2011 Fiscal Year Final Research Report
Construction and Functions of Novel Elemento-Organic Compounds by Introduction of Innovative and Versatile Bulky Groups
| Project/Area Number |
19002008
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| Research Category |
Grant-in-Aid for Specially Promoted Research
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| Allocation Type | Single-year Grants |
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| Review Section |
Science and Engineering
Chemistry
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| Research Institution | The Institute of Physical and Chemical Research |
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Principal Investigator |
TAMAO Kohei 独立行政法人理化学研究所, 基幹研究所, 基幹研究所長 (60026218)
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| Co-Investigator(Kenkyū-buntansha) |
MATSUO Tsukasa 独立行政法人理化学研究所, 機能性有機元素化学特別研究ユニット, 副ユニットリーダー (90312800)
TANAKA Kazuyoshi 京都大学, 大学院・工学研究科, 教授 (90155119)
MINARI Takeo 物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, MANA研究者 (90443035)
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| Project Period (FY) |
2007 – 2011
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| Keywords | 有機化学 / 合成化学 / 高分子合成 / 高分子構造・物性 / 構造・機能材料 |
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| Research Abstract |
Novelπ-conjugated architectures containing heavy unsaturated bonds such as disilene and phosphasilene have been synthesized by the introduction of the newly developed bulky groups based on a fused-ring octa-R-substituted s-hydrindacene skeleton. Their unique electronic and photophysical properties based on the highly coplanarπ-frameworks have been demonstrated including the first observation of electroluminescene in an organic light-emitting diode. We have also succeeded to synthesize new unsaturated main group compounds ; their electronic and bonding nature have been elucidated by the experimental and theoretical studies.
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[Journal Article] Synthesis and Structures of a Series of Size-Controllable Bulky "Rind-Br" Based on a Rigid Fused-Ring s-Hydrindacene Skeleton2011
Author(s)
T. Matsuo, K. Suzuki, T. Fukawa, B. Li, M. Ito, Y. Shoji, T. Otani, L. Li, M. Kobayashi, M. Hachiya, Y. Tahara, D. Hashizume, T. Fukunaga, A. Fukazawa, Y. Li, H. Tsuji, K. Tamao
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Journal Title
Bull. Chem. Soc. Jpn
Volume: 84
Pages: 1178-1191
Peer Reviewed
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