °C) and to obtain remnant BiI3 by controlling the nature of the substrate and precursor concentration. This eventually resulted in remarkable enhancement in the power conversion efficiency, reaching 2.12%, and the long-term stability of AgBi2I7 solar cells towards light, heat and humidity.

Research Progress Status

平成30年度が最終年度であるため、記入しない。

Strategy for Future Research Activity

平成30年度が最終年度であるため、記入しない。

  • Research Products

    (6 results)

All 2019 2018

All Journal Article (3 results) (of which Int'l Joint Research: 3 results) Presentation (3 results)

  • [Journal Article] Performance enhancement of AgBi2I7 solar cells by modulating a solvent-mediated adduct and tuning remnant BiI3 in one-step crystallization2019

    • Author(s)
      Ashish Kulkarni, Ajay Jena, Masashi Ikegami, Tsutomu Miyasaka
    • Journal Title

      Chemical Communication

      Volume: 55 Pages: 4031-4034

    • DOI

      10.1039/C9CC00733D

    • Int'l Joint Research
  • [Journal Article] Halide Perovskite Photovoltaics: Background, Status, and Future Prospects2019

    • Author(s)
      Ajay Jena, Ashish Kulkarni, Tsutomu Miyasaka
    • Journal Title

      Chemical Reviews

      Volume: 119 (5) Pages: 3036-3103

    • DOI

      10.1021/acs.chemrev.8b00539

    • Int'l Joint Research
  • [Journal Article] Stabilization of α-CsPbI3 in Ambient Room Temperature Conditions by Incorporating Eu into CsPbI32018

    • Author(s)
      Ajay Jena, Ashish Kulkarni, Yoshitaka Sanehira, Masashi Ikegami, Tsutomu Miyasaka
    • Journal Title

      Chemistry of Materials

      Volume: 30 (19) Pages: 6668-6674

    • DOI

      10.1021/acs.chemmater.8b01808

    • Int'l Joint Research
  • [Presentation] Highly Stable and Efficient Silver-Bismuth Halide Materials for Lead-Free Perovskite Solar Cells2019

    • Author(s)
      Ashish Kulkarni, Ajay Jena, Masashi Ikegami, Tsutomu Miyasaka
    • Organizer
      International Conference on Perovskite and Organic Photovoltaics and Optoelectronics (IPEROP)
  • [Presentation] Addressing Lead Toxicity with Silver-Bismuth Halide Materials for Non-Toxic and Stable Solar Cells2019

    • Author(s)
      Ashish Kulkarni, Tsutomu Miyasaka
    • Organizer
      International Workshop and Conference on Perovskite and Hybrid Photovoltaics (ICPHPV), New-Delhi, India
  • [Presentation] Solvent Engineering to Enhance the Performance of Silver-Bismuth Halide Material for Lead-Free Perovskite Solar Cells2019

    • Author(s)
      Ashish Kulkarni, Masashi Ikegami, Tsutomu Miyasaka
    • Organizer
      First Indian Materials Conclave and 30th Annual General Meeting of MRSI (MRSIAGM), Bangalore, India

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Published: 2019-12-27  

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