Basic research on development of new ionics devices

2009 Fiscal Year Final Research Report

• Project/Area Number: 18205024
• Research Category: Grant-in-Aid for Scientific Research (A)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Inorganic industrial materials
• Research Institution: Tokyo Institute of Technology
• Principal Investigator: KANNO Ryoji Tokyo Institute of Technology, 大学院・総合理工学研究科, 教授 (90135426)
• Co-Investigator(Kenkyū-buntansha): SONOYAMA Noriyuki 名古屋工業大学, 大学院・工学部, 准教授 (50272696) ; YONEMURA Masao 茨城大学, 理工学研究科, 助教 (60400602) ; TAMURA Kazuhisa 日本原子力研究開発機構, 量子ビーム応用研究部門, 研究員 (10360405)
• Co-Investigator(Renkei-kenkyūsha): YAMADA Atsuo 東京工業大学, 大学院・総合理工学研究科, 准教授 (30359690) ; KOBAYASHI Hironori 産業技術総合研究所, ユピキタスエネルギー研究部門, 研究員 (30357016) ; TORIKAI Naoya 高エネルギー加速器研究機構, 物質構造科学研究所, 准教授 (70300671)
• Project Period (FY): 2006 – 2009
• Keywords: 固体イオニクス / 二次電池 / 固体電池 / 電気化学界面

Research Abstract

Analysis techniques at electrochemical interfaces have been developed to design new ionic devices suitable for high power-density battery operation. Interfacial reactions of lithium batteries have been determined by new in situ X-ray surface scattering measurements using epitaxial thin-films electrodes. Furthermore, mechanistic studies for new solid electrolyte with highest lithium conductivity show a guideline for development of new materials for energy devices.

Research Products

• [Journal Article] Surface characterization of LiFePO4 epitaxial thin films by X-ray/neutron reflectometry (2010)
  • Author(s): Masaaki Hirayama, Masao Yonemura, Kouta Suzuki, Naoya Torikai, Hillary Smith, Erik Watkinsand, Jarek Majewski, Ryoji Kanno
  • Journal Title: Electrochemistry 78 Pages: 413-415
  • Peer Reviewed
• [Journal Article] Crystal Structure of High-Temperature Phase of Lithium Ionic Conductor, Li3PS4 (2010)
  • Author(s): Kenji Homma, Masao Yonemura, Miki Nagao, Masaaki Hirayama, Ryoji Kanno
  • Journal Title: J. Phys. Soc. Jpn. 79 Pages: 90-93
  • Peer Reviewed
• [Journal Article] Structural changes in surface and bulk LiNi0. 5Mn0. 5O2 during electrochemical reaction on epitaxial thin-film electrodes characterized by in situ X-ray scattering (2010)
  • Author(s): Kazuyuki Sakamoto, Masaaki Hirayama, Hiroaki Konishi, Noriyuki Sonoyama, Nicolas Dupre, Dominique Guyomard, Kazuhisa Tamura, Jun'ichiro Mizuki, Ryoji Kanno
  • Journal Title: Physical Chemistry Chemical Physics 12 Pages: 3815-3823
  • Peer Reviewed
• [Journal Article] Synthesis of LixMnO2 by chemical lithiation in an aqueous media (2009)
  • Author(s): Won Il Jung, Miki Nagao, Cedric Pitteloud, Atsuo Yamada, Ryoji Kanno
  • Journal Title: Journal of Power Sources 195 Pages: 3328-3332
  • Peer Reviewed
• [Journal Article] All solid-state sheet battery using lithium inorganic solid electrolyte, thio-LISICON (2009)
  • Author(s): Taro Inada, Takeshi Kobayashi, Noriyuki Sonoyama, Atsuo Yamada, Shigeo Kondo, Miki Nagao, Ryoji Kanno
  • Journal Title: Journal of Power Sources 194 Pages: 1085-1088
  • Peer Reviewed
• [Journal Article] Surface Structure of LiNi0. 8Co0. 2O2: a New Experimental Technique Using in Situ X-ray Diffraction and Two-Dimensional Epitaxial Film Electrodes (2009)
  • Author(s): Kazuyuki Sakamoto, Masaaki Hirayama, Noriyuki Sonoyama, Daisuke Mori, Atsuo Yamada, Kazuhisa Tamura, Jun ' ichiro Mizuki, Ryoji Kanno
  • Journal Title: Chemistry of Materials 21 Pages: 2632-2640
  • Peer Reviewed
• [Journal Article] Chemically oxidizedγ-MnO2 for lithium secondary batteries: structure and intercalation/ deintercalation properties (2009)
  • Author(s): Won Il Jung, Miki Nagao, Ce ´ dric Pitteloud, Keiji Itoh, Atsuo Yamada, Ryoji Kanno
  • Journal Title: Journal of Materials Chemistry 19 Pages: 800-806
  • Peer Reviewed
• [Journal Article] All solid-state battery with sulfur electrode and thio-LISICON electrolyte (2008)
  • Author(s): Takeshi Kobayashi, Yuki Imade, Daisuke Shishihara, Kenji Homma, Miki Nagao, Ryota Watanabe, Toshiyuki Yokoi, Atsuo Yamada, Ryoji Kanno, Takashi Tatsumi
  • Journal Title: Journal of Power Sources 182 Pages: 621-625
  • Peer Reviewed
• [Journal Article] Interfacial reactions at electrode/ electrolyte boundary in all solid-state lithium battery using inorganic solid electrolyte, thio-LISICON (2008)
  • Author(s): Takeshi Kobayashi, Atsuo Yamada, Ryoji Kanno
  • Journal Title: Electrochimica Acta 53 Pages: 5045-5050
  • Peer Reviewed
• [Journal Article] Chemically oxidized manganese dioxides for lithium secondary batteries (2007)
  • Author(s): Won Il Jung, Kazuyuki Sakamoto, Cedric Pitteloud, Noriyuki Sonoyama, Atsuo Yamada, Ryoji Kanno
  • Journal Title: Journal of Power Sources 174 Pages: 1137-1141
  • Peer Reviewed
• [Journal Article] Mechanistic study on lithium intercalation using a restricted reaction field in LiNi0. 5Mn0. 5O2 (2007)
  • Author(s): Kazuyuki Sakamoto, Hiroaki Konishi, Noriyuki Sonoyama, Atsuo Yamada, Kazuhisa Tamura, Jun'ichiro Mizuki, Ryoji Kanno
  • Journal Title: Journal of Power Sources 174 Pages: 678-682
  • Peer Reviewed
• [Journal Article] Characterization of electrode/electrolyte interface for lithium batteries using in situ synchrotron X-ray reflectometry-A new experimental technique for LiCoO2 model electrode (2007)
  • Author(s): Masaaki Hirayama, Noriyuki Sonoyama, Takeshi Abe, Machiko Minoura, Masumi Ito, Daisuke Mori, Atsuo Yamada, Ryoji Kanno, Takahito Terashima, Mikio Takano, Kazuhisa Tamura, Jun'ichiro Mizuki
  • Journal Title: Journal of Power Sources 168 Pages: 493-500
  • Peer Reviewed
• [Journal Article] Characterization of electrode/electrolyte interface using in situ X-ray reflectometry and LiNi0. 8Co0. 2O2 epitaxial film electrode synthesized by pulsed laser deposition method (2007)
  • Author(s): Masaaki Hirayama, Kazuyuki Sakamoto, Tetsuya Hiraide, Daisuke Mori, Atsuo Yamada, Ryoji Kanno, Noriyuki Sonoyama, Kazuhisa Tamura, Jun'ichiro Mizuki
  • Journal Title: Electrochimica Acta 53 Pages: 871-881
  • Peer Reviewed
• [Journal Article] Characterization of electrode/electrolyte interface with X-ray reflectometry and epitaxial-film LiMn2O4 electrode (2007)
  • Author(s): Masaaki Hirayama, Noriyuki Sonoyama, Masumi Ito, Machiko Minoura, Daisuke Mori, Atsuo Yamada, Kazuhisa Tamura, Jun'ichiro Mizuki, Ryoji Kanno
  • Journal Title: J. Electrochem. Soc. 154 Pages: A1065-A1072
  • Peer Reviewed
• [Presentation] Interfacial phenomena of lithium battery electrodes studied by in-situ X-ray scattering methods (2009)
  • Author(s): Ryoji Kanno, Masaaki Hirayama
  • Organizer: scattering methods" The 50th battery symposium in Japan
  • Place of Presentation: Kyoto, Japan
  • Year and Date: 2009-12-02
• [Presentation] Interfacial Structure Changes of Intercalation Materials during Electrochemical Process (2009)
  • Author(s): Ryoji Kanno
  • Organizer: 2nd International Conference on Advanced Lithium Batteries for Automobile Applications (ABAA)
  • Place of Presentation: Tokyo, Japan
  • Year and Date: 2009-11-26
• [Presentation] All Solid-state Lithium-sulfur Battery Using Meso-sized Electrode Structure (2009)
  • Author(s): R. Kanno, M. Nagao, Y. Imade, K. Homma, Y. Yamakawa, R. Watanabe, T. Yokoi, T. Tatsumi
  • Organizer: 216th Meeting of The Electrochemical Society
  • Place of Presentation: Wienna, Austria
  • Year and Date: 2009-10-09
• [Presentation] Structure and electrochemical properties of epitaxial thin film electrodes for lithium batteries (2009)
  • Author(s): M. Hirayama, T. Toujigamori, K. Suzuki, W. Cho, K. Tamura, J. Mizuki, R. Kanno
  • Organizer: 216th Meeting of The Electrochemical Society
  • Place of Presentation: Wienna, Austria
  • Year and Date: 2009-10-07
• [Presentation] All solid-state battery with sulfur electrode and Thio-LISICON electrolyte (2008)
  • Author(s): Takeshi Kobayashi, Yuki Imade, Miki Nagao, Daisuke Shishihara, Kenji Homma, Ryota Watanabe, Toshiyuki Yokoi, Atsuo Yamada, Ryoji Kanno, Takashi Tatsumi
  • Organizer: International Meeting on Lithium Batteries (IMLB-14)
  • Place of Presentation: Tianjin, China
  • Year and Date: 20080622-20080628
• [Presentation] Surface and bulk structure changes of intercalation electrodes at electrochemical reaction (2008)
  • Author(s): Ryoji Kanno, Masaaki Hirayama, Kazuyuki Sakamoto, Atsuo Yamada, Noriyuki Sonoyama, Kazuhisa Tamura, Junichiro Mizuki
  • Organizer: International Meeting on Lithium Batteries (IMLB-14)
  • Place of Presentation: Tianjin, China
  • Year and Date: 20080622-20080628
• [Presentation] Interfacial Structure Changes of Intercalation Electrodes at Electrochemical Reaction (2008)
  • Author(s): Ryoji Kanno, Masaaki Hirayama, Kazuyuki Sakamoto, Atsuo Yamada, Noriyuki Sonoyama, Kazuhisa Tamura, Jun'ichiro Mizuki
  • Organizer: 3rd Asian Conference on Electrochemical Power Sources (ACEPS-3)
  • Place of Presentation: Seoul, Korea
  • Year and Date: 2008-11-10
• [Presentation] Surface Structure Changes of Intercalation Cathodes during the Initial Electrochemical Process (2008)
  • Author(s): Masaaki Hirayama, Kazuyuki Sakamoto, Takeshi Tojigamori, Kouta Suzuki, Woosuk Cho, Atsuo Yamada, Kazuhisa Tamura, Junichiro Mizuki, Ryoji Kanno
  • Organizer: Pacific Rim Meeting on Electrochemical and Solid-state Science (PRiME2008)
  • Place of Presentation: Honolulu, USA.
  • Year and Date: 2008-10-14
• [Presentation] Mechanistic Studies of Intercalation Reactions using Epitaxial Thin-Film Electrodes (2007)
  • Author(s): Ryoji Kanno, Masaaki Hirayama, Kazuyuki Sakamoto, Daisuke Mori, Atsuo Yamada, Noriyuki Sonoyama, Kazuhisa Tamura, Jun'ichiro Mizuki
  • Organizer: 16th International Conference on Solid State Ionics (SSI-16)
  • Place of Presentation: Shanghai, China
  • Year and Date: 2007-07-04
• [Presentation] Structure and Ionic Conductivity of Thio-LISICON, The Li2S-P2O5 System (2007)
  • Author(s): Takeshi Kobayashi, Daisuke Shishihara, Atsuo Yamada, R. Kanno
  • Organizer: 16th International Conference on Solid State Ionics (SSI-16)
  • Place of Presentation: Shanghai, China
  • Year and Date: 2007-07-03
• [Book] 材料科学-基礎と応用 (2008)
  • Author(s): 戒能俊邦,菅野了次
  • Total Pages: 348
  • Publisher: 東京化学同人
• [Remarks] ホームページ
  • URL: http://www.echem.titech.ac.jp/~kanno/index.html