2007 Fiscal Year Final Research Report Summary
Ferroelectrics of charge ordering type and its non-linear response in triangular mixed valence iron oxide
Project/Area Number |
18340094
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Research Category |
Grant-in-Aid for Scientific Research (B)
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Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Condensed matter physics I
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Research Institution | Okayama University |
Principal Investigator |
IKEDA Naoshi Okayama University, Dept Phys., Professor (00222894)
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Co-Investigator(Kenkyū-buntansha) |
MORI Shigeo Osaka Prefecture University, Graduate School of Science, Professor (20251613)
YOSHII Kenji Japan Atomic Energy Agency, Quantum Bean Science Directorate, Researcher (90354985)
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Project Period (FY) |
2006 – 2007
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Keywords | RFe2O4 / Electronic Ferroelectricity / Triangular lattice / Chrage Ordering / Charge Frustration |
Research Abstract |
We made a research for triangular mixed valence material RFe2O4 which exhibits a polar charge ordering from the frustrated charge interaction. In this two years we had built up an air tight furnace having sample weight measurement system. From the detailed information of the sample weight change during the various heat treatment, we developed couple of method in obtaining fine sample of RFe2O4. During the course of the research we found the various electronic phases and properties for YbFe2O4, RFeCoO4, RFeCuO4 and RGaCuO4 (R.= Yb, Lu) Recently the ferroelectricity arise from the polar ordering of electrons have got much attention, however the usability for the actual application on the ferroelectric material have still been an open question. For example high electronic conductivity that possibly exist in the correlated electron system may prevent the usual application for the ferroelectrics like as insulator, charge condenser and so on. This report is one of the possibility search for s
… More
uch quests. For example in some sample treatment condition can possibly realize a high resistivity states of electronic ferroelectrics. It is also interesting that the sample having less oxygen vacancy shows high activation energy than non-stoichiometric material. It has been explained that the origin of the dielectric dispersion for Rfe_2O_4 is the boundary motion for polar domains. The higher Q value for higher stoichiometric sample indicates that the less oxygen vacant sample has larger charge ordering coherence length. Which realizes lamer scale of the collective electron motion. We emphasize that such ferroelectricity, defined by the electron distribution, is crucially different from previously known ferroelectrics. The difference in the origin of ferroelectricity may enable the development of a new class of device application in the near future. For example an anomaly report exists in electron microscope observation, which revealed an extremely small ferroelectric domain having a coherent size of 10 nm scale. This is a consistent estimate from the X-ray diffraction experiments. The superlattice profile is wider than the fundamental Bragg spot. Using the Schemer's formula the coherence length was estimated as about 10 nm from the full width of the half maximum of the peak profile in the a-b plane. In this ferroelectric the Coulomb interactions between Fe^<3+> and Fe^<2+> dominate the total energy for the presence of the domain sizes, that is decoupled from the lattice distortion. This indicates a typical property of the ferroelectricity by ordered electrons, free of lattice distortion. Future study may reveal such an extremely small ferroelectric element in high density electric devices in such extremely small domains. The applicability of electronic ferroelectric material for conventional ferroelectrics is still an open question. We should continue to find out better method to realize high stoichiometric RFe_2O_4, or also we should find out more characteristic application that may suit for such material having electric polarization and good conductivity. Less
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Research Products
(138 results)
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[Journal Article] NaV205の逐次電何不均化による悪魔の花-悪魔の花を咲かせるIsingスピンの詳細と競合する相互作用の理解-2008
Author(s)
大和田謙二, 藤井保彦, 村岡次郎, 中尾裕則, 村上洋一, 野田幸男, 大隅寛幸, 池田直, 菖蒲敬久, 礒部正彦, 上田寛
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Journal Title
Description
「研究成果報告書概要(和文)」より
Peer Reviewed
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[Journal Article] X-ray magnetic circular dichroism photoemission studies of ferromagnetism in CaMnl-xRuxO3 thin films2008
Author(s)
K., Terai, K., Yoshii, Y., Takeda, S., I., Fujimori, Y., Saitoh, K., Ohwada, T., Inami, T., Okane, M., Arita, K., Shimada, H., Namatame, M., Taniguchi, K., Kobayashi, M., Kobayashi, A., Fujimori
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Journal Title
Phys., Rev B 77
Pages: 115128-6
Description
「研究成果報告書概要(欧文)」より
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[Journal Article] Structural relations between two ground states of NaV2O5 under high pressure : A synchrotron x-ray diffraction study2008
Author(s)
Kenji, Ohwada, Yasuhiko, Fujii, Jiro, Muraoka, Hironori, Nakao, Youichi, Murakami, Yukio, Noda, Hiroyuki, Ohsumi, Naoshi Ikeda, Takahisa Shobu, Masahiko Isobe, Yutaka, Ueda
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Journal Title
Jpn. J. Synch. Rad. Soc 21
Pages: 87-96
Description
「研究成果報告書概要(欧文)」より
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[Journal Article] Electronic structure and magnetism of CaMnl-xRux03 thin films2007
Author(s)
K. Terai, K, Yoshii, Y. Takeda, S. -i, Fujimori, Y. Saitoh. K. Ohwada, T, Inami, T. Okane, M. Arita, K. Shimada, H. Namatame. M. Taniguchi, K. Kobayashi, M, Kobayashi and A. Fujimori.
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Journal Title
J. Mag. Mag. Mater 310
Pages: 1070-1072
Description
「研究成果報告書概要(和文)」より
Peer Reviewed
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[Journal Article] Soft x-ray magnetic circular dichroism study of Cal-xSrxRu03 across the ferromagnetic quantum phase transition2007
Author(s)
J. Okamoto, T. Okane, Y. Saitoh, K. Terai, S. -I, Fujimori, Y. Muramatsu, K. Yoshii, K. Mamiya, T. Koide, A. Fujimori, Z. Fang, Y. Takeda, and M. Takano
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Journal Title
Phys. Rev. B 76
Pages: 184441-5
Description
「研究成果報告書概要(和文)」より
Peer Reviewed
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[Journal Article] Structural properties of a mixed valence compound Fe2BO42007
Author(s)
S., Shimomura, S., Nakamura, N., Ikeda, E., Kaneko, K., Kato, K., Kohn
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Journal Title
J. Mag. Mag. Mat 310
Pages: 793-795
Description
「研究成果報告書概要(欧文)」より
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[Journal Article] Magnetic and dielectric properties of Tb0.5Ca0.5Mn032007
Author(s)
Hiramitsu, Y., Yoshii, K., Yoneda, Y., Mizuki, Nakamura, A., Shimojo, Y., Ishii, Y., Morii, Y., Ikeda, N
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Journal Title
Jpn. J. Appl. Phys 46
Pages: 7171-7174
Description
「研究成果報告書概要(欧文)」より
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[Journal Article] Magnetic and Dielectric Properties of RFe2O4, RFeMO4, and RGaCuO4 (R=Yb and Lu, M=Co and Cu)2007
Author(s)
K., Yoshii, N., Ikeda, Y., Matsuo, Y., Horibe, S., Mori
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Journal Title
Phys Rev B 76
Pages: 24423-12
Description
「研究成果報告書概要(欧文)」より
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[Journal Article] Structural relations between two ground states of NaV2O5 under high pressure : A synchrotron x-ray diffraction study2007
Author(s)
Kenji, Ohwada, Yasuhiko, Fujii, Jiro, Muraoka, Hironori, Nakao, Youichi, Murakami, Yukio, Noda, Hiroyuki, Ohsumi, Naoshi Ikeda, Takahisa, Shobu, Masahiko, Isobe, Yutaka, Ueda
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Journal Title
Phys. Rev B 76
Pages: 94113-10
Description
「研究成果報告書概要(欧文)」より
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[Journal Article] Lattice modulation in YMn2O5 TbMn2O5 studied by SR x-ray J. Korean2007
Author(s)
Y., Noda, H., Kimura, Y., Kamada, Y., Ishikawa, S., kobayashi, Y., Wakabayashi, N., Ikeda, K., Kohn
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Journal Title
Phys. Soc 51
Pages: 821-831
Description
「研究成果報告書概要(欧文)」より
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[Journal Article] Structural Phase Transition in Two-Dimensional Crystallites of Organic Dye Molecules Formed on Aqueous Subphases2007
Author(s)
Noritaka, Kato, Ichiro, Hirosawa, Masugu, Sato, Naoshi, Ikeda, Ken-Ichi, Iimura, Yoshiaki, Uesu
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Journal Title
Ferroelectrics 346
Pages: 162-167
Description
「研究成果報告書概要(欧文)」より
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[Journal Article] Morii Neutron diffraction and X-ray absorption study of Ag5Pb2O62007
Author(s)
K., Yoshii, M., Mizumaki, K., Kato, T., Uruga, H., Abe, A., Nakamura, Y., Shimojo, Y., Ishii, Y
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Journal Title
J. Solid State Chem 181
Pages: 377-381
Description
「研究成果報告書概要(欧文)」より
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[Journal Article] Magnetic and dielectric behavior of Magnetic and Dielectric Behavior of the Ruthenium Double Perovskite2007
Author(s)
K., Yoshii, N., Ikeda, S., Mori, Y., Yoneda, M., Mizumaki, H., Tanida, Naomi Kawamura
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Journal Title
Oxides R2MRuO6 (R=La, Pr and Nd, M=Mg, Co, Ni and Zn Trans., Mater., Res., Soc., Jpn 32(1)
Pages: 51-54
Description
「研究成果報告書概要(欧文)」より
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[Journal Article] Electronic structure and magnetism of CaMnl-xRuxO3 thin films2007
Author(s)
K., Terai, K., Yoshii, Y., Takeda, S,-i., Fujimori, Y., Saitoh, K., Ohwada, T., Inami, T., Okane, M., Arita, K., Shimada, H., Namatame, M., Taniguchi, K., Kobayashi, M., Kobayashi, A., Fujimori
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Journal Title
J. Mag. Mag. Mater 310
Pages: 1070-1072
Description
「研究成果報告書概要(欧文)」より
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[Journal Article] Soft x-ray magnetic circular dichroism study of Cal-xSrxRuO3 across the ferromagnetic quantum phase transition2007
Author(s)
J., Okamoto, T., Okane, Y., Saitoh, K., Terai, S.,-I., Fujimori, Y., Muramatsu, K.,Yoshii, K., Mamiya, T., Koide, A., Fujimori, Z., Fang, Y., Takeda, M., Takano
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Journal Title
Phys. Rev B 76
Pages: 184441-5
Description
「研究成果報告書概要(欧文)」より
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[Journal Article] Lattice modulation in YMn2O5 TbMn2O5 studied by using synchrotron radiation x-rays2007
Author(s)
Y., Noda, H., Kimura, Y., Kamada, Y., Ishikawa, S., Kobayashi, Y., Wakabayashi, H., Sawa, N., Ikeda, K., Kohn
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Journal Title
Journal of the Korean Physical Society 51
Pages: 828-831
Description
「研究成果報告書概要(欧文)」より
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[Journal Article] Nanoscale ferromagnetism in phase-separated manganites2007
Author(s)
S., Mori, Y., Horibe, T., Asaka, Y., Matsui, C.,H., Chen, S.,W., Cheong
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Journal Title
J. Mag. Mag. Mater 310
Pages: 870-872
Description
「研究成果報告書概要(欧文)」より
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[Journal Article] Observation of magnetic domain structures in Lal-xSrxMnO32007
Author(s)
T., Asaka, S., Mori, Y., Horibe, K., Takenaka, K., Ishizuka, K., Kimoto Y., Matsui
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Journal Title
J. Mag. Mag. Mater 310
Pages: 782-784
Description
「研究成果報告書概要(欧文)」より
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[Journal Article] Coercivity nanostructure in magnetic spinet Mg(Mn,Fe)2O42007
Author(s)
C., L., Zhang, S., Yeo, Y., Horibe, Y., J., Choi, S., Guha, M., Croft, S.-W., Cheong, S., Mori
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Journal Title
Appl. Phys. Lett 90
Pages: 133123-3
Description
「研究成果報告書概要(欧文)」より
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[Journal Article] Doping Effect on Ferroelectric Microstructure in YMnI-xTixO32007
Author(s)
S., Mori, J., Tokunaga, Y., Horibe, T., Asada, Y., Koyama, T., Katsufuji
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Journal Title
Ferroelectrics 348
Pages: 170-176
Description
「研究成果報告書概要(欧文)」より
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[Journal Article] Conduction characteristics of charge ordering type ferroelectrics YFe2O42006
Author(s)
K., Imamura, Y., Horibe, T., Yoshimura, N., Fujimura, S., Mori, N., Ikeda
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Journal Title
Materials Research Society Symposium Proceedings 96
Pages: 210-216
Description
「研究成果報告書概要(欧文)」より
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[Journal Article] Relation between ferroelectric and antiferromagnetic order in RMn2O52006
Author(s)
Y., Noda, H., Kimura, Y., Kamada, T., Osawa, Y., Fukuda, Y., Ishikawa, S., Kobayashi, Y., Wakabayashi, H., Sawa, N., Ikeda K., Kohn
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Journal Title
Physica B 385-386
Pages: 119-122
Description
「研究成果報告書概要(欧文)」より
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[Journal Article] Solid state self-assembly of nanocheckerboards2006
Author(s)
S., Yeo, Y., Horibe, S., Mori, C., M., Tseng, C., H., Chen
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Journal Title
J. Appl. Phys 99
Pages: 233120-3
Description
「研究成果報告書概要(欧文)」より
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[Journal Article] Spontaneous formation of vanadium "molecules" in a geometrically frustrated compound : A1V204"2006
Author(s)
Y., Horibe, M., Shingu, K., Kurushima, H., Ishibashi, N., Ikeda, K., Kato, Y., Motome, N., Furukawa, S., Mod, T., Katsufuji
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Journal Title
Phys., Rev., Lett 96
Pages: 86406-4
Description
「研究成果報告書概要(欧文)」より
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[Journal Article] Resonant X-ray Scattering Study at Y K-edge in YI-xCaxTiO32006
Author(s)
Hironori, Nakao, Soukichi, Kodama, Kouhei, Kiyoto, Youichi, Murakami, Masami, Tsubota, Fumitoshi, Iga, Kazuyuki Uchihira, Toshiro Takabatake, Hiroyuki Ohsumi, Masaichiro Mizumaki, Naoshi, Ikeda
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Journal Title
J. Phys. Soc. Jpn 75
Pages: 94706-5
Description
「研究成果報告書概要(欧文)」より
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[Journal Article] Direct Determination of Low-Dimensional Structures : Synchrotron X-ray Scattering on One-Dimensional Charge-Ordered MMX-Chain Complexes2006
Author(s)
Yusuke, Wakabayashi, Atsushi, Kobayashi, Hiroshi, Sawa, Hiroyuki, Ohsumi, Naoshi, Ikeda, Hiroshi, Kitagawa
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Journal Title
J. Am. Chem. Soc 128
Pages: 6676-6682
Description
「研究成果報告書概要(欧文)」より
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[Presentation] Current dependence of the energy Gap for θ-(BEDT-TTF)2CsM(SCN)42008
Author(s)
I., Terasaki,B., Sawano, T., Suko,S., Tasaki, H., Mori, T., Mori, Y., Nogami, N., Ikeda, M., Watanabe., Y., Noda
Organizer
Annual meeting of Japan Physical Society
Place of Presentation
Hokkaido Univ
Year and Date
2008-09-22
Description
「研究成果報告書概要(欧文)」より
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[Presentation] Time resolved 2-Dimensional diffraction study ofθ-(BEDT-TTF)2CsZn(SCN)4 under current flow2008
Author(s)
M., Watanabe, K., Yamamoto, T., Ito, N., Hanasaki, N., Ikeda, Y., Nogami, H., Toyokawa, Y., Noda, T., Inada, T., Suko, I., Terasaki, K., Mori
Organizer
Annual meeting of Japan Physical Society
Place of Presentation
Hokkaido Univ
Year and Date
2008-09-21
Description
「研究成果報告書概要(欧文)」より
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[Presentation] Distortion analysis of topological crystal in TaSe32008
Author(s)
K., Yamamoto, T., Matsuura, S., Ta, T., Ito, S., Horita, N., Ikeda, Y.,Nogami
Organizer
Meeting of Japan Physical Society
Place of Presentation
Kagoshima Univ
Year and Date
2008-03-19
Description
「研究成果報告書概要(欧文)」より
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[Presentation] Structure Phase Transition in YFe2042008
Author(s)
S., Shinohara,Y., Matsuo, S., Mori, Y., Horibe, K., Yoshii, N., Ikeda
Organizer
Meeting of Japan Physical Society
Place of Presentation
Kagoshima Univ
Year and Date
2008-03-19
Description
「研究成果報告書概要(欧文)」より
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[Presentation] Ordering of LuFe204in magnetic field2008
Author(s)
K., Kakurai, M., Matsuda, K., Yoshii, N., Ikeda, T., Ishii, H., Kito, Y., Yamada
Organizer
Meeting of Japan Physical Society
Place of Presentation
Kagoshima Univ
Year and Date
2008-03-19
Description
「研究成果報告書概要(欧文)」より
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[Presentation] Giant Lattice distortion and nonlinear electronic conduction in θ-(BEDT-TTF)2CsZn(SCN)42008
Author(s)
M., Watanabe, K., Yamamoto, Y., Nakajima, T., Ito, M., Tanabe, N., Hanasaki, N., Ikeda, Y., Nogami, H., Toyokawa, Y., Noda, I., Terasaki, B., Sawano, T., Suko, H., Mori, K., Mori
Organizer
Meeting of Japan Physical Society
Place of Presentation
Kagoshima Univ
Year and Date
2008-03-19
Description
「研究成果報告書概要(欧文)」より
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[Presentation] Ferroelectric Properties of RFe204 by the Charge Ordering2007
Author(s)
Naoshi, Ikeda, Takamasa, Michiuchi, Yusuke, Yokota, Hironori, Hayakawa,Yoji, Matsuo, Shigeo, Mori, Kenji, Yoshii
Organizer
13th US-Japan Seminar on Dielectric and Piezoelectric Ceramics
Place of Presentation
Awaji Japan
Year and Date
2007-11-04
Description
「研究成果報告書概要(欧文)」より
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[Presentation] RFe204の電場応答12007
Author(s)
池田直, 横田祐輔, 道内尊正, 森茂生, 吉井賢資
Organizer
日本物理学会 第62回年次大会
Place of Presentation
北海道大学
Year and Date
2007-09-24
Description
「研究成果報告書概要(和文)」より
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[Presentation] 時間分割2次元ディテクタを用いたθ-(BEDT-TTF)2CsZn(SCN)4の電流下X線回折実験2007
Author(s)
渡邉真史, 山本健一郎.伊藤崇芳, 花咲徳亮, 池田直, 野上由夫, 豊川秀訓, 野田幸男, 稲田太一, 須子友博, 寺崎一郎.森初果, 森健彦
Organizer
日本物理学会 第62回年次大会
Place of Presentation
北海道大学
Year and Date
2007-09-21
Description
「研究成果報告書概要(和文)」より
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[Presentation] θ-(BEDT-TTF)2CsZn(SCN)4の非線形伝導と巨大格子変形2007
Author(s)
渡邉真史, 山本健一郎, 中島悠策, 伊藤崇芳, 田辺誠, 花咲徳亮, 池田直, 野上由夫, 豊川秀訓, 野田幸男, 寺崎一郎, 澤野文章, 須子友博, 森初果, 森健彦
Organizer
日本物理学会 春季大会
Place of Presentation
鹿児島大学
Year and Date
2007-03-19
Description
「研究成果報告書概要(和文)」より
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[Presentation] Magnetism and dielectrics in Ruthenium double perovskite2006
Author(s)
K., Yoshii, N., Ikeda, S., Mori Y., Yoneda, M., Mizumaki., H., Tanida and N., Kawamura
Organizer
17th Japan MRS Meeting
Place of Presentation
Nihon Univ
Year and Date
2006-12-10
Description
「研究成果報告書概要(欧文)」より
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[Presentation] Charge Ordering and its domain structure of YFe2O42006
Author(s)
S., Mori, S., Shinohara, Y., Matsuo, Y., Horibe, K., Yoshii, N., Ikeda
Organizer
17th Japan MRS Meeting
Place of Presentation
Nihon Univ
Year and Date
2006-12-10
Description
「研究成果報告書概要(欧文)」より
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[Presentation] TEM study of charge ordered structure in YFe2O4-δ2006
Author(s)
S., Mori, S., Shinohara, Y., Matsuo, Y., Horibe, K., Yoshii, N., Ikeda
Organizer
Kyoto Conference on Solid State Chemistry
Place of Presentation
Kyoto University
Year and Date
2006-11-05
Description
「研究成果報告書概要(欧文)」より
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[Presentation] Lattice distortion ofθ-(BEDT-TTF)2CsZn(SCN)4 in nonlinear electronic conduction state2006
Author(s)
M., Watanabe, T., Ito, K., Yamamoto, Y., Nakajima, N., Hanasaki, N., Ikeda, Y., Nogami, H., Ohsumi, H., Toyokawa, Y., Noda, I., Terasaki, B., Sawano, T., Suko, H., Mori, K., Mori
Organizer
Meeting of Japan Physical Society
Place of Presentation
Chiba Univ
Year and Date
2006-09-25
Description
「研究成果報告書概要(欧文)」より
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[Presentation] International Physics Olympic (IPhO) and BUTURI-CHARENGE (2006)2006
Author(s)
I., Harada, N., Ikeda, M., Sakuda, M., Mino, M., Ninomiya, M., Ariyama, T., Namiki, K., Kitahara
Organizer
Meeting of Japan Physical Society
Place of Presentation
Chiba Univ
Year and Date
2006-09-24
Description
「研究成果報告書概要(欧文)」より
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[Presentation] Crystal Structure analysis in ferroelectric phase Tb0.3Gd0.7Mn032006
Author(s)
T., Goto, T Arima, Y., Yamazaki, N., Ikeda, H., Ohsumi, Y., Tokura
Organizer
Meeting of Japan Physical Society
Place of Presentation
Chiba Univ
Year and Date
2006-09-23
Description
「研究成果報告書概要(欧文)」より
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[Presentation] Fujimori Electronic structure and magnetism of CaMnl-xRuxO3 thin films2006
Author(s)
K., Terai, K., Yoshii, Y., Takeda, S.,I., Fujimori, K., Oowada, T., Inami, T., Okane, M., Arita, K., Shimada, H., Namatame, M., Taniguchi, K .,Kobayashi, M., Kobayashi, A
Organizer
International Conference on Magnetism
Place of Presentation
Kyoto International Conference Hall
Year and Date
2006-08-25
Description
「研究成果報告書概要(欧文)」より
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[Presentation] Magnetic ordering process in the charge-frustrated ferroelectric system LuFe2O42006
Author(s)
K., Kakurai, N., Ikeda, S., Nagai, M., Matsuda, Y., Ishii, K., Ohwada, T., Inami, K., Yoshii, Y., Murakami, H., Kito, Y., Yamada
Organizer
International Conference on Magnetism
Place of Presentation
Kyoto International Conference Hall
Year and Date
2006-08-24
Description
「研究成果報告書概要(欧文)」より
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[Presentation] Doping Effect on Ferroelectric Microstructure in YMnl-xTixO32006
Author(s)
S., Mori, J., Tokunaga, Y., Horibe, T., Katsufuji, T., Asada, Y., Koyama
Organizer
The 8th Russia/CIS/Baltic/Japan Symposium on Ferroelectricity (RCBJSF-8)
Place of Presentation
Tsukuba Univ
Year and Date
2006-05-16
Description
「研究成果報告書概要(欧文)」より
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