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2010 Fiscal Year Final Research Report

New developments in polymer science through polymer chain imaging : empirical foundation research using scanning near-field optical microscopy

Research Project

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Project/Area Number 18105005
Research Category

Grant-in-Aid for Scientific Research (S)

Allocation TypeSingle-year Grants
Research Field Polymer chemistry
Research InstitutionKyoto University

Principal Investigator

ITO Shinzaburo  Kyoto University, 大学院・工学研究科, 教授 (50127049)

Co-Investigator(Kenkyū-buntansha) OHKITA Hideo  京都大学, 大学院・工学研究科, 准教授 (50301239)
AOKI Hiroyuki  京都大学, 先端医工学研究ユニット, 准教授 (90343235)
BENTEN Hiroaki  京都大学, 大学院・工学研究科, 助教 (60422995)
Project Period (FY) 2006 – 2010
Keywords高分子構造 / 近接場光学 / 走査顕微鏡 / 蛍光法 / 単一分子鎖 / 高分子薄膜・表面
Research Abstract

The spatial dimensions ranging from 10nm to 100nm, which is called the critical length in polymer science, have been visualized by scanning near-field optical microscopy with an extremely high sensitivity and a high resolution. This emerging technology enabled us to show up the real images of single polymer chains embedded in polymer matrices and molecular assemblies. Consequently, the macroscopic physical properties and functions of polymeric materials, that used to be studied by statistics and/or analytical models, have come to be molecular level subjects investigated from a real image of polymer chain.

  • Research Products

    (15 results)

All 2011 2010 2009 2007 Other

All Journal Article (5 results) (of which Peer Reviewed: 5 results) Presentation (6 results) Book (3 results) Remarks (1 results)

  • [Journal Article] Relaxation of Single Polymer Chain in Poly(methyl methacrylate) Films under Uniaxial Extension Observed by Scanning Near-field Optical Microscopy2011

    • Author(s)
      Toru Ube, Hiroyuki Aoki, Shinzaburo Ito, Jun-ichi Horinaka, Toshikazu Takigawa, Toshiro Masuda
    • Journal Title

      Macromolecules in press

    • Peer Reviewed
  • [Journal Article] Conformation of Single Block Copolymer Chain in Two-Dimensional Microphase-Separated Structure Studied by Scanning Near-Field Optical Microscopy2009

    • Author(s)
      Ryojun Sekine, Hiroyuki Aoki, Shinzaburo Ito
    • Journal Title

      J.Phys.Chem.B 113

      Pages: 7095-7100

    • Peer Reviewed
  • [Journal Article] Conformation of Single Homopolymer Chain in Microphase-Separated Block Copolymer Monolayer Studied by Scanning Near-Field Optical Microscopy2009

    • Author(s)
      Yasunari Tamai, Ryojun Sekine, Hiroyuki Aoki, Shinzaburo Ito
    • Journal Title

      Macromolecules 42

      Pages: 4224-4229

    • Peer Reviewed
  • [Journal Article] Affine Deformation of Single Polymer Chain in Poly(methyl methacrylate) Films under Uniaxial Extension Observed by Scanning Near-Field Optical Microscopy2009

    • Author(s)
      Toru Ube, Hiroyuki Aoki, Shinzaburo Ito, Jun-ichi Horinaka, Toshikazu Takigawa, Toshiro Masuda
    • Journal Title

      Polymer 50

      Pages: 3016-3021

    • Peer Reviewed
  • [Journal Article] Chain End Distribution of Block Copolymer in Two-Dimensional Microphase-Separated Structure Studied by Scanning Near-Field Optical Microscopy2009

    • Author(s)
      Ryojun Sekine, Hiroyuki Aoki, Shinzaburo Ito
    • Journal Title

      J.Phys.Chem.B 113

      Pages: 12865-12869

    • Peer Reviewed
  • [Presentation] Direct Evaluation of Chain Dimension of Single Macromolecule by Super-Resolution Optical Microscopy Technique2010

    • Author(s)
      Hiroyuki Aoki, Kazuki Mori, Shinzaburo Ito
    • Organizer
      Pacifichem 2010
    • Place of Presentation
      Hawaii, USA
    • Year and Date
      2010-12-15
  • [Presentation] Dynamics of Single Polymer Chain Studied by Defocus Fluorescence Imaging Technique2010

    • Author(s)
      Hiroyuki Aoki, Toshiaki Takahashi, Shinzaburo Ito
    • Organizer
      5th Pacific Rim Conference on Rheology
    • Place of Presentation
      Sapporo
    • Year and Date
      2010-08-05
  • [Presentation] Conformation of Single Polymer Chain during the Extension and Relaxation Processes Studied by Scanning Near-Field Optical Microscopy2010

    • Author(s)
      Toru Ube, Hiroyuki Aoki, Shinzaburo Ito, Jun-ichi Horinaka
    • Organizer
      MACRO2010 : 43rd IUPAC World Polymer Congress
    • Place of Presentation
      Glasgow, UK
    • Year and Date
      2010-07-13
  • [Presentation] Properties of Single Polymer Chain Studied by Near-Field/Super-Resolution Optical Microscopy2010

    • Author(s)
      Hiroyuki Aoki
    • Organizer
      6th Single Molecule Meeting
    • Place of Presentation
      東京工業大学
    • Year and Date
      2010-03-10
  • [Presentation] Conformation of Single Polymer Chain in Uniaxally Stretched Film Studied by Scanning Near-Field Optical Microscopy2009

    • Author(s)
      Toru Ube, Hiroyuki Aoki, Shinzaburo Ito, Jun-ichi Horinaka
    • Organizer
      11th Pacific Polymer Conference
    • Place of Presentation
      Cairns, Australia
    • Year and Date
      2009-12-08
  • [Presentation] Scanning Near-Field Optical Microscopy Study for Single Homopolymer Chain Location and Orientation in Microphase-Separated Block Copolymer Monolayer2009

    • Author(s)
      Yasunari Tamai, Hiroyuki Aoki, Shinzaburo Ito
    • Organizer
      7th Asia-Pacific Conference on Near-Field Optics
    • Place of Presentation
      Jeju Island, Korea
    • Year and Date
      2009-11-26
  • [Book] 近接場光学顕微鏡による高分子材料の構造評価(近接場光のセンシング・イメージング技術への応用-最新のバイオ・化学・デバイス分野への展開-)(民谷栄一,朝日剛 監修)第10章2010

    • Author(s)
      青木裕之
    • Total Pages
      113-123
    • Publisher
      シーエムシー出版
  • [Book] 近接場光学顕微鏡による高分子薄膜・表面領域のナノ空間観察(高分子表面・界面分析法の新展開)2009

    • Author(s)
      青木裕之、伊藤紳三郎
    • Total Pages
      164-175
    • Publisher
      シーエムシー出版
  • [Book] 近接場光学顕微鏡-光でみるナノの世界-(高分子先端材料One Point別巻 高分子分析技術最前線)(高分子学会編)2007

    • Author(s)
      青木裕之
    • Total Pages
      39-51
    • Publisher
      共立出版
  • [Remarks] ホームページ等

    • URL

      http://photo.polym.kyoto-u.ac.jp/

URL: 

Published: 2012-01-26   Modified: 2016-04-21  

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