イオン液体を用いた次世代エネルギー変換・貯蔵デバイスの開発

Products Report

• Project/Area Number: 20246140
• Research Category: Grant-in-Aid for Scientific Research (A)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Energy engineering
• Research Institution: Kyoto University
• Principal Investigator: HAGIWARA Rika (HAGIWAR Rika) 京都大学, エネルギー科学研究科, 教授 (30237911)
• Co-Investigator(Kenkyū-buntansha): NOHIRA Toshiyuki 京都大学, エネルギー科学研究科, 准教授 (00303876) ; 後藤 琢也 京都大学, エネルギー科学研究科, 助教 (60296754)
• Co-Investigator(Renkei-kenkyūsha): GOTO Takuya 同志社大学, 工学部, 准教授 (60296754)
• Project Period (FY): 2008 – 2012

Research Products

• [Journal Article] Polymorphism of Alkali Bis (fluorosulfonyl) amides (M[N(SO_2F)_2], M=Na, K, and Cs) (2013)
  • Author(s): Kazuhiko Matsumoto, Takaaki Oka, Toshiyuki Nohira and Rika Hagiwara
  • Journal Title: Inorg. Chem Volume: 52 Issue: 2 Pages: 568-576
  • DOI: 10.1021/ic3010486
  • Peer Reviewed
• [Journal Article] Intermediate-temperature ionic liquid NaFSA-KFSA and its application to sodium secondary batteries (2012)
  • Author(s): Atsushi Fukunaga, Toshiyuki Nohira, Yu Kozawa, Rika Hagiwara, Shoichiro Sakai, Koji Nitta and Shinji Inazawa
  • Journal Title: J. Power Sources Volume: 209 Pages: 52-56
  • DOI: DOI:10.1016/j.jpowsour.2012.02.058
  • Peer Reviewed
• [Journal Article] Nonhumidified fuel cell using N-ethyl-N-methylpyrrolidinium fluorohydrogenate ionic liquid-polymer composite membranes (2012)
  • Author(s): Pisit Kiatkittikul, Toshiyuki Nohira and Rika Hagiwara
  • Journal Title: J. Power Sources Volume: 220 Pages: 10-14
  • DOI: DOI:10.1016/j.jpowsour.2012.07.124
  • Peer Reviewed
• [Journal Article] Trialkylsulfonium Fluorohydrogenate Giving the Highest Conductivity in Room Temperature Ionic Liquids (2012)
  • Author(s): Ryosuke Taniki, Kazuhiko Matsumoto and Rika Hagiwara
  • Journal Title: Electrochem. Solid-State Lett. Volume: 15(4) Pages: F13-F15
  • DOI: DOI:10.1149/2.025204esl
  • Peer Reviewed
• [Journal Article] Highly Conductive Plastic Crystals Based on Fluorohydrogenate Anions (2012)
  • Author(s): Ryosuke Taniki, Kazuhiko Matsumoto, Rika Hagiwara, Kan Hachiya, TakashiMorinaga and Takaya Sato
  • Journal Title: J Phys Chem B
  • DOI: DOI:10.1021/jp311558h
  • Peer Reviewed
• [Journal Article] Phase behavior of 1-dodecyl-3-methylimidazolium fluorohydrogenate salts (C12MIm(FH)nF, n = 1.0-2.3) and their anisotropic ionic conductivity as ionic liquid crystal electrolytes (2012)
  • Author(s): Fei Xu
  • Journal Title: J Phys Chem B Volume: 116(33) Pages: 10106-10112
  • DOI: 10.1021/jp30522
  • Peer Reviewed
• [Journal Article] Charge-discharge behavior of tin negative electrode for a sodium secondary battery using intermediate temperature ionic liquid sodium bis(fluorosulfonyl)amide–potassium bis(fluorosulfonyl)amide (2012)
  • Author(s): Takayuki Yamamoto
  • Journal Title: Journal of Power Sources Volume: 217(0) Pages: 479-484
  • DOI: 10.1016/j.jpowsour.2012.05.110
  • Peer Reviewed
• [Journal Article] Properties of an Intermediate Temperature Ionic Liquid Natfsa-Cstfsa and Charge-Discharge Properties of Nacro2 Positive Electrode at 423 K for a Sodium Secondary Battery. (2012)
  • Author(s): Toshiyuki Nohira
  • Journal Title: J. Power Sources Volume: 205 Pages: 506-509
  • DOI: 10.1016/j.jpowsour.2011.11.086
  • Peer Reviewed
• [Journal Article] New inorganic ionic liquids possessing low melting temperatures and wide electrochemical windows : Ternary mixtures of alkali bis(fluorosulfonyl)amides (2012)
  • Author(s): Keigo Kubota, Toshiyuki Nohira, Rika Hagiwara
  • Journal Title: Electrochim.Acta Volume: 66 Pages: 320-324
  • DOI: doi:10.1016/j.electacta.2012.01.097
  • Peer Reviewed
• [Journal Article] Physicochemical properties and plastic crystal structures of phosphonium fluorohydrogenate salts (2011)
  • Author(s): Takeshi Enomoto Shunsuke Kanematsu Katsuhiko Tsunashima Kazuhiko Matsumoto, Rika Hagiwara
  • Journal Title: Physical Chemistry and Chemical Physics Volume: 13 Pages: 12536-12544
  • DOI: DOI:10.1039/c1cp20285e
  • Peer Reviewed
• [Journal Article] Solubility and diffusion coefficient of oxygen in EMPyr(FH)1.7F room temperature ionic liquid at 297-373 K (2011)
  • Author(s): Yuta Tani, Toshiyuki Nohira, Rika Hagiwara
  • Journal Title: Electrochim. Acta Volume: 56 Pages: 3852-3856
  • DOI: DOI:10.1016/j.electacta.2011.02.038
  • Peer Reviewed
• [Journal Article] Ionic liquids based on fluoro- and oxofluorocomplex anions (2011)
  • Author(s): Kazuhiko Matsumoto, Toshiyuki Nohira, Rika Hagiwara
  • Journal Title: Yoyuen oyobi Koon Kagaku Volume: 54(1) Pages: 29-36
  • Peer Reviewed
• [Journal Article] Effects of the cationic structures of fluorohydrogenate ionic liquid electrolytes on the electric double layer capacitance (2010)
  • Author(s): Atsushi Senda, Kazuhiko Matsumoto, Toshiyuki Nohira, Rika Hagiwara
  • Journal Title: Journal of Power Sources Volume: 195(13) Pages: 4414-4417
  • DOI: DOI:10.1016/j.jpowsour.2010.01.055
  • Peer Reviewed
• [Journal Article] Electrochemical Properties of the Ionic Liquid 1-Ethyl-3-methylimidazolium Difluorophosphate as an Electrolyte for Electric Double-Layer Capacitors (2010)
  • Author(s): Kazuhiko Matsumoto, Rika Hagiwara
  • Journal Title: Journal of the Electrochemical Society Volume: 157(5) Pages: A578-A581
  • DOI: DOI:10.1149/1.3336831
  • Peer Reviewed
• [Journal Article] Thermal Properties of Alkali Bis(pentafluoroethylsulfonyl)amides and Their Binary Mixtures (2010)
  • Author(s): Keigo Kubota, Toshiyuki Nohira, Rika Hagiwara
  • Journal Title: Journal of Chemical & Engineering Data Volume: 55(7) Pages: 2546-2549
  • DOI: DOI:10.1021/je9010932
  • Peer Reviewed
• [Journal Article] Effects of Alkyl Chain Length on Properties of 1-Alkyl-3-methylimidazolium Fluorohydrogenate Ionic Liquid Crystals (2010)
  • Author(s): Fei Xu, Kazuhiko Matsumoto, Rika Hagiwara
  • Journal Title: Chemistry--A European Journal Volume: 16(43) Pages: 12970-12976
  • DOI: DOI:10.1002/chem.201001364
  • Peer Reviewed
• [Journal Article] Thermal Properties of Alkali (Fluorosulfonyl)(trifluoromethylsulfonyl)amides (2010)
  • Author(s): Keigo Kubota, Toshiyuki Nohira, Rika Hagiwara, Hajime Matsumoto
  • Journal Title: Chemistry Letters Volume: 39(12) Pages: 1303-1304
  • DOI: DOI:10.1246/cl.2010.1303
  • Peer Reviewed
• [Journal Article] Electrochemical properties of alkali bis(trifluoromethylsulfonyl)amides and their eutectic mixtures (2010)
  • Author(s): Keigo Kubota, K. Tamaki, Toshiyuki Nohira, Takuya Goto, Rika Hagiwara
  • Journal Title: Electrochimica Acta Volume: 55, No. 3 Pages: 1113-1119
  • DOI: DOI:10.1016/j.electacta.2009.09.024
  • Peer Reviewed
• [Journal Article] Development and application of high functional ionic liquid (Academic Award) (2010)
  • Author(s): Rika Hagiwara
  • Journal Title: Electrochemistry (Tokyo, Japan) Volume: 78 Issue: 7 Pages: 626
  • Peer Reviewed
• [Journal Article] A new series of ionic liquids based on the difluorophosphate anion (2009)
  • Author(s): Kazuhiko Matsumoto, Rika Hagiwara
  • Journal Title: Inorganic Chemistry Volume: 48 Pages: 7350-7358
  • DOI: DOI:10.1021/ic9008009
  • Peer Reviewed
• [Journal Article] Electrochemically stable fluorohydrogenate ionic liquids based on quaternary phosphonium cations (2009)
  • Author(s): Shunsuke Kanematsu, Kazuhiko Matsumoto, Rika Hagiwara
  • Journal Title: Electrochemistry Communications Volume: 11 Pages: 1312-1315
  • DOI: DOI:10.1016/j.elecom.2009.05.002
  • Peer Reviewed
• [Journal Article] A rechargeable lithium metal battery operating at intermediate temperatures using molten alkali bis(trifluoromethylsulfonyl)amide mixture as an electrolyte (2008)
  • Author(s): Atsushi Watarai, Keigo Kubota, Masaki Yamagata, Takuya Goto, Toshiyuki Nohira, Rika Hagiwara, Koichi Ui and Naoaki Kumagai
  • Journal Title: Journal of Power Sources Volume: 183 Pages: 724-729
  • DOI: DOI:10.1016/j.jpowsour.2008.05.054
  • Peer Reviewed
• [Journal Article] Novel inorganic ionic liquids possessing low melting temperatures and wide electrochemical windows: Binary mixtures of alkali bis(fluorosulfonyl)amides (2008)
  • Author(s): Keigo Kubota, Toshiyuki Nohira, Takuya Goto and Rika Hagiwara
  • Journal Title: Electrochemistry Communications Volume: 10 Pages: 1886-1888
  • DOI: DOI:10.1016/j.elecom.2008.10.001
  • Peer Reviewed
• [Journal Article] Ternary Phase Diagrams of Alkali Bis(trifluoromethylsulfonyl)amides (2008)
  • Author(s): Keigo Kubota, Toshiyuki Nohira, Takuya Goto and Rika Hagiwara
  • Journal Title: Journal of Chemical & Engineering Data Volume: 53 Pages: 2144-2147
  • DOI: DOI:10.1021/je800292f
  • Peer Reviewed
• [Journal Article] Thermal Properties of Mixed Alkali Bis(trifluoromethylsulfonyl)amides (2008)
  • Author(s): 26 Rika Hagiwara, Kenichiro Tamaki, Keigo Kubota, Takuya Goto and Toshiyuki Nohira
  • Journal Title: Journal of Chemical & Engineering Data Volume: 53 Pages: 355-358
  • DOI: DOI:10.1021/je700368r
  • Peer Reviewed
• [Presentation] Bis (fluorosulfonyl) amide salts as the electrolytes for rechargeable sodium batteries (2013)
  • Author(s): Rika Hagiwara, Toshiyuki Nohira, Takayuki Yamamoto, Koma Numata, Astushi Fukunaga, Shoichiro Sakai, Koji Nitta, Shinji Inazawa
  • Organizer: 21st Winter Fluorine Conference
• [Presentation] A Non-humidified Fuel Cell Using Fluorohydrogenate Ionic Liquid-Polymer Composite Membrane Prepared by Living Radical Polymerization (2012)
  • Author(s): Pisit Kiatkittikul, Jumpei Yamaguchi, Toshiyuki Nohira, Rika Hagiwara, Yoshinobu Tsujii, Takaya Sato
  • Organizer: ECS meeting 222nd Prime
  • Place of Presentation: Hawaii, U.S.A
  • Year and Date: 20121007-12
• [Presentation] A Novel Rechargeable Sodium Battery Using a Mixed Molten Amide Electrolyte (2012)
  • Author(s): Rika Hagiwara
  • Organizer: 4th Asian and 44th Symposium on Molten Salt Chemistry
  • Place of Presentation: 宮城県,宮城市
  • Year and Date: 20120923-20120927
  • Invited
• [Presentation] NaFSA-KFSAイオン液体を用いたNa二次電池用Sn-Na合金負極の平衡電位と合金相に関する検討 (2012)
  • Author(s): 山本貴之, 野平俊之, 萩原理加, 福永篤史, 酒井将一郎, 新田耕司, 稲澤信二
  • Organizer: 電気化学会第53回電池討論会
• [Presentation] Performance and stability improvement of a non-humidified fuel cell using N-ethyl-N-methylpyrrolidinium fluorohydrogenate ionic liquid-polymer composite membrane (2012)
  • Author(s): P. Kiatkittikul, J. Yamaguchi, T. Nohira, R. Hagiwara, Y. Tsujii, T. Sato
  • Organizer: International Fuel Cell Workshop 2012
• [Presentation] Dialkylpyrrolidinium Fluorohydrogenate Ionic Liquid-Polymer Composite Membranes for a Non-humidified Fuel Cell (2011)
  • Author(s): Pisit Kiatkittikul, Ryosuke Taniki, Kazuhiko Matsumoto, Toshiyuki Nohira, Rika Hagiwara, Yoshinobu Tsujii, Takashi Morinaga, Takaya Sato
  • Organizer: The 62nd Annual Meeting of the International Society of Electrochemistry
  • Place of Presentation: Niigata, Japan
  • Year and Date: 20110911-16
• [Presentation] 高導電性トリアルキルスルフォニウムフルオロハイドロジェネートイオン液体 (2011)
  • Author(s): 谷木良輔, 松本一彦, 萩原理加
  • Organizer: 第1回イオン液体討論会
  • Place of Presentation: とりぎん文化会館, 鳥取
  • Year and Date: 20110117-18
• [Presentation] 混合アルカリアミド塩を用いた二次電池 (2011)
  • Author(s): 萩原理加
  • Organizer: 電池技術委員会新電池構想部会第79回講演会
  • Place of Presentation: 慶応義塾大学日吉キャンパス(招待講演)
  • Year and Date: 2011-11-18
• [Presentation] Rechargeable Alkaline Metal Batteries of Mixed Amide Salts (2011)
  • Author(s): Rika Hagiwara
  • Organizer: 米国電気化学会第220回大会
  • Place of Presentation: Boston, USA
  • Year and Date: 2011-10-11
• [Presentation] 低融点溶融塩を用いた新しい蓄電池 (2011)
  • Author(s): 萩原理加
  • Organizer: 日本化学会第92回春季年会 次世代エネルギー技術～分散型エネルギー社会を目指して～
  • Place of Presentation: 慶応義塾大学日吉キャンパス, 東京
  • Year and Date: 2011-03-27
• [Presentation] Sodium secondary batteries using binary molten (Na, K) FSA (2011)
  • Author(s): Atsushi Fukunaka
  • Organizer: The 62nd Annual Meeting of the International Society of Electrochemistry
• [Presentation] (Li, K, Cs)FSA三元系無機イオン液体のリチウム二次電池への応用 (2010)
  • Author(s): 沼田昂真, 野平俊之, 萩原理加, 宇井幸一, 熊谷直昭
  • Organizer: 第51回電池討論会
  • Place of Presentation: 愛知県産業労働センター
  • Year and Date: 20101109-20101111
• [Presentation] Structual and electrochemical studies of fluorohydrogenate ionic liquids (2010)
  • Author(s): Rika Hagiwara, Takeshi Enomoto, Atsushi Senda, Kazuhiko Matsumoto, Toshiyuki Nohira
  • Organizer: 16th European Symposium on Fluorine Chemistry
  • Place of Presentation: Ljubljana,Slovenia
  • Year and Date: 20100718-23
• [Presentation] New lithium secondary batteries operating at 50-170℃ using mixed alkali amide melts as the electrolytes (2010)
  • Author(s): Toshiyuki Nohira, Koma Numata, Tetsuya Fujimori, Rika Hagiwara, Kouichi Ui, Naoaki Kumagai
  • Organizer: The 8th Japan-France Joint Seminar on Lithium Ion Batteries
• [Presentation] フッ化物イオン液体の電解質としての可能性 (2010)
  • Author(s): 萩原理加
  • Organizer: 電気化学会 キャパシタ技術委員会 平成22年度第1回研究会
• [Presentation] Fluorohydrogenate Ionic Liquid Fuel Cells Operating at Intermediate Temperature under Unhumidified Condition (2009)
  • Author(s): Toshiyuki Nohira
  • Organizer: The 4th International Conference on Polymer Batteries and Fuel Cells
  • Place of Presentation: Yokohama, Japan
  • Year and Date: 20090802-06
• [Presentation] Unhumidified Fuel Cells Operating at Intermediate Temperature Using Fluorohydrogenate Ionic Liquids (2009)
  • Author(s): Toshiyuki Nohira
  • Organizer: 3rd Congress on Ionic Liquids
  • Place of Presentation: Cairns, Australia
  • Year and Date: 20090531-0604
• [Presentation] Physicochemical properties of mixed MFSA (M=Li, Na, K, Rb, Cs) ionic liquids (2009)
  • Author(s): Keigo Kubota
  • Organizer: 3rd Congress on Ionic Liquids
• [Presentation] Fluorohydrogenate Ionic Liquids - Their Unique Featuresand New Applications - (2008)
  • Author(s): Rika Hagiwara, Toshiyuki Nohira, Kazuhiko Matsumoto, Shinji Kohara
  • Organizer: 2008 Joint Symposium on Molten Salts
  • Place of Presentation: Kobe, Japan
  • Year and Date: 20081019-20081023
• [Presentation] NaTFSI-CsTFSI二元系溶融塩の物性とナトリウム二次電池への応用 (2008)
  • Author(s): 石橋達也, 金村祥平, 野平俊之, 萩原理加
  • Organizer: 第49回電池討論会
• [Presentation] Molten alkali bis (trifluoromethylsulfonyl) amides and their application to rechargeable lithium batteries (2008)
  • Author(s): Rika Hagiwara, Toshiyuki Nohira, Takuya Goto, Atsushi Watarai, Tetsuya Fujimori, Keigo Kubota, Masaki Yamagata, Koichi Ui, Naoaki Kumagai
  • Organizer: PRiME2008
• [Book] イオン液体の科学-新世代液体への挑戦-、 (2012)
  • Author(s): 萩原理加、イオン液体研究会監修、西川恵子・大内幸雄・伊藤敏幸・大野弘幸・渡邉正義編
  • Total Pages: 374
  • Publisher: 丸善出版
• [Book] Novel Fluoroanion Salts, in Electrochemical Aspects of Ionic Liquids. (2011)
  • Author(s): Rika Hagiwara and Kazuhiko Matsumoto
  • Total Pages: 392
  • Publisher: John Wiley & Sons, Inc.
• [Patent(Industrial Property Rights)] BATTERY AND ENERGY SYSTEM (2018)
  • Inventor(s): Fukunaga Astushi, Inazawa Shinji, Majima Masatoshi, Nitta Koji, Sakai Shoichiro,
  • Industrial Property Rights Holder: Kyoto University Sumitomo Electric Industries, Ltd
  • Industrial Property Rights Type: 特許
  • Industrial Property Number: CA2775284 C
  • Overseas
• [Patent(Industrial Property Rights)] 溶融塩電池 (2012)
  • Inventor(s): 新田耕司、稲澤信二、酒井将一郎、福永篤志、野平俊之、萩原理加
  • Industrial Property Rights Holder: 京都大学、住友電気工業株式会社
  • Industrial Property Rights Type: 特許
  • Patent Publication Number: 特開2012-182087
• [Patent(Industrial Property Rights)] 溶融塩電池 (2012)
  • Inventor(s): 新田耕司、稲澤信二、酒井将一郎、福永篤志、野平俊之、萩原理加
  • Industrial Property Rights Holder: 京都大学、住友電気工業株式会社
  • Industrial Property Rights Type: 特許
  • Industrial Property Number: W02012/117916 A1
  • Overseas
• [Patent(Industrial Property Rights)] 溶融塩電池 (2012)
  • Inventor(s): 新田耕司、稲澤信二、酒井将一郎、福永篤志、野平俊之、萩原理加
  • Industrial Property Rights Holder: 京都大学、住友電気工業株式会社
  • Industrial Property Rights Type: 台湾特許
  • Industrial Property Number: 201232874
  • Overseas
• [Patent(Industrial Property Rights)] 溶融塩電池 (2012)
  • Inventor(s): 新田耕司、稲澤信二、真嶋正利、山口 篤、酒井将一郎、福永篤志、萩原理加、野平俊之、松本一彦
  • Industrial Property Rights Holder: 京都大学、住友電気工業株式会社
  • Industrial Property Rights Type: 特許
  • Industrial Property Number: W02012/073653 A1
  • Overseas
• [Patent(Industrial Property Rights)] 溶融塩電池の稼働方法 (2011)
  • Inventor(s): 福永篤志、稲澤信二、新田耕司、酒井将一郎、沼田昴真、萩原理加、野平俊之、山本貴之
  • Industrial Property Rights Holder: 京都大学、住友電気工業株式会社
  • Industrial Property Number: 特願2011-228111
  • Filing Date: 2011-10-17
• [Patent(Industrial Property Rights)] 電気およびエネルギーシステム (2011)
  • Inventor(s): 福永 篤志, 稲澤 信二, 間嶋 正利, 新田 耕司, 酒井 将一郎, 萩原 理加, 野平 俊之, 石橋 達也
  • Industrial Property Rights Holder: 京都大学, 住友電気工業株式会社
  • Industrial Property Rights Type: 特許
  • Industrial Property Number: 第10-1684718号
  • Filing Date: 2011-12-09
  • Acquisition Date: 2016-12-02
  • Overseas
• [Patent(Industrial Property Rights)] 溶融塩電池 (2011)
  • Inventor(s): 新田耕司、稲澤信二、真嶋正利、山口 篤、酒井将一郎、福永篤志、萩原理加、野平俊之、松本一彦
  • Industrial Property Rights Holder: 京都大学、住友電気工業株式会社
  • Industrial Property Rights Type: 特許
  • Industrial Property Number: 特願2010-267261
• [Patent(Industrial Property Rights)] 電気二重層キャパシタ用炭素材料及びその製造方法並びに核材料を用いた電気二重層キャパシタ (2011)
  • Inventor(s): 白石荘志、安島大輔、萩原理加
  • Industrial Property Rights Holder: 群馬大学
  • Industrial Property Rights Type: 特許
  • Industrial Property Number: W02011/142048 A1
  • Overseas
• [Patent(Industrial Property Rights)] 電気およびエネルギーシステム (2011)
  • Inventor(s): 福永篤志、稲澤信二、真嶋正利、新田耕司、酒井将一郎、萩原理加、野平俊之、石橋達也
  • Industrial Property Rights Holder: 京都大学、住友電気工業株式会社
  • Industrial Property Rights Type: 特許
  • Industrial Property Number: W02011/036907 A1
  • Overseas
• [Patent(Industrial Property Rights)] 電気二重層キャパシタ (2010)
  • Inventor(s): 萩原理加、伊藤靖彦、宇恵 誠、鳥海明子
  • Industrial Property Rights Holder: 三菱化学株式会社
  • Industrial Property Rights Type: 特許
  • Industrial Property Number: 特許4453174
• [Patent(Industrial Property Rights)] 溶融塩組成物 (2010)
  • Inventor(s): 萩原理加、後藤琢也、野平俊之、窪田啓吾
  • Industrial Property Rights Holder: 京都大学
  • Industrial Property Rights Type: 特許
  • Industrial Property Number: JP2009/067644 A