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2008 Fiscal Year Final Research Report

Development of Kitosan Resinds Modified with Amino Acids and Persuing the Collection and Separation Abilities

Research Project

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Project/Area Number 18550138
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Environmental chemistry
Research InstitutionKanazawa University

Principal Investigator

UEDA Kazumasa  Kanazawa University, 物質化学系, 教授 (40019758)

Co-Investigator(Renkei-kenkyūsha) HASEGAWA Hiroshi  金沢大学, 物質化学系, 准教授 (90253335)
MAKI Teruya  金沢大学, 物質化学系, 准教授 (70345601)
Project Period (FY) 2006 – 2008
Keywords両性イオン交換樹脂 / 捕集分離 / 貴金属 / 生分解性
Research Abstract

架橋キトサン樹脂を母材に、各種アミノ酸を修飾したイオン交換樹脂を開発し、樹脂性能と金属イオンの捕集分離機能を明らかにした。アミノ酸の導入により、両性イオン交換能は強化され、酸性域では貴金属イオン、アルカリ性域で遷移金属に高吸着能を見出した。樹脂のイオン会合力と錯形成能が駆動力となるが、白金族の相互分離や遷移金属の定量的分離を達成出来た。吸着過程は、Langmuir 型で、化学反応律速の発熱反応と解明した。

Research Products

(56 results)

All 2009 2008 2007 2006 2000

All Journal Article (29 results) (of which Peer Reviewed: 29 results) Presentation (27 results)

  • [Journal Article] Effect of eutrophication on the distribution of arsenic species in eutrophic and mesotrophic lakes2009

    • Author(s)
      H. Hasegawa, M. Azizur Rahman, T. Matsuda, T. Kitahara, T. Maki, K. Ueda
    • Journal Title

      Sci. Total Environ 407

      Pages: 1418-1425

    • Peer Reviewed
  • [Journal Article] Arsenic uptake by aquatic macrophyte Spirodela polyrhiza L. : Interactions with phosphate and iron2008

    • Author(s)
      M. Azizur Rahman, H. Hasegawa, K. Ueda, T. Maki, M. Mahfuzur Rahman
    • Journal Title

      J. Hazard. Mater 160

      Pages: 356-361

    • Peer Reviewed
  • [Journal Article] Phylogenetic diversity and vertical distribution of a halobacterial community in the atmosphere of an Asian dust (KOSA) source region, Dunhuang City2008

    • Author(s)
      T. Maki, S. Susuki, F. Kobayashi, M. Kakikawa, M. Yamada, T. Higashi, B. Chen, G. Shi, C. Hong, Y. Tobo, H. Hasegawa, K. Ueda, Y. Iwasaka
    • Journal Title

      Air Qual. Atmos. Health 1

      Pages: 81-89

    • Peer Reviewed
  • [Journal Article] Determination of dissolved metals in the presence of organic ligands using molecular recognition technology (MRT) products2008

    • Author(s)
      S. Kinoshita, H. Hasegawa, T. Iwasa, K. Saitou, C. Okumura, T. Maki, K. Ueda
    • Journal Title

      J. Ecotechnol. Res 14.

      Pages: 1-4

    • Peer Reviewed
  • [Journal Article] Influence of dissolved organic matter on iron speciation and scavenging in the Tedori River Estuary2008

    • Author(s)
      H. Hasegawa, M. Shimomura, H. Tada, K. Kitahara, T. Maki, K. Ueda
    • Journal Title

      J. Ecotechnol. Res. 14

      Pages: 25-28

    • Peer Reviewed
  • [Journal Article] The effects of phosphorous on the accumulation of arsenic in water fern (Azolla pinnata L.)2008

    • Author(s)
      M. Azizur Rahman, H. Hasegawa, K. Kitahara, T. Maki, K. Ueda, M. Mahfuzur Rahman
    • Journal Title

      J. Ecotechnol. Res. 14

      Pages: 21-24

    • Peer Reviewed
  • [Journal Article] Bacterial community in the lake water spiked with dimethylarsenic acid estimated by PCR-DGGE analysis2008

    • Author(s)
      T. Shimada, T. Maki, W. Hirota, T. Kakimoto, H. Hasegawa, K. Ueda
    • Journal Title

      J. Ecotechnol. Res 14

      Pages: 17-20

    • Peer Reviewed
  • [Journal Article] Effect of iron stress on gene expression in harmful microalga Prymnesium parvum2008

    • Author(s)
      T. Maki, T. Suzuki, K. Kido, A. Nakahara, T. Higashi, H. Hasegawa, K. Ueda, K. Sijoh
    • Journal Title

      J. Ecotechnol. Res 14

      Pages: 13-16

    • Peer Reviewed
  • [Journal Article] Adsorption of gold(III), platinum(IV) and palladium(II) onto glycine modified crosslinked chitosan resin2008

    • Author(s)
      A. Ramesh, H. Hasegawa, W. Sugimoto, T. Maki, K. Ueda
    • Journal Title

      Bioresource Technology 99

      Pages: 3801-3809

    • Peer Reviewed
  • [Journal Article] Influence of EDTA and chemical species on arsenic accumulation in Spirodela polyrhiza L. (duckweed)2008

    • Author(s)
      M. Azizur Rahman, H. Hasegawa, K. Ueda, T. Maki, M. Mahfuzur Rahman
    • Journal Title

      Ecotoxicol Environ. Safety 70

      Pages: 311-318

    • Peer Reviewed
  • [Journal Article] Arsenic accumulation in rice (Oriza sativa L.); Human exposure through food chain2008

    • Author(s)
      M. Azizur Rahman, H. Hasegawa, M. Mahfuzur Rahman, M. A. Majid Miah, A. Tasmin
    • Journal Title

      Ecotoxicol Environ. Safety 69

      Pages: 317-324

    • Peer Reviewed
  • [Journal Article] Straighthead disease of rice (Oriza sativa L.) induced by arsenic toxicuty2008

    • Author(s)
      M. Azizur Rahman, H. Hasegawa, M. Mahfuzur Rahman, M. A. Majid Miah, A. Tasmin
    • Journal Title

      Environmental and Experimental Botany 62

      Pages: 54-59

    • Peer Reviewed
  • [Journal Article] Accumulation of arsenic in tissues of rice plant (Oryza sativa L.) and its distribution in fractions of rice grain2007

    • Author(s)
      M. Azizur Rahman, H. Hasegawa, M. Mahfuzur Rahman, M. Nazrul Islam, M. A. Majid Miah
    • Journal Title

      Chemosphere 69

      Pages: 942-948

    • Peer Reviewed
  • [Journal Article] C. Okumura, C., M. Mahfuzur Rahman, Arsenic accumulation in duckweed (Spirodela polyrhiza L.) : A good option for phytoremediation2007

    • Author(s)
      M. Azizur Rahman, H. Hasegawa, K. Ueda T. Maki, C. Okumura, C., M. Mahfuzur Rahman
    • Journal Title

      Chemosphere 69

      Pages: 493-499

    • Peer Reviewed
  • [Journal Article] 海洋植物プランクトンを巡る鉄の化学形態別分析2007

    • Author(s)
      長谷川浩
    • Journal Title

      ぶんせき

      Pages: 468-69

    • Peer Reviewed
  • [Journal Article] Microcolumn preconcentration of trace metal ions in environmental samples using nanometer sized alumina immobilized with chromotropic acid and determination by ICP-AES2007

    • Author(s)
      A. Ramesh, H. Hasegawa, T. Maki, K. Ueda
    • Journal Title

      J. Ecotechnol. Res 13

      Pages: 85-90

    • Peer Reviewed
  • [Journal Article] Adsorption of inorganic and organic arsenic from aqueous solutions by polymeric Al/Fe modified montmorillonite2007

    • Author(s)
      A. Ramesh, H. Hasegawa, T. Maki, K. Ueda
    • Journal Title

      Separation and Purification Technology 56

      Pages: 90-100

    • Peer Reviewed
  • [Journal Article] Adsorption of platinum (IV), palladium (II) and gold (III) from aqueous solutions onto L-lysine modified crosslinked chitosan resin2007

    • Author(s)
      K. Fujiwara, A. Ramesh , T. Maki, H. Hasegawa, K. Ueda
    • Journal Title

      J. Hazard. Mater 146

      Pages: 43-50

    • Peer Reviewed
  • [Journal Article] Nanometer-sized alumina coated with chromotropic acid as solid phase metal extractant from environmental samples and determination by inductively coupled plasma atomic emission spectrometry2007

    • Author(s)
      A. Ramesh, B. A. Devi, H. Hasegawa, T. Maki, K. Ueda
    • Journal Title

      Microchemical Journal 86

      Pages: 124-130

    • Peer Reviewed
  • [Journal Article] Arsenic Accumulation in Rice (Oryza sativa L.) Varieties of Bangladesh : A Glass House Study2007

    • Author(s)
      M. Azizur Rahman, H. Hasegawa, M. Mahfuzur Rahman, M. Nazrul Islam, M. A. M. Miah, A. Tasmin
    • Journal Title

      Water Air Soil Pollut 185

      Pages: 53-61

    • Peer Reviewed
  • [Journal Article] Effect of arsenic on photosynthesis,growth and yield of five widely cultivated rice (Oryza sativa L.) varieties in Bangladesh2007

    • Author(s)
      M. Azizur Rahman, H. Hasegawa, M. Mahfuzur Rahman, M. Nazrul Islam, M. A. Majid Miah, A. Tasmen
    • Journal Title

      Chemosphere 67

      Pages: 1072-1079

    • Peer Reviewed
  • [Journal Article] Determination of iron in phytoplankton cultures by radiochemical analysis with ^<55>Fe2007

    • Author(s)
      C. Okumura, H. Hasegawa, T. Maki, K. Ueda
    • Journal Title

      J. Ecotechnol. Res. 13

      Pages: 11-14

    • Peer Reviewed
  • [Journal Article] Effects of chemical species and microbial activity on arsenic accumulation by the hyperaccumulation fern2007

    • Author(s)
      T. Maki, R. Tsutsumibata, D. Tsunekawa, T. Kakimoto, H. Hasegawa, K. Ueda
    • Journal Title

      J. Ecotechnol. Res. 13

      Pages: 15-19

    • Peer Reviewed
  • [Journal Article] I. Imai Effects of the substances secreted from Closterium aciculare (Charophyceae, Chlorophyta) on the growth of freshwater phytoplankton under iron-deficient conditions2006

    • Author(s)
      K. Naito, M. Suzuki, S. Mito, H. Hasegawa, M. Matsui
    • Journal Title

      Plankton Benthos Res. 1

      Pages: 191-199

    • Peer Reviewed
  • [Journal Article] Influence of cooking method on arsenic retention in cooked rice related to dietary exposure2006

    • Author(s)
      M. Azizur Rahman, H. Hasegawa, M. Arifur Rahman, M. Mahfuzur Rahman and M.A. Majid Miah
    • Journal Title

      Sci. Total Environ 370

      Pages: 51-60

    • Peer Reviewed
  • [Journal Article] Isolation of monomethylarsonic acid (MMAA)-mineralizing bacteria from arsenic contaminated soils of Island Ohkunoshima2006

    • Author(s)
      Maki, T, Takeda, N, Hasegawa, H, Ueda, K
    • Journal Title

      Appl. Organometal. Chem. 20

      Pages: 538-544

    • Peer Reviewed
  • [Journal Article] Bacterial degradation of antibiotic residues in a marine fish farm sediment of Uranouchi Bay and phylogenetic analysis of the antibiotic-degrading bacteria using 16S rDNA sequences2006

    • Author(s)
      Maki, T, Hasegawa, H, Kitami, H, Fumoto, K, Munekage, Y, Ueda, K.
    • Journal Title

      Fisheries Sci. 72

      Pages: 811-820

    • Peer Reviewed
  • [Journal Article] Seasonal dynamics of dimethylarsenic acid degrading bacteria dominated in Lake Kibagata2006

    • Author(s)
      Maki, T, Watarai, H, Kakimoto, T, Takahashi, M, Hasegawa, H, Ueda, K
    • Journal Title

      Geomicrobiol. J. 23

      Pages: 311-318

    • Peer Reviewed
  • [Journal Article] Influence of phosphate and iron ions in selective uptake of arsenic species by water fern (Salvinia natans L.)2000

    • Author(s)
      M. Azizur Rahman, H. Hasegawa, K. Ueda, T. Maki, M. Mahfuzur Rahman
    • Journal Title

      Chemical Engineering Journal 145

      Pages: 179-184

    • Peer Reviewed
  • [Presentation] 原子吸光法を用いた有機ヒ素化合物定量のための前処理法2008

    • Author(s)
      北原清志、長谷川浩、前美沙子、田多宏海、牧輝弥、上田一正
    • Organizer
      日本分析化学会第57年会
    • Place of Presentation
      福岡大
    • Year and Date
      2008-09-10
  • [Presentation] 鉄制限下で発現する植物プランクトン外膜タンパク質の解析2008

    • Author(s)
      浅川壮太郎、長谷川浩、中原歩夢、岩佐朋紀、牧輝弥、上田一正
    • Organizer
      日本分析化学会第57年会
    • Place of Presentation
      福岡大
    • Year and Date
      2008-09-10
  • [Presentation] イネのヒ素吸収に及ぼすキレート剤の影響2008

    • Author(s)
      長谷川浩、モハマド アジズ ラハマン、齋藤圭太、岩佐朋紀、門端孝太、牧輝弥、上田一正
    • Organizer
      日本分析化学会第57年会
    • Place of Presentation
      福岡大
    • Year and Date
      2008-09-10
  • [Presentation] 湖沼における有機ヒ素の生成と富栄養化の関係2008

    • Author(s)
      北原清志、長谷川浩、松田知恵、田多宏海、海木亜玲、牧輝弥、上田一正
    • Organizer
      第69回分析化学討論会
    • Place of Presentation
      名古屋大
    • Year and Date
      2008-05-15
  • [Presentation] 生分解性キレート剤による植物の鉄欠乏解消メカニズムの解明2008

    • Author(s)
      齋藤圭太、長谷川浩、山田陽子、木下早苗、奥村真子、牧輝弥、上田一正
    • Organizer
      第69回分析化学討論会
    • Place of Presentation
      名古屋大
    • Year and Date
      2008-05-15
  • [Presentation] 水圏中のバイオ粒子が関与する有機ヒ素無機化プロセスの分析化学的解析2008

    • Author(s)
      廣田和香奈、牧輝弥、島田孝志、長谷川浩、上田一正
    • Organizer
      第69回分析化学討論会
    • Place of Presentation
      名古屋大
    • Year and Date
      2008-05-15
  • [Presentation] 生長制限下の植物プランクトンにおける鉄運搬体の形成2008

    • Author(s)
      浅川壮太郎、長谷川浩、藤田万巳、木下早苗、牧輝弥、上田一正
    • Organizer
      第69回分析化学討論会
    • Place of Presentation
      名古屋大
    • Year and Date
      2008-05-15
  • [Presentation] 宝石サンゴの炭酸塩骨格中における微量元素の分布と利用2008

    • Author(s)
      長谷川浩、海木亜玲、北原清志、田多宏海、牧輝弥、上田一正、鈴木淳、岩崎望
    • Organizer
      第69回分析化学討論会
    • Place of Presentation
      名古屋大
    • Year and Date
      2008-05-15
  • [Presentation] ファイトレメディエーションにおけるヒ素浄化効果の繰り返し抽出定量法の検討2008

    • Author(s)
      恒川大玄、牧輝弥、岡田晃範、長谷川浩、上田一正
    • Organizer
      第69回分析化学討論会
    • Place of Presentation
      名古屋大
    • Year and Date
      2008-05-15
  • [Presentation] Ecophysiological Analysis of Halophilic Bacteria in Bioaerosol2007

    • Author(s)
      T. Maki, Susuki S, Kobayashi F, Kakikawa M, Yamada M, Higashi T, Hong C, Toubou Y, Hasegawa H, Ueda K, Iwasaka Y
    • Organizer
      Biomicroworld2007
    • Place of Presentation
      Spain
    • Year and Date
      2007-12-01
  • [Presentation] Seasonal dynamics of bacterial population degrading dimethylarsenic acid in Lake Kahokugata2007

    • Author(s)
      W. Hirota, Maki T, Kakimoto T, Shimada T, Hasegawa H, Ueda K
    • Organizer
      Biomicroworld2007
    • Place of Presentation
      Spain
    • Year and Date
      2007-12-01
  • [Presentation] 有害ハプト藻の鉄ストレスに関わる遺伝子群の探索2007

    • Author(s)
      鈴木峰、牧輝弥、城戸耕介、中原歩夢、長谷川浩、上田一正
    • Organizer
      日本分析化学会第56年会
    • Place of Presentation
      徳島大
    • Year and Date
      2007-09-20
  • [Presentation] 分子認識ゲルを用いた有機配位子存在下における鉄の分離分析2007

    • Author(s)
      木下早苗、長谷川浩、岩佐朋紀、齋藤圭太、奥村真子、牧輝弥、上田一正
    • Organizer
      日本分析化学会第56年会
    • Place of Presentation
      徳島大
    • Year and Date
      2007-09-19
  • [Presentation] 湖沼における有機ヒ素のスペシエーションと起源に関する研究2007

    • Author(s)
      長谷川浩、北原清志、松田知恵、田多宏海、牧輝弥、上田一正
    • Organizer
      日本分析化学会第56年会
    • Place of Presentation
      徳島大
    • Year and Date
      2007-09-19
  • [Presentation] 植物成長において生分解性キレート剤が鉄の生物学的有効性に及ぼす影響2007

    • Author(s)
      齋藤圭太、長谷川浩、山田陽子、木下早苗、奥村真子、牧輝弥、上田一正
    • Organizer
      日本分析化学会第56年会
    • Place of Presentation
      徳島大
    • Year and Date
      2007-09-19
  • [Presentation] Arsenic adsorption on iron plaque and uptake in duckweed (Spirodela polyrhiza L.) affected by chemical species2007

    • Author(s)
      M. Azizur Rahman, H. Hasegawa, K. Ueda, T. Maki, M. Mahfuzur Rahman
    • Organizer
      in Proceeding of International Conference on Environmental Science and Technology (IC-EST)
    • Place of Presentation
      Texas, Houston, USA
    • Year and Date
      2007-08-08
  • [Presentation] アルカリ土壌で生育する植物の生長阻害に対するキレート剤の効果2007

    • Author(s)
      長谷川浩、齋藤圭太、奥村真子、牧輝弥、上田一正
    • Organizer
      第68回分析化学討論会
    • Place of Presentation
      宇都宮大
    • Year and Date
      2007-05-20
  • [Presentation] Microcolumn preconcentration of trace metal ions in environmental samples using nanometer sized alumina immobilized with chromotropic acid and determination by ICP-AES2007

    • Author(s)
      A. Ramesh, H. Hasegawa, T. Maki, K. Ueda
    • Organizer
      in Proceedings of 58th Pittsburgh Conference on Analytical Chemistry and Applied Spectroscopy
    • Place of Presentation
      Chicago
    • Year and Date
      2007-02-27
  • [Presentation] Determination of iron in phytoplankton cultures by radiochemical analysis with ^<55>Fe2006

    • Author(s)
      H. Hasegawa, C. Okumura, T. Maki, K. Ueda
    • Organizer
      Journal of Ecotechnology Research (Abstracts of 13th Asian Symposium on Ecotechnology (ASET13))
    • Place of Presentation
      Toyama
    • Year and Date
      2006-12-03
  • [Presentation] Determination of Fe(II) and Fe(III) in the presence of EDTA in solutions using molecular recognition technology (MRT) products2006

    • Author(s)
      S. Kinoshita, H. Hasegawa, C. Okumura, T. Maki, K. Ueda
    • Organizer
      Journal of Ecotechnology Research (Abstracts of 13th Asian Symposium on Ecotechnology (ASET13))
    • Place of Presentation
      Toyama
    • Year and Date
      2006-12-03
  • [Presentation] Microcolumn preconcentration of trace metal ions in environmental samples using nanometer sized alumina immobilized with chromotropic acid and determination by ICP-AES2006

    • Author(s)
      A. Ramesh, H. Hasegawa, T. Maki, K. Ueda
    • Organizer
      Journal of Ecotechnology Research (Abstracts of 13th Asian Symposium on Ecotechnology (ASET13))
    • Place of Presentation
      Toyama
    • Year and Date
      2006-12-03
  • [Presentation] Effects of chemical species and microbial activity on arsenic accumulation by the hyperaccumulation fern2006

    • Author(s)
      T. Maki, R. Tsutsumibata, D. Tsunekawa, T. Kakimoto, H. Hasegawa, K. Ueda
    • Organizer
      Journal of Ecotechnology Research (Abstracts of 13th Asian Symposium on Ecotechnology (ASET13))
    • Place of Presentation
      Toyama
    • Year and Date
      2006-12-03
  • [Presentation] Arsenic uptake potential of duckweed (Spirodela polyrhiza L.) in Proceedings of 1st International Symposium on Health Hazards of Arsenic Contamination of Groundwater and its Countermeasures2006

    • Author(s)
      Rahman, M. A, Hasegawa, H, Ueda, K, Maki, T, Okumura, C, Rahman, M. M.
    • Place of Presentation
      Miyazaki
    • Year and Date
      2006-11-04
  • [Presentation] バクテリア由来マンガン酸化物の沈殿挙動2006

    • Author(s)
      下村碧、長谷川浩、松田知恵、牧輝弥、上田一正
    • Organizer
      日本分析化学会第55年会
    • Place of Presentation
      大阪大
    • Year and Date
      2006-09-20
  • [Presentation] 鉄制限下の植物プランクトンにおける膜タンパク質の分離分析2006

    • Author(s)
      加藤清香、長谷川浩、森亮祐、福本愛、牧輝弥、上田一正
    • Organizer
      日本分析化学会第55年会
    • Place of Presentation
      大阪大
    • Year and Date
      2006-09-20
  • [Presentation] キレート剤によって鉄欠乏状態にある微細藻の鉄応答型分子機能の解明2006

    • Author(s)
      牧輝弥、鈴木峰、城戸耕介、奥村真子、長谷川浩、上田一正
    • Organizer
      日本分析化学会第55年会
    • Place of Presentation
      大阪大
    • Year and Date
      2006-09-20
  • [Presentation] 溶存ヒ素のスペシエーションに及ぼす富栄養化の影響2006

    • Author(s)
      松田知恵、長谷川浩、那須友香里、下村碧、牧輝弥、上田一正
    • Organizer
      日本分析化学会第55年会
    • Place of Presentation
      大阪大
    • Year and Date
      2006-09-20

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Published: 2010-06-09   Modified: 2016-04-21  

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