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2020 Fiscal Year Annual Research Report

Electronic structure characterization of non-aqueous solvents

Research Project

Project/Area Number 18K14178
Research InstitutionKyoto University

Principal Investigator

THUERMER STEPHAN  京都大学, 理学研究科, 准教授 (40722161)

Project Period (FY) 2018-04-01 – 2021-03-31
Keywordselectron spectroscopy / non-aqueous solvents / electronic structure / ionization energy / valence band
Outline of Annual Research Achievements

This project's aim was to study the electronic structure of liquids, with focus on non-aqueous solutions, in novel ways using photoelectron spectroscopy.
For the first time, the full valence band of ethanol and methanol was successfully characterized, which revealed that, unlike water, the molecular character is largely preserved even in the liquid state for these alcohols. The measurement protocol established here will be expanded to acetonitrile, propanol and other chemically relevant liquids in the future.
In parallel, a novel energy-referencing method for measuring absolute ionization energies was developed and applied to liquid water. Measuring accurate ionization energies is a prerequisite to study the electronic structure and chemistry of solutions. Applying this method to above alcohols revealed a distinct energy shift in ethanol, which hints at the presence of surface dipoles from orientated molecules at the liquid's surface. This may pave the way for novel ways to study the surface structure of liquids.
Furthermore, measurements of liquid ammonia with a unprecedented cryogenic liquid-jet have been made possible in international collaboration, which enabled first direct study of a insulator-to-metal transition in an alkali metal-ammonia solution. The gained knowledge was applied to study metallic water-solutions by forming a liquid water layer on a sodium-potassium droplet.
Overall, the project has expanded the scope and applicability of photoelectron spectroscopy to both aqueous and non-aqueous solutions for studying novel phenomena and chemically relevant parameters.

  • Research Products

    (6 results)

All 2021 Other

All Int'l Joint Research (2 results) Journal Article (2 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 2 results,  Open Access: 1 results) Remarks (2 results)

  • [Int'l Joint Research] Fritz Haber Institute/Helmholtz Zentrum Berlin/DESY Hamburg(ドイツ)

    • Country Name
      GERMANY
    • Counterpart Institution
      Fritz Haber Institute/Helmholtz Zentrum Berlin/DESY Hamburg
  • [Int'l Joint Research] Czech Academy of Sciences(チェコ)

    • Country Name
      CZECH
    • Counterpart Institution
      Czech Academy of Sciences
  • [Journal Article] Valence Photoelectron Spectra of Liquid Methanol and Ethanol Measured Using He II Radiation2021

    • Author(s)
      Thuermer Stephan、Shinno Takatoshi、Suzuki Toshinori
    • Journal Title

      The Journal of Physical Chemistry A

      Volume: 125 Pages: 2492~2503

    • DOI

      10.1021/acs.jpca.1c00288

    • Peer Reviewed
  • [Journal Article] Low-energy constraints on photoelectron spectra measured from liquid water and aqueous solutions2021

    • Author(s)
      Malerz Sebastian、Trinter Florian、Hergenhahn Uwe、Ghrist Aaron、Ali Hebatallah、Nicolas Christophe、Saak Clara-Magdalena、Richter Clemens、Hartweg Sebastian、Nahon Laurent、Lee Chin、Goy Claudia、Neumark Daniel M.、Meijer Gerard、Wilkinson Iain、Winter Bernd、Thuermer Stephan
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 23 Pages: 8246~8260

    • DOI

      10.1039/D1CP00430A

    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Remarks] Google Scholar User Profile

    • URL

      https://scholar.google.com/citations?user=05yx0h0AAAAJ

  • [Remarks] University Group Homepage

    • URL

      http://kuchem.kyoto-u.ac.jp/bukka/

URL: 

Published: 2021-12-27  

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