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2009 Fiscal Year Final Research Report

Construction of solid-state photovoltaic devices with use of mesoporous semiconductors and polymer-carbon composites

Research Project

  • PDF
Project/Area Number 18350111
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic industrial materials
Research InstitutionToin University of Yokohama

Principal Investigator

MIYASAKA Tsutomu  Toin University of Yokohama, 大学院・工学研究科, 教授 (00350687)

Co-Investigator(Kenkyū-buntansha) IKEGAMI Masashi  桐蔭横浜大学, 大学院・工学研究科, 講師 (30375414)
SHIRAI Yasuo  東京工芸大学, 工学部, 教授 (50064275)
Project Period (FY) 2006 – 2009
Keywords太陽電池 / ナノ材料 / 電気化学 / 半導体物性 / エネルギー
Research Abstract

This study has aimed at constructing a novel solid-state photovoltaic device that comprises a junction of oxide semiconductor, ionic conductor, electro-conductive olymer, and carbon material in which one of the heterogeneous interfaces formed is loaded with a light-absorbing material that causes photo-excited electron transfer and light energy conversion with high efficiency. Two types of devices based on the above concept have been constructed ; one is composed of organic dye (light absorber), TiO_2 semiconductor, ionic liquid, and polyaniline/carbon composite and the other composed of organo lead halide type nano-crystal (light absorber), TiO_2 semiconductor, and ionic electrolyte. The former yielded an energy conversion efficiency with respect to the solar spectrum of 4.1% and the latter yielded 3.8%.

  • Research Products

    (26 results)

All 2010 2009 2008 2007 2006 2004 2002 Other

All Journal Article (8 results) (of which Peer Reviewed: 6 results) Presentation (8 results) Book (3 results) Remarks (1 results) Patent(Industrial Property Rights) (6 results)

  • [Journal Article] Organometal halide perovskites as visible light sensitizers for photovoltaic cells2009

    • Author(s)
      A. Kojima, K. Teshima, Y. Shirai, T. Miyasaka
    • Journal Title

      J, Am. Chem. Soc 131

      Pages: 6050-6051

    • Peer Reviewed
  • [Journal Article] Highly porous PProDOT-Et2 film as counter electrode for plastic dye-sensitized solar cells2009

    • Author(s)
      K.-M. Lee, C.-Y. Hsu, P.-Y. Chen, M. Ikegami, T. Miyasaka, K.-C. Ho
    • Journal Title

      Phys. Chem. Chem. Phys 18

      Pages: 3375-3379

    • Peer Reviewed
  • [Journal Article] Effect of thin TiO_2 buffer layer on the performance of plastic-based dye-sensitized solar cells using indoline dye2008

    • Author(s)
      K. Miyoshi, M. Numao, M. Ikegami, T. Miyasaka
    • Journal Title

      Electrochemistry 76

      Pages: 158-160

    • Peer Reviewed
  • [Journal Article] Chlorin-sensitized high-efficiency photovoltaic cells that mimic spectral response of photosynthesis2008

    • Author(s)
      M. Ikegami, M. Ozeki, Y. Kijitori, T. Miyasaka
    • Journal Title

      Electrochemistry 76

      Pages: 140-142

    • Peer Reviewed
  • [Journal Article] Conductive polymer-based mesoscopic counter-electrodes for plastic dye-sensitized solar cells2007

    • Author(s)
      T. Muto, M. Ikegami, K. Kobayashi, T. Miyasaka
    • Journal Title

      Chem. Lett 36

      Pages: 804-805

    • Peer Reviewed
  • [Journal Article] A platinum/titanium bimetallic layer deposited on polymer film as efficient counter electrodes for plastic dyesensitized solar cells2007

    • Author(s)
      M. Ikegami, K. Teshima, K. Miyoshi, T. Miyasaka, T.C. Wei, C.C. Wan, Y.Y. Wang
    • Journal Title

      Appl. Phys. Lett 90

      Pages: 153122-153124

    • Peer Reviewed
  • [Journal Article] Plastic and Solid-state Dye-sensitized Solar Cells Incorporating Single-wall Carbon Nanotubes2007

    • Author(s)
      N. Ikeda, T. Miyasaka
    • Journal Title

      Chem. Lett 36

      Pages: 466-467

  • [Journal Article] Light energy conversion and charge storage with soft carbonaceous materials that solidify mesoscopic electrochemical interfaces2007

    • Author(s)
      T. Miyasaka, N. Ikeda, T.N. Murakami, K. Teshima
    • Journal Title

      Chem. Lett 36

      Pages: 480-487

  • [Presentation] 塗布プロセスによる有機・無機ハイブリッド太陽電池の開発2010

    • Author(s)
      宮坂力, 池上和志
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学
    • Year and Date
      20100326-20100329
  • [Presentation] Organo-metal quantum dot sensitizers for mesoscopic TiO_2 solar cell2009

    • Author(s)
      T. Miyasaka
    • Organizer
      MRS Fall Meeting 2009
    • Place of Presentation
      Boston, USA
    • Year and Date
      20091130-20091204
  • [Presentation] Novel photoelectrochemical cell with mesoscopic electrodes sensitized by lead-halide compounds (11)2008

    • Author(s)
      A. Kojima, K. Teshima, Y. Shirai, T. Miyasaka
    • Organizer
      214th ECS Meeting
    • Place of Presentation
      Honolulu, Hawaii
    • Year and Date
      2008-10-12
  • [Presentation] ハロゲン化鉛系化合物を可視光増感剤に用いた新規光電気化学セル(10)2008

    • Author(s)
      小島陽広, 手島健次郎, 白井靖男, 宮坂力
    • Organizer
      光化学討論会
    • Place of Presentation
      大阪府立大学
    • Year and Date
      2008-09-11
  • [Presentation] ハロゲン化鉛系化合物を可視光増感剤に用いた新規光電気化学セル(9)2008

    • Author(s)
      小島陽広, 手島健次郎, 白井靖男, 宮坂力
    • Organizer
      電気化学会第75回大会
    • Place of Presentation
      山梨大学
    • Year and Date
      2008-03-29
  • [Presentation] カーボン材料を用いる固体型フレキシブル色素増感太陽電池2008

    • Author(s)
      宮坂力, 池田信之, 池上和志
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学
    • Year and Date
      2008-03-26
  • [Presentation] Novel photovoltaic cell with mesoscopic electrodes sensitized by leadhalide compounds (8)2007

    • Author(s)
      A. Kojima, K. Teshima, Y. Shirai, T. Miyasaka
    • Organizer
      17th International Photovoltaic Science and Engineering Conference (PVSEC-17)
    • Place of Presentation
      福岡
    • Year and Date
      2007-12-03
  • [Presentation] Organo lead-halide quantum dot as efficient sensitizers for TiO2-based solar cells

    • Author(s)
      T. Miyasaka
    • Organizer
      Japan & China Workshop on Sensitized Solar Cells
    • Place of Presentation
      Tokyo (invited)
  • [Book] 新コンセプト太陽電池と製造プロセス2009

    • Author(s)
      宮坂力監修
    • Publisher
      シーエムシー出版
  • [Book] 太陽エネルギー有効利用最前線2008

    • Author(s)
      宮坂力,手島健次郎, 瓦家正英, 池上和志, 池田信之 共著
    • Total Pages
      271-283
    • Publisher
      エヌティーエス出版
  • [Book] 有機薄膜形成とデバイス応用展開(大森裕監修)2007

    • Author(s)
      池上和志,宮坂力
    • Total Pages
      111-118
    • Publisher
      シーエムシー出版
  • [Remarks] ホームページ:宮坂研究室

    • URL

      http://www.cc.toin.ac.jp/sc/miyasaka/

  • [Patent(Industrial Property Rights)] 色素増感型光電変換素子2008

    • Inventor(s)
      宮坂力、池上和志
    • Industrial Property Rights Holder
      ペクセル・テクノロジーズ(株)、学校法人桐蔭学園
    • Industrial Property Number
      特願2008-120570
    • Filing Date
      2008-05-02
  • [Patent(Industrial Property Rights)] Dye-sensitization photoelectric device2008

    • Inventor(s)
      宮坂力
    • Industrial Property Rights Holder
      帝人デュポン株式会社
    • Industrial Property Number
      出願番号US-12/035,613
    • Filing Date
      2008-05-05
  • [Patent(Industrial Property Rights)] 色素増感型光電変換素子2007

    • Inventor(s)
      宮坂力
    • Industrial Property Rights Holder
      帝人デュポンフィルム(株)、学校法人桐蔭学園
    • Industrial Property Number
      特願2008-048946
    • Filing Date
      2007-08-22
  • [Patent(Industrial Property Rights)] 色素増感型光電変換素子2006

    • Inventor(s)
      宮坂力、池上和志
    • Industrial Property Rights Holder
      学校法人桐蔭学園, 他
    • Industrial Property Number
      特願2006-45356
    • Filing Date
      2006-02-22
  • [Patent(Industrial Property Rights)] 導電性被覆形成組成物、それを用いた電極及びその電極を用いた光電極2004

    • Inventor(s)
      宮坂力
    • Industrial Property Rights Holder
      学校法人桐蔭学園, 他
    • Industrial Property Number
      特願2005-209458
    • Filing Date
      2004-01-21
  • [Patent(Industrial Property Rights)] 光発電体シート、それを用いた太陽光発電用ユニット及び発電装置2002

    • Inventor(s)
      宮坂力
    • Industrial Property Rights Holder
      学校法人桐蔭学園
    • Industrial Property Number
      特許第4233260号
    • Filing Date
      2002-03-06

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Published: 2011-06-18   Modified: 2016-04-21  

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