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2019 Fiscal Year Annual Research Report

Exploration of stable and efficient Tin Perovskite Solar Cells for next generation PV

Research Project

Project/Area Number 18H02079
Research InstitutionNational Institute for Materials Science

Principal Investigator

イスラム アシュラフル  国立研究開発法人物質・材料研究機構, エネルギー・環境材料研究拠点, 主席研究員 (70531177)

Project Period (FY) 2018-04-01 – 2021-03-31
KeywordsSensitized Solar Cell / Perovskite Solar Cell / Pb free / Sn perovskite
Outline of Annual Research Achievements

During last year, I have prepared the dimensionally tuned 2D/3D ultra-stable perovskite absorbers films by tuning cation and anion composition. One-step precursor deposition and sequential deposition methods was used to form high quality 2D PS films. Finally, prepared and characterized the 2D/3D dimensional PS films along with degradation analysis and environmental stability of the films.
The research results are published in peer reviewed scientific journals.

Current Status of Research Progress
Current Status of Research Progress

3: Progress in research has been slightly delayed.

Reason

In the beginning of the research, I have found some difficulties to synthesis the fluorous ammonium salts with Fluorous mono- and bisammonium cations A’ which delayed my research schedule from the original time frame. Due to this reason, I could not complete some research Tasks in Phase I.

Strategy for Future Research Activity

Phase III: Fabrication of graded heterojunction structure (GHJ) in planar PSCs using 2D/3D dimensional PS films:
Task 1. Preparation and performance evaluation of prototype PSCs: Selected 2D/3D dimensionally tuned PS prepared will be integrated as absorbers in a graded heterojunction structure (GHJ) in planar PSCs and using heavily doped inorganic charge extraction layers of NiMgLiO and Ti(Nb)Ox.
Task 2. Performance evaluation of prototype PSCs: Photovoltaic performances of the PSCs will be evaluated by J-V) characteristics, external quantum efficiency (EQE) and the long-term stability of devices will be assessed by comparison of their J-V curves as a function of storage time in air.

  • Research Products

    (7 results)

All 2021 2020 2019

All Journal Article (7 results) (of which Int'l Joint Research: 7 results,  Peer Reviewed: 7 results)

  • [Journal Article] Chemical passivation of the under coordinated Pb2+ defects in inverted planar perovskite solar cells via β-diketone Lewis base additives2021

    • Author(s)
      Abdel-Shakour Muhammad、Chowdhury Towhid H.、Matsuishi Kiyoto、Moritomo Yutaka、Islam Ashraful
    • Journal Title

      Photochemical & Photobiological Sciences

      Volume: 20 Pages: 357~367

    • DOI

      10.1007/s43630-021-00023-z

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] A facile approach to construct organic D-π-A dyes via sequential condensation reactions for dye-sensitized solar cells2021

    • Author(s)
      Chen Hongjin、Islam Ashraful、Chowdhury Towhid H.、Bedja Idriss、Ghaithan Hamid M.、Zhang Rui、Liu Jian
    • Journal Title

      Sustainable Energy & Fuels

      Volume: 5 Pages: 289~296

    • DOI

      10.1039/d0se01519a

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Facile and low-cost synthesis of a novel dopant-free hole transporting material that rivals Spiro-OMeTAD for high efficiency perovskite solar cells2021

    • Author(s)
      Abdellah Islam M.、Chowdhury Towhid H.、Lee Jae-Joon、Islam Ashraful、Nazeeruddin Mohamad K.、Greatzel Michael、El-Shafei Ahmed
    • Journal Title

      Sustainable Energy & Fuels

      Volume: 5 Pages: 199~211

    • DOI

      10.1039/D0SE01323D

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Application of small molecules based on a dithienogermole core in bulk heterojunction organic solar cells and perovskite solar cells2020

    • Author(s)
      Yadagiri B.、Narayanaswamy K.、Chowdhury Towhid H.、Islam Ashraful、Gupta Vinay、Singh Surya Prakash
    • Journal Title

      Materials Chemistry Frontiers

      Volume: 4 Pages: 2168~2175

    • DOI

      10.1039/d0qm00267d

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Novel dopant-free hole-transporting materials for efficient perovskite solar cells2020

    • Author(s)
      Abdellah Islam M.、Chowdhury Towhid H.、Lee Jae-Joon、Islam Ashraful、El-Shafei Ahmed
    • Journal Title

      Solar Energy

      Volume: 206 Pages: 279~286

    • DOI

      10.1016/j.solener.2020.06.016

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Fabrication of lead-free CsBi3I10 based compact perovskite thin films by employing solvent engineering and anti-solvent treatment techniques: an efficient photo-conversion efficiency up to 740 nm2020

    • Author(s)
      Mariyappan Pandiyarajan、Chowdhury Towhid H.、Subashchandran Shanthi、Bedja Idriss、Ghaithan Hamid M.、Islam Ashraful
    • Journal Title

      Sustainable Energy & Fuels

      Volume: 4 Pages: 5042~5049

    • DOI

      10.1039/d0se00786b

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Functional π-conjugated tetrathiafulvalene decorated with benzothiadiazole organic sensitizers for dye sensitized solar cells2019

    • Author(s)
      Duvva Naresh、Reddy Govind、Singh Surya Prakash、Chowdhury Towhid H.、Bedja Idriss、Islam Ashraful、Giribabu Lingamallu
    • Journal Title

      New Journal of Chemistry

      Volume: 43 Pages: 8919~8929

    • DOI

      10.1039/c9nj01029g

    • Peer Reviewed / Int'l Joint Research

URL: 

Published: 2021-12-27  

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