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2011 Fiscal Year Final Research Report

New Functional Co-base Alloys-Phase stability and Its Industrial Applications

Research Project

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Project/Area Number 19106012
Research Category

Grant-in-Aid for Scientific Research (S)

Allocation TypeSingle-year Grants
Research Field Structural/Functional materials
Research InstitutionTohoku University

Principal Investigator

ISHIDA Kiyohito  東北大学, 大学院・工学研究科, 名誉教授 (20151368)

Co-Investigator(Kenkyū-buntansha) OHNUMA Ikuo  東北大学, 大学院・工学研究科, 准教授 (20250714)
Co-Investigator(Renkei-kenkyūsha) KAINUMA Ryosuke  東北大学, 大学院・工学研究科, 教授 (20202004)
OIKAWA Katsunari  東北大学, 大学院・工学研究科, 准教授 (70356608)
YAMAUCHI Kiyoshi  東北大学, 大学院・工学研究科, 教育研究支援者 (70375202)
SUTOU Yuji  東北大学, 大学院・工学研究科, 准教授 (80375196)
Project Period (FY) 2007 – 2011
Keywords新機能材料 / 状態図 / 熱力学データベース / 耐熱合金 / 磁気記録媒体 / 生体材料
Research Abstract

Thermodynamic database on Co-base alloys has been constructed based on the experimental determinations and thermodynamic assessments by Calphad (Calculation of Phase Diagrams)approach. Using this database, a new type of Co-base superalloys strengthend by the L1_2 compound of γ' Co_3(Al, W)phase has been designed. The developed wrought Co-base superalloy shows the expected creep strength of 100MPa at 800 oC for 10^5 hours, while the cast Co-base superalloy has been applied to the FSW (Friction Stir Welding)tool for practical use. It is shown that the Co-W thin film and Co-based Heusler alloys are attracted for magnetic recording media and spin electronics, respectively. Furthermore, the optimum conditions for compositions and heat treatment to form porous structure on the surface to develop drug eluting stent have been obtained by microstructural control of γ (fcc)/β (B2)lamellar structure of Co-Al-based alloys.

  • Research Products

    (62 results)

All 2012 2011 2010 2009 2008 2007 Other

All Journal Article (36 results) (of which Peer Reviewed: 36 results) Presentation (20 results) Remarks (3 results) Patent(Industrial Property Rights) (3 results)

  • [Journal Article] Magnetic properties of Co_<50>-XENIX_<25> Al_<25> alloys with B2 structure2011

    • Author(s)
      A. Okubo, X. Xu, R. Y. Umetsu, T. Kanomata, K. Ishida and R. Kainuma
    • Journal Title

      J. Appl. Phys.

      Volume: 109 Pages: 07B114

    • Peer Reviewed
  • [Journal Article] Phase transformations in the B2 phase of Co-rich Co-Al binary alloys2011

    • Author(s)
      K. Niitsu, T. Omori, M. Nagasako, K. Oikawa, R. Kainuma, K. Ishida
    • Journal Title

      J. Alloys Compds.

      Volume: 509 Pages: 2697-2702

    • Peer Reviewed
  • [Journal Article] Magnetic properties and phase stability of L2_1 phase in Co_2Mn(Ga_<1-x> Z_x)(Z=Si, Ge, and Sn)Heusler alloys2010

    • Author(s)
      A. Okubo, R. Y. Umetsu, K. Kobayashi, R. Kainuma and K. Ishida
    • Journal Title

      Appl. Phys. Lett.

      Volume: 96 Pages: 222507

    • Peer Reviewed
  • [Journal Article] Powder neutron diffraction studies for the L2_1 phase of Co_2YGa (Y=Ti, V, Cr, Mn and Fe)Heusler alloys2010

    • Author(s)
      R. Y. Umetsu, K. Kobayashi, R. Kainuma, Y. Yamaguchi, K. Ohoyama, A. Sakuma, K. Ishida
    • Journal Title

      J. Alloys Compds.

      Volume: 499 Pages: 1-6

    • Peer Reviewed
  • [Journal Article] Soft X-ray magnetic circular dichroism of L2_1-type Co_2FeGa Heusler alloy2010

    • Author(s)
      R. Y. Umetsu, T. Nakamura, K. Kobayashi, R. Kainuma, A. Sakuma, K. Fukamichi and K. Ishida
    • Journal Title

      J. Phys. D : Appl. Phys.

      Volume: 43 Pages: 105001

    • Peer Reviewed
  • [Journal Article] Electronic specific heat coefficient and magnetic properties of L2_1 phase in Co_2YGa(Y=Cr, Mn and Fe)Heusler alloys2010

    • Author(s)
      R. Y. Umetsu, N. Endo, A. Fujita, R. Kainuma, A. Sakuma, K. Fukamichi and K. Ishida
    • Journal Title

      J. Phys.: Conf. Ser.

      Volume: 200 Pages: 062036

    • Peer Reviewed
  • [Journal Article] Magnetic properties and phase stability of Co_2(Ti_<1-x> Mn_x)Ga Heusler alloys2010

    • Author(s)
      A. Okubo, R. Y. Umetsu, R. Kainuma and K. Ishida
    • Journal Title

      J. Phys.: Conf. Ser.

      Volume: 200 Pages: 062018

    • Peer Reviewed
  • [Journal Article] Large magnetic-field-induced strain in Co-Ni-Al single-variant ferromagnetic shape memory alloy2010

    • Author(s)
      H. Morito, K. Oikawa, A. Fujita, K. Fukamichi, R. Kainuma and K. Ishida
    • Journal Title

      Scripta Mater.

      Volume: 63 Pages: 379-382

    • Peer Reviewed
  • [Journal Article] Magnetization Process near the Curie Temperature of a Ferromagnetic Heusler Alloy Co2CrGa2010

    • Author(s)
      H. Nishihara, Y. Furutani, T. Wada, T. Kanomata, K. Kobayashi, R. Kainuma, K. Ishida, k. Koyama, K. Watanabe
    • Journal Title

      J. Physics : Conference Series

      Volume: 200 Pages: 032053

    • Peer Reviewed
  • [Journal Article] Hyperfine coupling constant for 59Co estimated from a high-field susceptibility and high-field NMR shift in ferromagnetic Co2TiGa and Co2VGa2010

    • Author(s)
      H. Nishihara, Y. Furutani, T. Wada, T. Kanomata, K. Kobayashi, R. Kainuma, K. Ishida and T. Yamauchi
    • Journal Title

      J. Physics : Conference Series

      Volume: 200 Pages: 032052

    • Peer Reviewed
  • [Journal Article] Experimental determination and thermodynamic assessment of the phase diagram in the Co-Zr system2009

    • Author(s)
      X. J. Liu, H. H. Zhang, C. P. Wang, K. Ishida
    • Journal Title

      J. Alloys Compds

      Volume: 482 Pages: 99-105

    • Peer Reviewed
  • [Journal Article] Thermodynamic assessments of the Co-Er and V-Er systems2009

    • Author(s)
      C. P. Wang, A. Q. Zheng, X. J. Liu, K. Ishida
    • Journal Title

      J. Alloys Compds.

      Volume: 478 Pages: 197-201

    • Peer Reviewed
  • [Journal Article] Intermetallic Compounds in Co-Base Alloys-Phase Stability and Application to Super alloys2009

    • Author(s)
      K. Ishida
    • Journal Title

      Mater. Res. Soc. Symp. Proc.

      Volume: 1128 Pages: 357-368

    • Peer Reviewed
  • [Journal Article] Phase Stability of the L1_2 Compound and Microstructural Changes in Co-(W or Mo)-Ta Ternary Alloys2009

    • Author(s)
      H. Chinen, T. Omori, K. Oikawa, I. Ohnuma, R. Kainuma and K. Ishida
    • Journal Title

      Mater. Res. Soc. Symp. Proc.

      Volume: 1128 Pages: 375-379

    • Peer Reviewed
  • [Journal Article] Determination of phase equilibria in the Co-rich Co-Al-W ternary system with a diffusion-couple technique2009

    • Author(s)
      S. Kobayashi, Y. Tsukamoto, T. Takasugi, H. Chinen, T. Omori, K. Ishida, S. Zaefferer
    • Journal Title

      Intermetalics

      Volume: 17 Pages: 1085-1089

    • Peer Reviewed
  • [Journal Article] Phase Equilibria and Ternary Intermetallic Compound with L1_2 Structure in Co-W-Ga System2009

    • Author(s)
      H. Chinen, T. Omori, K. Oikawa, I. Ohnuma, R. Kainuma, and K. Ishida
    • Journal Title

      J. Phase Equilibria and Diffusion

      Volume: 30 Pages: 587-594

    • Peer Reviewed
  • [Journal Article] Experimental investigation and thermodynamic calculation of the phase equilibria in the Co. Mo. W system2009

    • Author(s)
      C. P. Wang, J. Wang, S. H. Guo, X. J. Liu, I. Ohnuma, R. Kainuma and K. Ishida
    • Journal Title

      Intermetallics

      Volume: 17 Pages: 642-650

    • Peer Reviewed
  • [Journal Article] Ductility enhancement by boron addition in Co-Al-W high-temperature alloys2009

    • Author(s)
      K. Shinagawa, T. Omori, K. Oikawa, R. Kainuma and K. Ishida
    • Journal Title

      Scripta Mater.

      Volume: 61 Pages: 612-615

    • Peer Reviewed
  • [Journal Article] Stress-assisted large magnetic-field-induced strain in single-variant Co. Ni. Ga ferromagnetic shape memory alloy2009

    • Author(s)
      H. Morito, K. Oikawa, A. Fujita, K. Fukamichi, R. Kainuma and K. Ishida
    • Journal Title

      J. Phys. Condens. Matter

      Volume: 21 Pages: 256002-256007

    • Peer Reviewed
  • [Journal Article] Magnetic anisotropy of epitaxially grown Co and its alloy thin films2009

    • Author(s)
      J-J Wang, T. Sakurai, K. Oikawa, K. Ishida, N. Kikuchi, S. Okamoto, H. Sato, T. Shimatsu and O. Kitakami
    • Journal Title

      J. Phys : Condens. Matter

      Volume: 21 Pages: 185008-13

    • Peer Reviewed
  • [Journal Article] Thermodynamic evaluation of the Co-Sc and Fe-Sc systems2008

    • Author(s)
      X. J. Liu, P. Yu, C. P. Wang, K. Ishida
    • Journal Title

      J. Alloys and Compds.

      Volume: 466 Pages: 169-175

    • Peer Reviewed
  • [Journal Article] Experimental determination of phase equilibria in the Co-Ti-Mo ternary system2008

    • Author(s)
      Y. Yu, C. P. Wang, X. J. Liu, I. Ohnuma, R. Kainuma and K. Ishida
    • Journal Title

      Intermetallics

      Volume: 16 Pages: 1199-1205

    • Peer Reviewed
  • [Journal Article] Recent Progress on Co-Base Alloys . Phase Diagrams and Application2008

    • Author(s)
      K. Ishida
    • Journal Title

      Archive of Metallurgy and Materials

      Volume: 53 Pages: 1075-1088

    • Peer Reviewed
  • [Journal Article] Magnetic properties and stability of L2_1 and B2 phases in the Co_2MnAl Heusler alloy2008

    • Author(s)
      R. Y. Umetsu, K. Kobayashi, A. Fujita, R. Kainuma and K. Ishida
    • Journal Title

      J. Appl. Phys.

      Volume: 103 Pages: 07D718-1-3

    • Peer Reviewed
  • [Journal Article] Computional Study of Atomic Mobility in Co-Fe-Ni Ternary Fcc Alloys2008

    • Author(s)
      Y. W. Cui, M. Jiang, I. Ohnuma, K. Oikawa, R. Kainuma and K. Ishida
    • Journal Title

      J. Phase Equilibria and Diffusion

      Volume: 29 Pages: 312-321

    • Peer Reviewed
  • [Journal Article] Phase stability anode magnetic properties of Co_2(Ti_<1-x> Fax)Ga Heusler alloys2008

    • Author(s)
      A. Okubo, R. Y. Umetsu, M. Nagasako, A. Fujita, R. Kainuma and K. Ishida
    • Journal Title

      Scripta Mater.

      Volume: 59 Pages: 830-833

    • Peer Reviewed
  • [Journal Article] Phase Equilibria and Microstructure on γ' Phase in Co-Ni-Al-W System2008

    • Author(s)
      K. Shinagawa, T. Omori, J. Sato, K. Oikawa, I. Ohnuma, R. Kainuma and K. Ishida
    • Journal Title

      Mater. Trans.

      Volume: 49 Pages: 1474-1479

    • Peer Reviewed
  • [Journal Article] Thermodynamic assessment of the Co-La and Mo-La system2008

    • Author(s)
      C. P. Wang, J. Wang, X. J. Liu, I. Ohnuma, R. Kainuma and K. Ishida
    • Journal Title

      J. Alloys Compds.

      Volume: 453 Pages: 174-179

    • Peer Reviewed
  • [Journal Article] Phase stability and magnetic properties of L2_1 phase in Co_2Mn(Al_<1-x> Six)Heusler alloys2008

    • Author(s)
      R. Y. Umetsu, K. Kobayashi, A. Fujita, R. Kainuma and K. Ishida
    • Journal Title

      Scripta Mater.

      Volume: 58 Pages: 723-726

    • Peer Reviewed
  • [Journal Article] Computational Study of Atomic Mobility for fact Phase of Co-Fe and Co-Ni Binaries2008

    • Author(s)
      Y. W. Cui, M. Jiang, I. Ohnuma, R. Kainuma and K. Ishida
    • Journal Title

      J. Phase Equilibria and Diffusion

      Volume: 29 Pages: 2-10

    • Peer Reviewed
  • [Journal Article] Magnetic properties, phase stability, electronic structure, and half-metallicity of L2_1-type Co_2(V_<1-x> Manx)Ga Heusler alloys2008

    • Author(s)
      R. Umetsu, K. Kobayashi, A. Fujita, R. Kainuma and K. Ishida
    • Journal Title

      PHYSICAL REVIEW

      Volume: B77 Pages: 104422-1-8

    • Peer Reviewed
  • [Journal Article] Thermodynamic assessment of the Co-The and Fe-Th systems2008

    • Author(s)
      C. P. Wang, P. Yu, X. J. Liu, I. Ohnuma, R. Kainuma and K. Ishida
    • Journal Title

      J. Alloys Compds.

      Volume: 457 Pages: 150-156

    • Peer Reviewed
  • [Journal Article] Phase equilibria in the Ni. Co. Ga alloy system2008

    • Author(s)
      R. Ducher, R. Kainuma, K. Ishida
    • Journal Title

      J. Alloys Compds.

      Volume: 466 Pages: 208-213

    • Peer Reviewed
  • [Journal Article] Phase equilibria and stability of B2 and L2_1 ordered phases in the Co-Fe-Ga Heusler alloy system2007

    • Author(s)
      R. Ducher, R. Kainuma and K. Ishida
    • Journal Title

      J. Alloys Compds.

      Volume: 437 Pages: 93-101

    • Peer Reviewed
  • [Journal Article] Phase Stability of B2 and L2_1 ordered phases in Co_2YGa (Y=Ti, V, Cr, Mn, Fe)alloys2007

    • Author(s)
      K. Kobayashi, K. Ishikawa, R. Y. Umetsu, R. Kainuma, K. Aoki and K. Ishida
    • Journal Title

      J. Mag. Mag. Mater.

      Volume: 310 Pages: 1794-1795

    • Peer Reviewed
  • [Journal Article] New ternary compound Co_3(Ge, W)with L1_2 structure2007

    • Author(s)
      H. Chinen, J. Sato, T. Omori, K. Oikawa, I. Ohnuma, R. Kainuma and K. Ishida
    • Journal Title

      Scripta Mater.

      Volume: 56 Pages: 141-143

    • Peer Reviewed
  • [Presentation] New Co-base Superalloys Strengthened By γ' Phase-Phase Equilibria and Applications-2012

    • Author(s)
      K. Ishida
    • Organizer
      1^<st> NIST γ/γ' Cobalt-Based superalloy Workshop
    • Place of Presentation
      Washington, U.S.A.(Keynote lecture)
    • Year and Date
      2012-05-02
  • [Presentation] Co-Al-W基耐熱合金系熱力学データベースの構築2012

    • Author(s)
      品川一矢, 大森俊洋, 及川勝成, 大沼郁雄, 貝沼亮介, 石田清仁
    • Organizer
      日本金属学会2012年春期講演(第150回)大会
    • Place of Presentation
      横浜国立大学:横浜市
    • Year and Date
      2012-03-30
  • [Presentation] γ' 相析出型Co-Al-W基鍛造合金の設計と現状2012

    • Author(s)
      大森俊洋, 品川一矢, 石田清仁, 佐藤順, 今野晋也, 大崎元嗣, 植田茂紀
    • Organizer
      日本金属学会2012年春期講演(第150回)大会
    • Place of Presentation
      横浜国立大学:横浜市
    • Year and Date
      2012-03-30
  • [Presentation] New Co-base Superalloys Strengthened By γ' Phase-Phase Equilibria and Application-2012

    • Author(s)
      K. Ishida
    • Organizer
      TMS 2012
    • Place of Presentation
      Orland, U. S. A.(Invited lecture)
    • Year and Date
      2012-03-14
  • [Presentation] New Co-Base Superalloys Strengthened By γ' Phase Phase Equilibria and Applications-2011

    • Author(s)
      K. Ishida
    • Organizer
      3^<rd> International Conference HighMatTech
    • Place of Presentation
      Kiev, Ukraine(Invited lecture)
    • Year and Date
      2011-10-04
  • [Presentation] Friction-Stir Welding of High-Softening-Temperature Materials using Cobalt-Based Alloy Tool2011

    • Author(s)
      S. H. C. Park, S. Hirano, S. Imano, Y. S. Sato, H. Kokawa, T. Omori and K. Ishida
    • Organizer
      THERMEC' 2011
    • Place of Presentation
      Quebec City, Canada(Invited lecture)
    • Year and Date
      2011-08-04
  • [Presentation] New Co-base Superalloys Strengthened By γ' Phase-Phase Equilibria and Application .2011

    • Author(s)
      K. Ishida
    • Organizer
      CALPHAD XL
    • Place of Presentation
      Rio de Janeiro, Brasil(Invited lecture)
    • Year and Date
      2011-05-24
  • [Presentation] DEVELOPMENT OF COBALT-BASED ALLOY FSW TOOL FOR HIGH-SOFTENING-TEMPERATURE MATERIALS2011

    • Author(s)
      Y. S. Sato, M. Miyake, H. Kokawa, T. Omori, K. Ishida, S. Imano, S. H. C. Park, S. Hirano
    • Organizer
      TMS 2011
    • Place of Presentation
      San Diego, U. S. A.
    • Year and Date
      2011-03-01
  • [Presentation] Phase Diagrams and Design of Some Advanced Materials Recent Progress on Co-and Fe-based Alloys-Phase Equilibria and Application-2010

    • Author(s)
      K. Ishida
    • Organizer
      NCPDC
    • Place of Presentation
      Shenyang, China(Invited lecture)
    • Year and Date
      2010-10-14
  • [Presentation] Partition of Alloying Elements in Co-Al-W-Base Systems2010

    • Author(s)
      T. Omori, J. Sato, K. Oikawa, I. Ohnuma, R. Kainuma and K. Ishida
    • Organizer
      PRICM
    • Place of Presentation
      Cairns, Australia
    • Year and Date
      2010-08-05
  • [Presentation] Effect of Alloying Elements on Phase Equilibria in New Co-based Superalloy2010

    • Author(s)
      T. Omori, J. Sato, K. Oikawa, I. Ohnuma, R. Kainuma and K. Ishida
    • Organizer
      CIMTEC 2010
    • Place of Presentation
      Montecatini Terme, Italy
    • Year and Date
      2010-06-14
  • [Presentation] 合金状態図と先端材料設計2010

    • Author(s)
      石田清仁
    • Organizer
      日本金属学会2010年第146回春期大会
    • Place of Presentation
      筑波大学(本多記念講演)
    • Year and Date
      2010-03-28
  • [Presentation] L1_2 Compound in Co-base Alloys2009

    • Author(s)
      K. Ishida
    • Organizer
      Thermec 2009
    • Place of Presentation
      Berlin, Germany(Invited lecture)
    • Year and Date
      2009-08-25
  • [Presentation] Co-base High Temperature Alloys2009

    • Author(s)
      K. Ishida
    • Organizer
      Materials 2009
    • Place of Presentation
      Lisbon, Portugal
    • Year and Date
      2009-04-05
  • [Presentation] Intermetallic Compounds in Co-base Alloys-Phase Stability and Application to Superalloys-2008

    • Author(s)
      K. Ishida
    • Organizer
      MRS2008
    • Place of Presentation
      Boston, U. S. A.(Invited lecture)
    • Year and Date
      2008-12-01
  • [Presentation] Phase Diagrams and Design of Some Advanced Materials2008

    • Author(s)
      K. Ishida
    • Organizer
      2008NCMS
    • Place of Presentation
      Chansha, China (Keynote lecture)
    • Year and Date
      2008-11-03
  • [Presentation] RECENT PROGRESS ON CO-BASE alloys-phase diagrams and application-2008

    • Author(s)
      K. ISHIDA
    • Organizer
      TOFA 2008
    • Place of Presentation
      Krakow, Poland (Keynote lecture)
    • Year and Date
      2008-06-22
  • [Presentation] Phase Diagrams and Design of Some Non-Ferrous Advanced Materials2007

    • Author(s)
      K. Ishida
    • Organizer
      ICNFM 2007 (International Conference of Nonferrous Materials, 2007)
    • Place of Presentation
      Changsha, China (Keynote lecture)
    • Year and Date
      2007-11-26
  • [Presentation] Co基合金における金属間化合物-相安定性と耐熱合金への展開-2007

    • Author(s)
      石田清仁
    • Organizer
      日本金属学会2007年第141回秋期大会
    • Place of Presentation
      岐阜大学(基調講演)
    • Year and Date
      2007-09-19
  • [Presentation] Recent Progress on Co-base Alloys-Phase Diagrams and Application2007

    • Author(s)
      K. Ishida
    • Organizer
      62nd ABM' S ANNUAL INTERNATIONAL CONGRESS
    • Place of Presentation
      Vitoria, Brazil (Keynote lecture)
    • Year and Date
      2007-07-23
  • [Remarks] 新聞発表:○「硬い金属溶かさず接合日立・東北大が器具摩擦熱で柔らかく」(平成22年3月31日:日経産業新聞)

  • [Remarks] ○「高融点材も接合可能摩擦攪拌ツールを開発」(平成22年3月29日:電気新聞)

  • [Remarks] ○「融点高い金属を接合東北大と日立FSWツール開発」(平成22年3月29日:日刊工業新聞

  • [Patent(Industrial Property Rights)] Co基合金2012

    • Inventor(s)
      大崎元嗣、植田茂樹、石田清仁、大森俊洋、西田浩明、林祐宏、塩田智紀、今野晋也、佐藤順
    • Industrial Property Rights Holder
      大同特殊鋼(株)、国立大学法人東北大学、本田技研工業(株)、(株)日立製作所
    • Patent Publication Number
      特許、特開2012-41627
    • Filing Date
      2012-03-01
  • [Patent(Industrial Property Rights)] 摩擦攪拌用ツール2011

    • Inventor(s)
      朴勝煥、平野聡、今野晋也、佐藤順、粉川博之、佐藤裕、石田清仁、大森俊洋
    • Industrial Property Rights Holder
      (株)日立製作所、国立大学法人東北大学
    • Patent Publication Number
      特許、特開2011-062731
    • Filing Date
      2011-03-31
  • [Patent(Industrial Property Rights)] 高耐熱性Co基合金2009

    • Inventor(s)
      大崎元嗣、植田茂紀、志水哲也、石田清仁、大森俊洋、長濱大輔、林祐弘、輪嶋善彦
    • Industrial Property Rights Holder
      大同特殊鋼(株)、本田技研工業(株)、国立大学法人東北大学
    • Industrial Property Number
      特許、特開:2009-228024
    • Filing Date
      2009-10-08

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Published: 2013-07-31  

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