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2007 Fiscal Year Annual Research Report

機能性ナノチューブの電気・機械特性の高分解能電子顕微鏡内その場測定及び工学的加工

Research Project

Project/Area Number 19310080
Research InstitutionNational Institute for Materials Science

Principal Investigator

DMITRI GOLBERG  National Institute for Materials Science, ナノスケール物質センター, グルーブリーダー (80354405)

Co-Investigator(Kenkyū-buntansha) 板東 義雄  独立行政法人物質・材料研究機構, ナノスケール物質センター, フェロー (10344433)
三留 正則  独立行政法人物質・材料研究機構, ナノスケール物質センター, 主幹研究員 (50354410)
CHENGCHUN Tang  独立行政法人物質・材料研究機構, ナノスケール物質センター, 主幹研究員 (10370298)
Keywordsナノチューブ / 無機化合物 / ナノワイヤー / 電子顕微鏡 / 機械特性 / 電気特性
Research Abstract

本プロジェクトは、BN、B-C-N、CN_x、ZnS、ZnO、MgO、SiO_2などから成る種々の無機ナノチューブの電気的・機械的特性を、300kV電界放射型高分解能電子顕微鏡の中で、'その場'測定することを目的としている。この測定では、化学組成、原子配列、電子構造、欠陥構造が異なった個々の無機ナノチューブについて、一本一本独立にその物性を明らかにすることができる。実験は、ピエゾ駆動可能な探針を備え、電子顕微鏡観察と同時にSTM、AFM観察が可能な、新開発の試料ホルダーを用いて実施する。本試料ホルダーを用いることで、電子顕微鏡内において、STMおよびAFM探針を測定したい特定の無機ナノチューブに近づけ、一本のナノチューブから物性測定を行うことが可能となる。この最新装置の利用により、長い間望まれていたナノテク技術における最終ゴールへの到達、すなわち、種々の独立したナノチューブの構造および化学組成と、その電気・機械特性の関係を明らかにすることが可能となる。

  • Research Products

    (42 results)

All 2008 2007 Other

All Journal Article (21 results) (of which Peer Reviewed: 20 results) Presentation (11 results) Book (1 results) Remarks (1 results) Patent(Industrial Property Rights) (8 results)

  • [Journal Article] ZnO low-dimensional structures:electrical properties measured inside a transmission electron microscope2008

    • Author(s)
      Costa P.M.F.J., Golberg D., Mitome M., Shen G.Z., Bando Y.
    • Journal Title

      J.Mater.Sci. 41

      Pages: 1460-1470

    • Peer Reviewed
  • [Journal Article] Stone-Wales defects in single-walled BN nanotubes-formation energies,electronic structure and reactivity2008

    • Author(s)
      Li Y.F., Zhen Z., Golberg D., Bando Y., Schleyer P. V. R., Chen Z.F
    • Journal Title

      J.Phys.Chem.C 112

      Pages: 1365-1370

    • Peer Reviewed
  • [Journal Article] Electrical properties of CNx nanotubes probed in a transmission electron microscope2008

    • Author(s)
      Costa P.M.F.J., Golberg D., Mitome M., Bando Y.
    • Journal Title

      Appl.Phys.A.Mater.Sci.&Proc 90

      Pages: 225-229

    • Peer Reviewed
  • [Journal Article] Electron-beam-induced synthesis and characterization of W_<18>O<49>nanowires2008

    • Author(s)
      Shen G.Z., Bando Y., Golberg D., Zhou C.W
    • Journal Title

      J.Phys.Chem.C 112

      Pages: 5856-5859

    • Peer Reviewed
  • [Journal Article] Experimental and theoretical studies suggesting the possibility of metallic Boron Nitride edges in porous nanourchins"2008

    • Author(s)
      Terrones M., Charlier J.-C., Gloter A., Cruz-Silva E., Terres E., Li Y.B., Vinu A., Dominguez J.M., Terrones H., Bando Y., Golberg D
    • Journal Title

      Nano Letters 8

      Pages: 1026-1032

    • Peer Reviewed
  • [Journal Article] A novel core-shell heterostructure of branched ZnS nanotube-In nanowires:synthesis,structure and multiply enhanced field-emission properties2008

    • Author(s)
      Gautam U.K., Fang X.S., Bando Y., Zhan J.H., Golberg D.
    • Journal Title

      ACS Nano, DOI10.1021/nn800013b.(in press)

  • [Journal Article] Copper-filled carbon nanotubes:rheostat-like behavior and femtogram copper mass transport2007

    • Author(s)
      Golberg D., Costa P., Mitome M. Mueller C., Hampel S., Bando Y.
    • Journal Title

      Advanced Materials 19

      Pages: 1937-1942

    • Peer Reviewed
  • [Journal Article] Boron nitride nanotubes2007

    • Author(s)
      Golberg D., Bando Y., Tang C., Zhi C.Y.
    • Journal Title

      Advanced Materials 19

      Pages: 2413-2432

    • Peer Reviewed
  • [Journal Article] Direct force measurements and kinking under elastic deformation of individual multiwalled boron nitride nanotubes2007

    • Author(s)
      Golberg D., Costa P., Lourie 0., Mi-tome M., Tang C., Zhi C., Bando Y.
    • Journal Title

      Nano Letters 7

      Pages: 2146-2151

    • Peer Reviewed
  • [Journal Article] Structural peculiarities of in-situ deformation of an individual Boron Nitride nanotube inside a high-resolution transmission electron microscope2007

    • Author(s)
      Golberg D., Bai X.D., Mitome M., Tang C.C., Zhi C.Y., Bando Y.
    • Journal Title

      Acta Materialia 55

      Pages: 1293-1298

    • Peer Reviewed
  • [Journal Article] Boron nitride nanotubes nanoparticles functionalization and junction fabrication2007

    • Author(s)
      Zhi C.Y., Bando Y., Shen G.Z., Tang C.C., Golberg D
    • Journal Title

      Nanosci. Nanotech. 7

      Pages: 530-534

    • Peer Reviewed
  • [Journal Article] Donor-acceptor nanoensembles based on Boron Nitride nanotubes2007

    • Author(s)
      Huang Q., Sandanayaka A.S., Bando Y., Zhi C.Y., Golberg D., Zhao J., Araki Y., Ito O
    • Journal Title

      Adv. Mater. 19

      Pages: 934-938

    • Peer Reviewed
  • [Journal Article] Pure and doped boron nitride nanotubes2007

    • Author(s)
      Terrones M., Romo-Herrera J.M., Cruz-Silva E., Lopez-Uriaz F., Munoz-Sandoval E., Velazquez-Salazar J.J., Terrones H., Bando Y., Golberg D
    • Journal Title

      Materials Today 10

      Pages: 30-38

    • Peer Reviewed
  • [Journal Article] Mg_3N_2-Ga:Nanoscale semiconductor-liquid metal heterojunctions inside graphitic carbon nanotubes2007

    • Author(s)
      Hu J.Q., Bando Y., Zhan J.H., Li C. Z., Golberg D.
    • Journal Title

      Adv.Mater. 19

      Pages: 1342-1346

    • Peer Reviewed
  • [Journal Article] Multi-walled Boron Nitride nanotubes composed of diverse cross-section and helix type shells2007

    • Author(s)
      Golberg D., Mitome M., Bando Y., Tang C.C., Zhi C.Y.
    • Journal Title

      Appl.Phys.A 88

      Pages: 347-352

    • Peer Reviewed
  • [Journal Article] Photoinduced-charge-injecting and band-gap-engineering of high-specific-surface-area BN nanotubes using a monolayer of zinc phthalocyanine2007

    • Author(s)
      Huang Q., Bando Y, Sandanayaka, Tang C., Wang J., Sekiguchi T., Zhi C.Y., Golberg D., Araki Y., Ito O., Xu F.F., Gao L.
    • Journal Title

      Small 3

      Pages: 1330-1335

    • Peer Reviewed
  • [Journal Article] Recent developments in single-crystal inorganic nanotubes synthesized from removable templates2007

    • Author(s)
      Shen G.Z., Bando Y., Golberg D
    • Journal Title

      Int. J. Nanotechnology 4

      Pages: 730-749

    • Peer Reviewed
  • [Journal Article] Ultrafine ZnS nanobelts as field emitters2007

    • Author(s)
      Fang X.S., Bando Y., Shen G.Z., Ye C.H., Gautam U.K., Zhi C.Y., Hu J.Q., Costa P.J.M.F., Tang C.C., Golberg D
    • Journal Title

      Adv. Mater. 19

      Pages: 2593-2596

    • Peer Reviewed
  • [Journal Article] Boron nitride nanotubes:recent breakthroughs and challenges2007

    • Author(s)
      Golberg D., Costa P.M.F.J., Bai X.D., Tang C., Huang Q., Mitome M., Bando Y.
    • Journal Title

      ECS Transactions 11

      Pages: 15-19

    • Peer Reviewed
  • [Journal Article] Nitrogen-doped carbon nanotubes structure tailoring and time-resolved transport measurements in a transmission electron microscope2007

    • Author(s)
      Costa P., M., F., J., Golberg D., Mitome M., Bando Y.
    • Journal Title

      Appl.Phys.Lett. 91

      Pages: 2231081-3

    • Peer Reviewed
  • [Journal Article] Boron-Oxygen species luminescence centers in Boron-Nitrogen system2007

    • Author(s)
      Tang C.C.; Bando Y., Zhi C.Y., Golberg D.
    • Journal Title

      Chem.Comm.

      Pages: 4599-4601

    • Peer Reviewed
  • [Presentation] IN-SITU TRANSPORT MEASUREMENTS OF NOVEL NANOTUBES UNDER TEM2008

    • Author(s)
      Bando Y., Golberg D.
    • Organizer
      Remote Electron Microscopy for In Situ Studies
    • Place of Presentation
      Stanford,アメリカ
    • Year and Date
      20080331-0401
  • [Presentation] Thermally-conductive polymer composite films containing BN nanotubes as fillers2008

    • Author(s)
      Terao T., Bando Y, Golberg D., Mitame M., Zhi C., Tang C.
    • Organizer
      日本化学会第88春季年会(2008)
    • Place of Presentation
      東京,日本
    • Year and Date
      20080326-30
  • [Presentation] In-situ TEM electrical and mechanical property measurements of low-dimensional inorganic nanomaterials2008

    • Author(s)
      Golberg D., Costa P., Bai X., Lourie O, Kurashima K., Mitome M., Tang C., Bando Y.
    • Organizer
      IEEE International Nanoelectronics Conference (INEC)2008
    • Place of Presentation
      Shanghai, China
    • Year and Date
      20080324-27
  • [Presentation] Coating of BN nanotubes with metal oxides using novel ethanol-thermal method2008

    • Author(s)
      Huang Y., Bando Y., Tang C., Zhi C, Terao T., Golberg D
    • Organizer
      The 34th Fullerene Nanotubes General Symposium
    • Place of Presentation
      Nagoya,日本
    • Year and Date
      20080303-05
  • [Presentation] Recent Advances in in-situ TEM:Electrical and Mechanical Property Studies of Individual Low-Dimensional Inorganic Nanostructures2008

    • Author(s)
      Golberg D., Costa P., Bai X., Lourie O, Kurashima K, Mitome M., Tang C., Bando Y.
    • Organizer
      ACMM-20 & IUMAS-IV
    • Place of Presentation
      Perth,Australia
    • Year and Date
      20080210-15
  • [Presentation] Synthesis and propertiees of novel inorganic nanotubes2007

    • Author(s)
      Bando Y
    • Organizer
      INDIA-NIMS Workshop on Advanced Materials(INW AM-2007)
    • Place of Presentation
      Bangalore,インド
    • Year and Date
      20071217-18
  • [Presentation] In-situ transport measurements of novel nanotubes under TEM2007

    • Author(s)
      Bando Y., Golberg D., Costa P.
    • Organizer
      7th France-Japan Workshop on Nanosciences and Nanomaterials
    • Place of Presentation
      Strasbourg,フランス
    • Year and Date
      20071024-26
  • [Presentation] Boron nitride nanotubes:recent breakthroughs and challenges2007

    • Author(s)
      Golberg D., Zhi C., Costa P., Bai X., Mitome M., Tang C., Bando Y.
    • Organizer
      212th Meeting of Electrochemical Society of America
    • Place of Presentation
      Washington DC,USA
    • Year and Date
      20071007-12
  • [Presentation] Dispersing BN nanotubes with DNA and its applications2007

    • Author(s)
      Bando Y., Golberg D., Tang C., Kuwahara H.
    • Organizer
      European Congress and exhibition on advanced materials and processes
    • Place of Presentation
      Nurnberg,Germany
    • Year and Date
      20070910-13
  • [Presentation] Novel Functional Inorganic Nanotubes2007

    • Author(s)
      Golberg D., Bando Y., Mitome M., Costa P., Zhi C.
    • Organizer
      IWFAC'2007
    • Place of Presentation
      Petersburg,ロシア
    • Year and Date
      20070702-06
  • [Presentation] In-situ TEM electromechanical probing of BN nanotubes2007

    • Author(s)
      Golberg D., Bai X., Costa P., Mitome M, Kurashima K., Zhi C., Tang C., Bando Y.
    • Organizer
      日本顕微鏡学会第63回学術講演会JSM'07
    • Place of Presentation
      新潟市,日本(Japan)
    • Year and Date
      20070520-22
  • [Book] In-situ electron microscopy of filled nanotubes(in press)2008

    • Author(s)
      Golberg D., Bando Y.
    • Publisher
      World Scientific Publishers
  • [Remarks]

    • URL

      http://www.nims.go.jp/synthesis/index.html

  • [Patent(Industrial Property Rights)] 成形用ドープ2008

    • Inventor(s)
      桑原 明広、板東 義雄、Zhi Chunyi、Chengchun Tang、Dmitri Golberg
    • Industrial Property Rights Holder
      帝人株式会社、独立行政法人物質・材料研究機構
    • Industrial Property Number
      特願2008-000645
    • Filing Date
      2008-01-07
  • [Patent(Industrial Property Rights)] 複合ナノワイヤーの蒸発除去による窒化ホウ素ナノチューブとその製造方法2007

    • Inventor(s)
      板東義雄Chengchun Tang Dmitri Golberg
    • Industrial Property Rights Holder
      独立行政法人物質・材料研究機構
    • Industrial Property Number
      特願2007-114907
    • Filing Date
      2007-04-25
  • [Patent(Industrial Property Rights)] 窒化ホウ素ナノチューブゲルおよびアルキル化された窒化ホウ素ナノチューブならいびそれらの製造方法2007

    • Inventor(s)
      板東 義雄、Zhi Chunyi、Chengchun Tang、Dmitri Golberg、桑原 明広
    • Industrial Property Rights Holder
      独立行政法人物質・材料研究機構、帝人株式会社
    • Industrial Property Number
      特願2007-282523
    • Filing Date
      2007-10-30
  • [Patent(Industrial Property Rights)] 耐熱性に優れた樹脂組成物及びその製造方法2007

    • Inventor(s)
      桑原 明広、板東 義雄、Zhi Chunyi、Chengchun Tang、Dmitri Golberg
    • Industrial Property Rights Holder
      帝人株式会社、独立行政法人物質・材料研究機構
    • Industrial Property Number
      特願2007-138843
    • Filing Date
      2007-05-25
  • [Patent(Industrial Property Rights)] 耐熱性に優れた樹脂組成物及びその製造方法2007

    • Inventor(s)
      桑原 明広、板東 義雄、Zhi Chunyi、Chengchun Tang、Dmitri Golberg
    • Industrial Property Rights Holder
      帝人株式会社、独立行政法人物質・材料研究機構
    • Industrial Property Number
      特願2007-162631
    • Filing Date
      2007-06-20
  • [Patent(Industrial Property Rights)] 熱硬化樹脂複合組成物、樹脂シートおよびその製造方法2007

    • Inventor(s)
      桑原 明広、板東 義雄、Zhi Chunyi、Chengchun Tang、Dmitri Golberg
    • Industrial Property Rights Holder
      帝人株式会社、独立行政法人物質・材料研究機構
    • Industrial Property Number
      特願2007-222508
    • Filing Date
      2007-08-29
  • [Patent(Industrial Property Rights)] 機械特性に優れた耐熱性樹脂組成物及びその製造方法2007

    • Inventor(s)
      桑原 明広、板東 義雄、Zlli Chunyi、Chengchun Tang、Dmitri Golberg
    • Industrial Property Rights Holder
      帝人株式会社、独立行政法人物質・材料研究機構
    • Industrial Property Number
      特願2007-275072
    • Filing Date
      2007-10-23
  • [Patent(Industrial Property Rights)] 窒化ホウ素ナノ繊維及びその製造方法2007

    • Inventor(s)
      桑原 明広、板東 義雄、Zhi Chunyi、Chengchun Tang、Dmitri Golberg
    • Industrial Property Rights Holder
      帝人株式会社、独立行政法人物質・材料研究機構
    • Industrial Property Number
      特願2007-336861
    • Filing Date
      2007-12-07

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Published: 2010-02-04   Modified: 2021-09-21  

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