2009 Fiscal Year Final Research Report
A study of donor ability of fluorocarbon (C-F) using specific properties of macrocyclic compounds.
| Project/Area Number |
19550052
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Japan Women's University |
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Principal Investigator |
TAKEMURA Hiroyuki Japan Women's University, 理学部, 准教授 (60183456)
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| Project Period (FY) |
2007 – 2009
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| Keywords | C-F…HO水素結合 / C-F…M^+相互作用 / フッ素 / シクロファン / クリプタンド / X線結晶構造解析 |
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| Research Abstract |
The C-F…HO hydrogen bond was observed in the compounds, 2-fluorophenyldiphenylmethanol and 1-fluoro-4-methyl-8-naphthol. The structures showed shorter C-F…HO distances than those of the sum of van der Waals radii of F and H atoms. Fluorine containing macrocyclic compounds formed several metal ions and the relationship between ^<19>F NMR chemical shifts and ionic radii of the metal ions was observed.
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